全文获取类型
收费全文 | 7454篇 |
免费 | 1434篇 |
国内免费 | 779篇 |
专业分类
化学 | 1460篇 |
晶体学 | 54篇 |
力学 | 99篇 |
综合类 | 21篇 |
数学 | 180篇 |
物理学 | 3015篇 |
无线电 | 4838篇 |
出版年
2024年 | 29篇 |
2023年 | 95篇 |
2022年 | 139篇 |
2021年 | 286篇 |
2020年 | 187篇 |
2019年 | 187篇 |
2018年 | 210篇 |
2017年 | 318篇 |
2016年 | 420篇 |
2015年 | 431篇 |
2014年 | 641篇 |
2013年 | 563篇 |
2012年 | 705篇 |
2011年 | 699篇 |
2010年 | 550篇 |
2009年 | 479篇 |
2008年 | 536篇 |
2007年 | 528篇 |
2006年 | 487篇 |
2005年 | 363篇 |
2004年 | 298篇 |
2003年 | 264篇 |
2002年 | 218篇 |
2001年 | 156篇 |
2000年 | 163篇 |
1999年 | 114篇 |
1998年 | 91篇 |
1997年 | 108篇 |
1996年 | 82篇 |
1995年 | 46篇 |
1994年 | 66篇 |
1993年 | 33篇 |
1992年 | 34篇 |
1991年 | 31篇 |
1990年 | 17篇 |
1989年 | 14篇 |
1988年 | 18篇 |
1987年 | 13篇 |
1986年 | 9篇 |
1985年 | 5篇 |
1984年 | 9篇 |
1983年 | 1篇 |
1982年 | 8篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1977年 | 7篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有9667条查询结果,搜索用时 0 毫秒
61.
62.
The use of a tunable multimode diode laser system based on correlation spectroscopy and wavelength modulation spectroscopy to measure the concentration of the carbon dioxide in ambient air through the 2 υ1 + 2υ2 + υ3 absorption lines around 1570 nm is reported. The carbon dioxide concentrations are derived from the relationship between the normalized second-harmonic signal peak heights of the measurement and reference signals. The validation of the system is conducted by a set of experiments with controlled carbon dioxide and nitrogen mixtures. The correlation and standard deviation between the measured and actual carbon dioxide concentrations are 0.9973 and 4.03%, respectively, over the tested range. A detection limit of 340 ppm m was achieved using 30 successive measurements during 30 min. All these results demonstrated potential utility of the system for carbon dioxide sensing. 相似文献
63.
Jung-Sheng Chiang Chun-Lung Tseng Ken-Lin Chung Yen-Sheng Lin Nai-Hsiang Sun 《Fiber and Integrated Optics》2016,35(1):29-37
In this article, a broadband gallium-nitride-based light-emitting diode with a one-dimensional photonic crystal layer is investigated. The broadband light-emitting diode using the proposed backside reflector has high reflectance (>95%) over a 270-nm bandwidth in visible light at an arbitrary incidence angle. A broadband light-emitting diode of high output power due to the high reflectivity is achieved. Also reported are the results for light-emitting diodes by the transistor outline can (TO-can) package. The proposed light-emitting diodes possess broadband high reflected spectra, high output power for light extraction, and a good view angle. 相似文献
64.
65.
碳纳米微粒的共振散射光谱研究 总被引:35,自引:1,他引:35
液相碳纳米微粒的共振散射光谱实验表明,当碳浓度小于360mg/L时,它在400、470、510和940nm产生4个共振散射峰;浓度大于900mg/L时无共振散射、碳微粒浓度在0.45-45mg/L范围内与共振散射光强度I470nm成良好的性关系,研究了光源和扫描速度对液相碳纳米微粒共振散射光谱的影响。结果表明,光源的发射强度分布不一是产生共振散射光谱峰的一个重要因素,并结合已有的实验结果提出了界面共振吸收和黑白纳米微粒共振散射概念,解释了碳纳米微粒体系的共振散射光谱。 相似文献
66.
M.D. Gil García F. Cañada Cañada M.J. Culzoni L. Vera-Candioti G.G. Siano H.C. Goicoechea M. Martínez Galera 《Journal of chromatography. A》2009,1216(29):5489-5496
An analytical method for the simultaneous determination of seven non-steroidal anti-inflammatory drugs (naproxen, ketoprofen, diclofenac, piroxicam, indomethacin, sulindac and diflunisal) and the anticonvulsant carbamazepine in river and wastewater is reported. The method involves pre-concentration and clean-up by solid-phase microextraction using polydimethylsiloxane/divinylbenzene fibers, followed by liquid chromatography with diode array detection analysis. Owing to the fact that river water samples did not contain interferences and no sensitivity changes due to sample matrix were observed, external calibration was implemented. Standardization was also applied in order to carry out the prediction step by preparing only two diluted standards that were subjected to the pre-concentration step and a set of standards prepared in solvent. For the analysis of wastewater samples, in contrast, it was necessary to implement standard addition calibration in combination with the multivariate curve resolution-alternating least squares (MCR-ALS) algorithm, which allowed us to overcome matrix effect and exploit the second order advantage. Recoveries ranging from 72% to 125% for all pharmaceuticals proved the accuracy of the proposed method in river water samples. On the other hand, wastewater sample recoveries ranged from 83% to 140% for all pharmaceuticals, showing an acceptable performance – considering this sample contains no modeled interferences. 相似文献
67.
This paper describes the determination of alkaloids and amino acids (AAs) using CE in conjunction with sequential light-emitting diode-induced fluorescence (LEDIF) and electrochemiluminescence (ECL) detections. In the CE-LEDIF-ECL system, the ECL detector was located in the outlet of the capillary, while the LEDIF detector was positioned 12 cm from the outlet. Naphthalene-2,3-dicarboxaldehyde (NDA) was used to form fluorescent AA-NDA derivatives from AAs possessing primary amino groups, while Ru(bpy)(3) (2+) was used to obtain ECL signals for analytes having secondary and tertiary amino groups. In the presence of poly(ethylene oxide), we accomplished the CE-LEDIF-ECL separation of a mixture of 12 AA-NDA derivatives, anabasine, nicotine, and proline within 11 min. This low-cost CE-LEDIF-ECL system allows the analysis of these AA-NDA derivatives and alkaloids at concentrations in the ranges of 49 nM-0.2 microM and 0.66-4.7 microM, respectively. We applied our CE-LEDIF-ECL system to the analysis of a urine sample and also to tobacco extracts. We obtained good qualitative and quantitative results when using this method with these analytes: the RSDs were below 3.0 and 2.8%, respectively. This CE-LEDIF-ECL system provides the advantages of high efficiency, speed, and sensitivity for the analysis of analytes possessing amino groups. 相似文献
68.
Novel conjugated silole‐containing polyfluorenes, with green‐ and red‐emissive siloles on the backbone of the blue‐emissive polyfluorene are synthesized for white light electroluminescence (EL) from a single polymer with simultaneous red, green, and blue (RGB) emission. The CIE coordinates (0.33, 0.36) of the white light EL spectra are very close to that for pure white light (0.33, 0.33). The EL spectra are also quite stable at different applied voltages or brightness. The relative intensities for the three RGB peaks, at 450, 505, and 574 nm, were 0.94, 1, and 0.97, respectively, which demonstrates a balanced simultaneous RGB emission. A maximum luminous efficiency of 2.03 cd · A−1 for a brightness of 344 cd · m−2, and a luminous efficiency of 1.86 cd · A−1 for a more practical brightness of 2 703 cd · m−2, were achieved.
69.
A rapid, simple and interference-free method was developed to evaluate the inhibitory activity of hydro-lyzed peptides from egg white protein against the angiotensin-converting enzyme. The total reaction volume was 60 μL, saving the cost. The assay was based on a HPLC separation and quantification of the synthetic substrate hip-puryl-L-histidyl-L-leucine and its hydrolyzed product―hippuric acid; the separation was performed on a C 18 column eluted by a mobile phase of acetonitrile/water(0.5% TFA) at a volume ratio of 25:75. At a signal to noise ratio(S/N) of 10, the detective limit of the quantitation of hippuric acid was (0.4600±0.0097) μmol/L. The standard curve shows a linear response with a slope of 49488 and a correlation coefficient of 0.9995. The assay was adequate for the study of ACE inhibition by Captopril and peptides derived from food protein, and showed a very good correlation with the previous methods. 相似文献
70.
José Alejandro Sánchez-Gutiérrez Monserrat Vázquez-Sánchez Dioselina Álvarez-Bernal María Daniela Mares-Quiñones Juan Ignacio Valiente-Banuet 《Analytical letters》2018,51(13):1986-1998
The total phenolic and flavonoid content, phenolic composition, and in vitro antioxidant capacity of ethanolic extracts of Ximenia parviflora Benth. var. parviflora fruits collected at Zinaparo, Michoacan (in central Mexico) were determined. Fruit extracts present a high scavenging activity of 2,2-diphenyl-1-picrylhydrazyl and 2,2′-azino-bis[3-ethylbenzothiazoline-6-sulfonic acid] radicals (71.49?±?0.11% and 85.00?±?1.29% inhibition, respectively). The four phenolic compounds identified in fruit extracts by high-performance liquid chromatography with diode array detection were gallic acid, chlorogenic acid, caffeic acid, and quercetin. X. parviflora fruits may be used as a starting material for the extraction of high value antioxidant phenolic compounds with potential applications in the pharmaceutical and dietary supplement industries. 相似文献