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961.
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965.
Peter B. Luppa Carolin MüllerAlice Schlichtiger 《Trends in analytical chemistry : TRAC》2011,30(6):887-898
Point-of-care testing (POCT) is a laboratory-medicine discipline that is evolving rapidly in analytical scope and clinical application. In this review, we first describe the state of the art of medical-laboratory tests that can be performed near the patient. At present, POCT ranges from basic blood-glucose measurement to complex viscoelastic coagulation assays. POCT shortens the time to clinical decision-making about additional testing or therapy, as delays are no longer caused by transport and preparation of clinical samples, and biochemical-test results are rapidly available at the point of care. Improved medical outcome and lower costs may ensue.Recent, evolving technological advances enable the development of novel POCT instruments. We review the underlying analytical techniques. If new instruments are not yet in practical use, it is often hard to decide whether the underlying analytical principle has real advantage over former methods. However, future utilization of POCT also depends on health-care trends and new areas of application. But, even today, it can be assumed that, for certain applications, near-patient testing is a useful complement to conventional laboratory analyses. 相似文献
966.
An experimental study was conducted to investigate the effects of several operational parameters in the emission spectra, in the 400-850 nm wavelength region, of a laboratory Argon plasma source. In particular, the emission spectra of the inductively coupled plasma and the Helicon plasma modes of operation were compared. Comparisons of spectra point to a significant increase in the ionization fraction of the plasma for the Helicon mode of operation. The spectral measurements allow one to determine the major trends in the plasma electron density for various parameters such as power delivered to the helical antenna, propellant mass flow rate, and applied external magnetic field intensity.Analysis of a prominent Argon single ion line, at 434.8 nm, points out that the plasma electron density increases linearly with the power delivered to the helical antenna, and that there is an optimum propellant mass flow rate for maximum ionization fraction. Additional analysis of the same line shows that above a minimum applied axial magnetic field intensity, the variation in the magnetic field strength has little effect on the plasma electron density. 相似文献
967.
J.J. Camacho L. DíazM. Santos J.M.L. Poyato 《Spectrochimica Acta Part B: Atomic Spectroscopy》2011,66(1):57-66
Laser-induced breakdown spectroscopy of helium plasma, initially at room temperature and pressures ranging from 12 to 101 kPa was investigated using a transverse excitation atmospheric CO2 pulsed laser (λ = 9.621 and 10.591 μm, a full width at half maximum of 64 ns, and an intensity from 1.5 to 5.36 GW cm−2). The helium breakdown spectrum is mainly due to electronic relaxation of excited He, He+ and H. Plasma characteristics were examined in detail on the emission lines of He and He+ by the time-integrated and time-resolved optical emission spectroscopy technique. Optical breakdown threshold intensities, ionization degree and plasma temperatures were obtained. An auxiliary metal mesh target was used to analyze the temporal evolution of the species in the plasma. The results show a faster decay of the continuum emission and He+ species than in the case of neutral He atoms. The velocity and kinetic energy distributions for He and He+ species were obtained from time-of-flight measurements. Electron density in the laser-induced plasma was estimated from the analysis of spectral data at various times from the laser pulse incidence. Temporal evolution of electron density has been used for the estimation of the three-body electron-ion recombination rate constant. 相似文献
968.
Xianglei Mao Alexander A. Bol'shakov Dale L. Perry Osman Sorkhabi Richard E. Russo 《Spectrochimica Acta Part B: Atomic Spectroscopy》2011,66(8):604-609
Laser Ablation Molecular Isotopic Spectrometry (LAMIS) was recently reported for optical isotopic analysis of condensed samples in ambient air and at ambient pressure. LAMIS utilizes molecular emissions which exhibit larger isotopic spectral shits than in atomic transitions. For boron monoxide 10BO and 11BO, the isotopic shifts extend from 114 cm−1 (0.74 nm) to 145–238 cm−1 (5–8 nm) at the B2Σ+ (v = 0) → X2Σ+ (v = 2) and A2Πi (v = 0) → X2Σ+ (v = 3) transitions, respectively. These molecular isotopic shifts are over two orders of magnitude larger than the maximum isotopic shift of approximately 0.6 cm−1 in atomic boron. This paper describes how boron isotope abundance can be quantitatively determined using LAMIS and how atomic, ionic, and molecular optical emission develops in a plasma emanating from laser ablation of solid samples with various boron isotopic composition. We demonstrate that requirements for spectral resolution of the measurement system can be significantly relaxed when the isotopic abundance ratio is determined using chemometric analysis of spectra. Sensitivity can be improved by using a second slightly delayed laser pulse arriving into an expanding plume created by the first ablation pulse. 相似文献
969.
H. Tsuruda M. MitoH. Deguchi S. TakagiA.A. Leitch K. LekinS.M. Winter R.T. Oakley 《Polyhedron》2011,30(18):2997-3000
The hydrostatic pressure response of TC of the bisdiselenazolyl radical ferromagnet 1 up to 5 GPa was investigated by AC magnetic susceptibility measurements using a SQUID magnetometer and a miniature diamond anvil cell. It was found that the ambient pressure value of TC = 17 K could be raised to 21 K at a pressure of 0.9 GPa. The experimental technique is described in detail and the pressure response is compared to that observed in related systems. 相似文献
970.
Adopting LB film method, an arachidic acid (AA)/PEDOT multilayer LB film was chosen, and polymerized EDOT monomers in hydrophilic group of LB to prepare arachidic acid (AA)/PEDOT multilayer LB film. UV‐Vis, FT‐IR and XPS analyses implied that EDOT was effectively polymerized in film, and thus PEDOT conducting polymer was produced. Analyses of XRR and SIMS indicated that film had a well‐arranged lamella structure, and further research showed that polymerization of EDOT in AA film destroyed the orderliness of the original LB film. This phenomenon could be related to the destructive effect of polymerization on layered structure. We used four‐point probe and semiconductor instrument to study the conductivity property of the film, and observed that the conductivity of AA/PEDOT film had sudden changes with the processing time of changes in effective conduction network. That was caused by "permeability" in conducting channel of multilayer film. The test results also indicated that the conductivity of AA/PEDOT film was obviously better than that of spin‐coating PEDOT/PSS film or that of ODA‐SA/PEDOT‐PSS film, which was due to the higher π structure of PEDOT structure and ordered film structure. 相似文献