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41.
通过湿化学法合成PZT陶瓷微粉实现粉料的高经、超细、粒度均匀及化学成分的精确控制。综述了湿化学法制备PZT陶瓷粉料的常用方法及其基本原理和生产工艺条件,并对溶胶-凝胶法、共沉淀-煅烧法和水热法制备PZT微粉的优越性及不足进行了评价。 相似文献
42.
Cu2O半导体超微粒子的光学性质 总被引:3,自引:0,他引:3
本文研究了表面修饰的Cu2O半导体超微粒子的光学性质.在Cu2O超微粒子中未观察到显著的量子尺寸效应,但测量到很强的宽带光致发光,且随着激发波长变短,其发光带的峰位蓝移,发光带宽度增加.最后,分析了Cu2O超微粒子的宽带发光机制,并讨论了热处理对超微粒子的发光强度的影响. 相似文献
43.
采用浸渍法制备了酸碱双功能催化剂 ,经过高温焙烧和气流粉碎得到超细粒子催化剂。结果表明 ,该超细催化剂对于由CO2 直接合成碳酸二甲酯的反应具有优良的催化活性 ,选择性和收率都要优于常规催化剂 ;结合反应精馏设备 ,可以将碳酸二甲酯的收率由 4 0 %提高至 70 %。 相似文献
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A simple and efficient extraction method based on acidic leaching has been developed for measurement of methylmercury (MeHg) in benthic organisms and plant material. Methylmercury was measured by speciated isotope-dilution mass spectrometry (SIDMS), using gas chromatography interfaced with inductively coupled plasma mass spectrometry (GC–ICP–MS). Reagent concentration and digestion temperature were optimized for several alkaline and acidic extractants. Recovery was evaluated by addition of MeHg enriched with CH3201Hg+. Certified reference materials (CRM) were used to evaluate the efficiency of the procedure. The final digestion method used 5 mL of 4 mol L–1 HNO3 at 55°C to leach MeHg from tissue and plant material. The digest was further processed by aqueous phase ethylation, without interference with the ethylation step, resulting in 96±7% recovery of CH3201Hg+ from oyster tissue and 93±7% from pine needles. Methylmercury was stable in this solution for at least 1 week and measured concentrations of MeHg in CRM were statistically not different from certified values. The method was applied to real samples of benthic invertebrates and inter-laboratory comparisons were conducted using lyophilized zooplankton, chironomidae, and notonectidae samples.Contribution No. 15 of the Mercury Experiment to Assess Atmospheric Loadings in Canada and the US (METAALICUS). 相似文献
46.
Marina Tikhonova Yuliya Kuzminova Xiaoying Fang Weiguo Wang Rustam Kaibyshev 《哲学杂志》2013,93(36):4181-4196
The effect of processing and annealing temperatures on the grain boundary characters in the ultrafine-grained structure of a 304-type austenitic stainless steel was studied. An S304H steel was subjected to multidirectional forging (MDF) at 500–800°C to total strains of ~4, followed by annealing at 800–1,000°C for 30 min. The MDF resulted in the formation of ultrafine-grained microstructures with mean grain sizes of 0.28–0.85 μm depending on the processing temperature. The annealing behaviour of the ultrafine-grained steel was characterized by the development of continuous post-dynamic recrystallization including a rapid recovery followed by a gradual grain growth. The post-dynamically recrystallized grain size depended on both the deformation temperature and the annealing temperature. The recrystallization kinetics was reduced with an increase in the temperature of the preceding deformation. The grain growth during post-dynamic recrystallization was accompanied by an increase in the fraction of Σ3n CSL boundaries, which was defined by a relative change in the grain size, i.e. a ratio of the annealed grain size to that evolved by preceding warm working (D/D0). The fraction of Σ3n CSL boundaries sharply rose to approximately 0.5 in the range of D/D0 from 1 to 5, which can be considered as early stage of continuous post-dynamic recrystallization. Then, the rate of increase in the fraction of Σ3n CSL boundaries slowed down significantly in the range of D/D0 > 5. A fivefold increase in the grain size by annealing is a necessary condition to obtain approximately 50% Σ3n CSL boundaries in the recrystallized microstructure. 相似文献
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48.
《Mechatronics》2022
In recent years a number of robotic steering systems have been proposed that are geared towards improving interventional radiology procedures such as tumor ablation and biopsy. These solutions have introduced new safety challenges in the physical human–robot interaction domain. This study presents a new 3D robotized needle steering algorithm compatible with CT and MR-imaging guidance. The steering algorithm is featured with an adaptive self-correction mechanism that works as a failure contingency tool that could be adapted online at each insertion step. The developed pHRI solution was designed to be compatible to ferro-magnetic issues and a reduced workspace inside the scanner bore. As far as we know, this is the first approach designed to steer rigid needles free of force sensors and which meets the challenges that prevail in our context. Our proposed approach helps overcome safety issues regarding the physical interaction between robotized needles and patients. Validation testing highlighted the feasibility of the new needle steering algorithm, while its accuracy revealed the potential of the approach under the proposed scope of application. 相似文献
49.
用溶液聚合法制备出轻度交联的含铅微凝胶,用光子相关光谱技术测定其在良溶剂中与H2S反应前、后的扩散行为,由外推法得到在浓度无限稀时的分子扩散系数,给出微凝胶的流体力学半径。结果表明:相同量的含铅微凝胶在不同的初始浓度下与H2S反应,生成含PbS纳米微粒的凝胶;但其体积增大不同,这说明H2S与含铅微凝胶的反应既可以在分子内也可以在分子间进行,分子间的反应使含硫化铅微凝胶扩散系数随浓度的变化曲线的线性范围变小。 相似文献
50.
由于半导体超微粒子具有独特的尺寸量子化效应和表面效应[1~6],它在利用太阳能光催化降解有机污染物,有机光合成及光电转化等领域中有着极其广泛的应用.目前,大量的工作集中在超微颗粒表面上有机物的光反应过程的研究[7]. 相似文献