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101.
A higher resolution edge‐based finite volume method for the simulation of the oil–water displacement in heterogeneous and anisotropic porous media using a modified IMPES method 下载免费PDF全文
Rogério Soares da Silva Paulo Roberto Maciel Lyra Ramiro Brito Willmersdorf Darlan Karlo Elisiário de Carvalho 《国际流体数值方法杂志》2016,82(12):953-978
In this article, we present a higher‐order finite volume method with a ‘Modified Implicit Pressure Explicit Saturation’ (MIMPES) formulation to model the 2D incompressible and immiscible two‐phase flow of oil and water in heterogeneous and anisotropic porous media. We used a median‐dual vertex‐centered finite volume method with an edge‐based data structure to discretize both, the elliptic pressure and the hyperbolic saturation equations. In the classical IMPES approach, first, the pressure equation is solved implicitly from an initial saturation distribution; then, the velocity field is computed explicitly from the pressure field, and finally, the saturation equation is solved explicitly. This saturation field is then used to re‐compute the pressure field, and the process follows until the end of the simulation is reached. Because of the explicit solution of the saturation equation, severe time restrictions are imposed on the simulation. In order to circumvent this problem, an edge‐based implementation of the MIMPES method of Hurtado and co‐workers was developed. In the MIMPES approach, the pressure equation is solved, and the velocity field is computed less frequently than the saturation field, using the fact that, usually, the velocity field varies slowly throughout the simulation. The solution of the pressure equation is performed using a modification of Crumpton's two‐step approach, which was designed to handle material discontinuity properly. The saturation equation is solved explicitly using an edge‐based implementation of a modified second‐order monotonic upstream scheme for conservation laws type method. Some examples are presented in order to validate the proposed formulation. Our results match quite well with others found in literature. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
102.
《Journal of polymer science. Part A, Polymer chemistry》2018,56(6):653-660
A new donor–acceptor (D–A) conjugated copolymer based on benzo[1,2‐b:4,5‐b′]dithiophene (BDT) and thieno[3,4‐c]pyrrole‐4,6‐dione (TPD) was synthesized via a Stille cross‐coupling reaction. A highly conjugated thiophene‐based side group, tris(thienylenevinylene) (TTV), was incorporated into each BDT unit to generate the two‐dimensional D–A copolymer (PBDT‐TTV). An alkoxy‐substituted BDT‐based TPD copolymer (PBDT‐OR) was synthesized using the same polymerization method for comparison. PBDT‐TTV thin films produced two distinct absorption peaks. The shorter wavelength absorption (458 nm) was attributed to the BDT units containing the TTV group, and the longer wavelength band (567–616 nm) was attributed to intramolecular charge transfer between the BDT donor and the TPD acceptor. The highest occupied molecular orbital energy levels of PBDT‐OR and PBDT‐TTV were calculated to be −5.53 and −5.61 eV, respectively. PBDT‐TTV thin films harvested a broad solar spectrum covering the range 300–700 nm. A comparison with the PBDT‐OR films revealed stronger interchain π–π interactions in the PBDT‐TTV films and, thus, a higher hole mobility. A polymer solar cell device prepared using PBDT‐TTV as the active layer was found to exhibit a higher power conversion efficiency than a device prepared using PBDT‐OR under AM 1.5 G (100 mW/cm2) conditions. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 653–660 相似文献
103.
《Analytical letters》2012,45(7):825-835
Abstract The sera of seventy-one women and twenty-six men of various ages were examined by a two dimensional (crossed) immunoelectrophoresis technique which was modified to detect a protein (the Down's Syndrome protein) originally found in the sera of mothers of trisomy 21 children. The sensitivity of the method is reported to be 0.1 to 1.0 mg/L. Modifications included use of a Tris-Tricine buffer, high voltage in the second dimension, and relatively low antibody concentration to allow easy detection of the Down's Syndrome (DS) protein. Of twenty-eight mothers and twelve fathers of trisomy 21 children, eighteen mothers and five fathers were positive, while of forty-three women and fourteen men having unaffected or no children, only seven women and two men were positive for the DS protein. Since the presence of the Down's Syndrome protein may indicate a propensity for giving birth to a trisomy 21 affected child, this crossed immunoelectrophoretic technique may be used as a screening procedure for the DS protein and, therefore, as a tool in genetic counseling. 相似文献
104.
《Journal of separation science》2017,40(18):3593-3601
The separation of high‐purity compounds from traditional Tibetan medicines plays an important role in investigating their bioactivity. Nevertheless, it is often quite difficult to isolate compounds with high purity because of the complexity of traditional Tibetan medicines. In this work, an offline two‐dimensional reversed‐phase preparative method was successfully developed for the separation of high‐purity compounds from Oxytropis falcata . Based on the analysis results, an ODS C18 prep column was used for first‐dimensional preparation, and 14.8 g of the crude sample was separated into five fractions with a recovery of 74.6%. Then, an XAqua C18 prep column was used to isolate high‐purity compounds in the second‐dimensional preparation because its separation selectivity is different with the ODS C18 stationary phase. As a result, eight compounds in the crude sample were isolated in more than 98% purity. This is the first report of trans‐cinnamic acid ( 1 ) and trifolirhizin ( 2 ) from Oxytropis falcata . This method has the potential to be an efficient separation method of high‐purity compounds from Oxytropis falcata and it shows great promise for the separation of high‐purity compounds from complex samples. 相似文献
105.
Cervix-cancer is the third most common female cancer worldwide. Papanicolaou (Pap) test, a well-recognized screening tool, is labor intensive, time consuming and prone to subjective interpretations. Optical spectroscopic methods, sensitive to molecular changes are being pursued as potential diagnostics tool. In this study we have explored Raman spectroscopic approach to differentiate exfoliated cell pellets using 94 cervical cell specimens (45-normal and 49-abnormal specimens). Study was carried out by two approaches. In the first approach, spectral data from 37 cell specimens were acquired and analyzed by Principal Component-Linear Discriminant Analysis (PC-LDA), which yielded classification efficiencies of 86% and 84% for normal and abnormal specimens, respectively. Mean and difference spectra suggest presence of blood in abnormal specimen as a major cause of discrimination. However, as tumor is vascular, bleeding was observed during abnormal sample collection. Hence, spectra of abnormal specimens show heme and fibrin features, and this can lead to false interpretations, as bleeding also occur in several non-cancerous conditions. Therefore, remaining 57 specimens were treated with Red Blood Corpuscles (RBC) lysis buffer in order to remove the RBC influence. PC-LDA resulted classification efficiency of about 79% and 78% for normal and abnormal smear, respectively – comparable to Pap test. Thus finding of the study suggests feasibility of Raman spectroscopic classification of normal and cancerous exfoliated cervical cell specimens. 相似文献
106.
阿尔茨海默病(AD)和轻度认知功能损伤(MCI)具有患者多、诊断难的特点,改进BP神经网络,提出自适应BP神经网络(ABP)进行100次AD和MCI诊断模拟,ABP神经网络的诊断正确率显著高于BP和RBF神经网络.采用留一法将101例正常人、200例MCI和90例AD患者的样本分为训练集和检测集,用ABP神经网络对其进行诊断模拟,总正确率达到73.91%. 相似文献
107.
108.
为了达到复杂系统快速故障搜寻的目的,设计了一种基于二元决策图优化的新型故障搜寻策略的检测系统设计。通过对基于二元决策图优化的故障搜寻方法研究和实际的硬件电路设计,最终实现了检测系统的软硬件设计。使用这种方法能够很好的实现故障诊断系统在嵌入式平台的开发,并能够取得较好的诊断效果。 相似文献
109.
最近几年我国经济发展速度加快,国民用电需求急剧增加,国家电力事业压力呈上升趋势。而在整个电力系统中,配电线路将发电厂与终端用户紧密联系起来,在其中发挥着重要的作用。由于现在终端用户越来越多,供电系统的压力增大,外界的各种干扰因素导致电力系统会发生电路故障,从而影响用户的正常使用。所以配电线路的质量直接关系到供电质量和供电可靠性,同时影响国家电网系统正常为用户提供电。所以必须重视配电线路质量问题,本文对配电线路故障识别与诊断进行初步分析,希望对国家电网运行安全有所帮助。 相似文献
110.