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171.
In this paper, we study the electronic band structure and the ferromagnetic properties of the organic radicalp-NPNN by employing density-functional theory with generalized gradient approximation (GGA) and local-spin densityapproximation (LSDA). The density of states, the total energy, and the spin magnetic moment are calculated. Thecalculations reveal that the δ-phase of p-NPNN has a stable ferromagnetic ground state. It is found that an unpairedelectron in this compound is localized in a single occupied molecular orbital (SOMO) constituted primarily of π* (NO)orbitals, and the main contribution of the spin magnetic moment comes from the π* (NO) orbitals. By comparison, wefind that the GGA is more suitable to describe free radical systems than LSDA. 相似文献
172.
Finite chains of a two-state random Potts spin model with periodic boundary conditions are studied within Glauber dynamics. The spin exchange is assumed random with frustration between ferro and antiferromagnetic values (±J). Time-dependent fluctuations are induced by periodic temperature oscillations. Master type differential equations for spin correlation functions are solved within linear response theory. The spectrum of relaxation times are calculated at different temperatures. The ±J Potts glass chains undergo a zero temperature phase transition. The barriers against inversion of the spin chain take only two values; 0 and 2|J|. The temperature behaviour of specific heat is characterized by rounded peaks. The frequency dependence displays two plateaus for the real part of specific heat and two corresponding peaks for the imaginary part. The dynamic specific heat is not affected by the longest relaxing mode like susceptibility. The time separation of the modes is demonstrated by the Cole-Cole plots. 相似文献
173.
L Guangshi School of Mathematics System Sciences Shandong University Jinan China. 《数学年刊B辑(英文版)》2005,(2)
§1. IntroductionIn the additive theory of prime numbers, one studies the representation of positive in-tegers by powers of primes. For the quadratic case, Hua [1] proved that each large integercongruent to 5 modulo 24 can be written as the sum of ?ve squ… 相似文献
174.
Adsorption of argon and nitrogen at their respective boiling points in cylindrical pores of MCM-41 type silica-like adsorbents is studied by means of a non-local density functional theory (NLDFT), which is modified to deal with amorphous solids. By matching the theoretical results of the pore filling pressure versus pore diameter against the experimental data, we arrive at a conclusion that the adsorption branch (rather than desorption) corresponds to the true thermodynamic equilibrium. If this is accepted, we derive the optimal values for the solid-fluid molecular parameters for the system amorphous silica-Ar and amorphous silica-N2, and at the same time we could derive reliably the specific surface area of non-porous and mesoporous silica-like adsorbents, without a recourse to the BET method. This method is then logically extended to describe the local adsorption isotherms of argon and nitrogen in silica-like pores, which are then used as the bases (kernel) to determine the pore size distribution. We test this with a number of adsorption isotherms on the MCM-41 samples, and the results are quite realistic and in excellent agreement with the XRD results, justifying the approach adopted in this paper. 相似文献
175.
The graded Hecke algebra for a finite Weyl group is intimately related to the geometry of the Springer correspondence. A
construction of Drinfeld produces an analogue of a graded Hecke algebra for any finite subgroup of GL(V). This paper classifies all the algebras obtained by applying Drinfeld's construction to complex reflection groups. By giving
explicit (though nontrivial) isomorphisms, we show that the graded Hecke algebras for finite real reflection groups constructed
by Lusztig are all isomorphic to algebras obtained by Drinfeld's construction. The classification shows that there exist
algebras obtained from Drinfeld's construction which are not graded Hecke algebras as defined by Lusztig for real as well
as complex reflection groups.
Received: July 25, 2001 相似文献
176.
We apply a method analogous to the eikonal approximation to the Maxwell wave equations in an inhomogeneous anisotropic medium and geodesic motion in a three dimensional Riemannian manifold, using a method which identifies the symplectic structure of the corresponding mechanics, to the five dimensional generalization of Maxwell theory required by the gauge invariance of Stueckelberg's covariant classical and quantum dynamics. In this way, we demonstrate, in the eikonal approximation, the existence of geodesic motion for the flow of mass in a four dimensional pseudo-Riemannian manifold. These results provide a foundation for the geometrical optics of the five dimensional radiation theory and establish a model in which there is mass flow along geodesics. We then discuss the interesting case of relativistic quantum theory in an anisotropic medium as well. In this case the eikonal approximation to the relativistic quantum mechanical current coincides with the geodesic flow governed by the pseudo-Riemannian metric obtained from the eikonal approximation to solutions of the Stueckelberg–Schrödinger equation. The locally symplectic structure which emerges is that of a generally covariant form of Stueckelberg's mechanics on this manifold. 相似文献
177.
This paper studies a supply chain consisting of two suppliers and one retailer in a spot market, where the retailer uses the
newsvendor solution as its purchase policy, and suppliers compete for the retailer’s purchase. Since each supplier’s bidding
strategy affects the other’s profit, a game theory approach is used to identify optimal bidding strategies. We prove the existence
and uniqueness of a Nash solution. It is also shown that the competition between the supplier leads to a lower market clearing
price, and as a result, the retailer benefits from it. Finally, we demonstrate the applicability of the obtained results by
deriving optimal bidding strategies for power generator plants in the deregulated California energy market.
Supported in part by RGC (Hong Kong) Competitive Earmarked Research Grants (CUHK4167/04E and CUHK4239/03E), a Distinguished
Young Investigator Grant from the National Natural Sciences Foundation of China, and a grant from Hundred Talents Program
of the Chinese Academy of Sciences. 相似文献
178.
Y.Charles Li 《Journal of Mathematical Analysis and Applications》2004,292(1):311-315
Isospectral problem of both 2D and 3D Euler equations of inviscid fluids, is investigated. Connections with the Clay problem are described. Spectral theorem of the Lax pair is studied. 相似文献
179.
Noninferior Nash Strategies for Multi-Team Systems 总被引:1,自引:0,他引:1
This paper is concerned with the optimization of systems that are controlled by several teams of decision makers. The decision makers within each team cooperate for the benefit of their team. On the other hand, the teams compete among themselves in order to achieve an objective that relates to the overall performance of the system. An approach that merges concepts from team theory and game theory for dealing with such systems and a solution called the noninferior Nash strategy are introduced. This multi-team solution provides a new framework for analyzing hierarchically controlled systems so as to address complicated coordination problems among the decision makers. The properties of the noninferior Nash solution in static multi-team systems are investigated and necessary conditions for its existence are derived. Analytical expressions for the noninferior Nash strategies are derived for a class of linear-quadratic static multi-team games. In order to deal with the issue of nonuniqueness of the solution, the concept of a noninferior Nash strategy with a team leader is introduced. Several examples are presented to illustrate the results. 相似文献
180.
Ya.G. Groda P. Argyrakis G.S. Bokun V.S. Vikhrenko 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,32(4):527-535
The selfconsistent diagram approximation (SCDA) is generalized for three-dimensional lattice gases with nearest neighbor repulsive
interactions. The free energy is represented in a closed form through elementary functions. Thermodynamical (phase diagrams,
chemical potential and mean square fluctuations), structural (order parameter, distribution functions) as well as diffusional
characteristics are investigated. The calculation results are compared with the Monte Carlo simulation data to demonstrate
high precision of the SCDA in reproducing the equilibrium lattice gas characteristics. It is shown that similarly to two-dimensional
systems the specific statistical memory effects strongly influence the lattice gas diffusion in the ordered states.
Received 7 August 2002 / Received in final form 22 January 2003 Published online 24 April 2003 相似文献