Resistive switching polymer materials based on poly(aryl ether)s containing triphenylamine and 1,2,4‐triazole moieties

A series of poly(aryl ether)s were successfully prepared via aromatic nucleophilic substitution reaction from various bisphenols and a novel bipolar aryl difluoride monomer containing electron‐donor triphenylamine and electron‐acceptor 1,2,4‐triazole moieties. The poly(aryl ether)s exhibited excellent solubility in organic solvents such as dimethylformamide, chloroform, and tetrahydrofuran at room temperature. The poly(aryl ether)s showed high thermal stability with T_d10 higher than 500 °C and glass transition temperatures (T_g) higher than 187 °C. The thin films of the poly(aryl ether)s indicated bistable resistive switching behavior with ON/OFF current ratios as high as 10³. The switching on and switching off bias voltages of the poly(aryl ether)s were affected by the bisphenol moiety. The good resistive switching behavior of the poly(aryl ether)s made them promising candidates for future nonvolatile memory applications. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6861–6871, 2008     

Silver microgrid transparent conductive electrode based on bulk plasmon effect for ultraviolet wavelength application

Silver microgrid/TiO₂/ITO (indium tin oxide glass) sandwich‐structure photodetectors with various pore sizes are fabricated by a microsphere lithography strategy. This ultraviolet (UV) detector possesses ohmic contact characteristics. The high UV transmittance results from an enhanced bulk plasmon effect of the silver microgrid electrode. Photoelectric properties of the sandwich structure with various pore sizes are discussed. The short transport distance of carriers and the low blocking of incoming UV light are the main reasons of the high activity for silver microgrid/TiO₂/ITO sandwich‐structure photodetectors. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Evaluation of Transparent Optical Network Performance in Presence of Incoherent Homodyne Crosstalk

Abstract

A simple method to evaluate the performance of transparent optical networks (TON) that takes into account the incoherent homodyne crosstalk, signal distortion, inter-symbol interference (ISI), amplified spontaneous emission (ASE) noise, and arbitrary optical and electrical filters is proposed. This method combines the effect of the incoherent homodyne crosstalk with an exhaustive Gaussian approximation for the influence of ASE noise, signal distortion, and ISI. It is shown that the incoherent homodyne crosstalk penalty depends on the ASE noise accumulated in the TON, ISI, and extinction ratio. The proposed method estimates are compared with experimental results published by other authors. Good agreement is observed for one, two, and four incoherent homodyne crosstalk signals, revealing that the proposed method provides accurate estimates even when the methods based on a Gaussian approximation for the incoherent homodyne crosstalk fail. The proposed method is used to assess the performance of a TON composed by optical add-drop multiplexers based on arrayed waveguide gratings. Results reveal that incoherent homodyne crosstalk, ASE noise, and ISI impair the TON performance and, therefore, none can be neglected in the TON design.     

Al- and Al:In-Doped ZnO Thin Films Deposited by RF Magnetron Sputtering for Spacecraft Charge Mitigation

We investigate the utility of impurity-doped ZnO as charge-mitigating thin films for spacecraft in geosynchronous orbit. Satellite solar panel cover glass and thermal control blankets are commonly coated in tin-doped indium oxide which serves as a leakage path for accumulated surface charge. The increase in demand for indium has generated interest in alternative space-stable satellite coatings. We demonstrate the orbital stability of Al- and Al:In-doped ZnO exposed to a high-energy electron flux and simulated solar ultraviolet (UV) radiation.     

Digital Nonlinear Metasurface with Customizable Nonreciprocity

Recently, investigation of metasurface has been extended to nonreciprocity through breaking time‐reversal symmetry. Among a number of magnetless strategies, nonlinearity is an important nonreciprocal principle amenable to the metasurface. As passive analog‐based devices, most of the existing nonlinear nonreciprocal metasurfaces are inherently characterized by the relatively unchangeable performance, sharp frequency response, and hysteresis loops. Here, an analog–digital–analog mechanism is proposed to realize the nonlinear nonreciprocity, which provides a digitally reconfigurable solution for a family of nonreciprocal performance within a shared hardware architecture. This concept is validated by a metasurface prototype with the integration of a digital module at microwave frequencies. Based on the proposed mechanism, the properties can be customized as demanded, ranging from a normal reciprocal response to a variety of nonreciprocal functions, including electromagnetic (EM) diode and EM unidirectional limiting functions, which have been experimentally demonstrated with direction reversibility and threshold tunability. The proposed metasurface is also underpinned by the nonhysteretic performance and wide operating bandwidth, thereby potentially making it an inexpensive and stable candidate for advanced manipulations of EM waves.     

Enhanced Thermal Transport across Self-Interfacing van der Waals Contacts in Flexible Thermal Devices

Minimizing the thermal contact resistance (TCR) at the boundary between two bodies in contact is critical in diverse thermal transport devices. Conventional thermal contact methods have several limitations, such as high TCR, low interfacial adhesion, a requirement for high external pressure, and low optical transparency. Here, a self-interfacing flexible thermal device (STD) that can form robust van der Waals mechanical contact and low-resistant thermal contact to planar and non-planar substrates without the need for external pressure or surface modification is presented. The device is based on a distinctive integration of a bioinspired adhesive architecture and a thermal transport layer formed from percolating silver nanowire (AgNW) networks. The proposed device exhibits a strong attachment (maximum 538.9 kPa) to target substrates while facilitating thermal transport across the contact interface with low TCR (0.012 m² K kW⁻¹) without the use of external pressure, thermal interfacial materials, or surface chemistries.     

绒面ZnO透明导电薄膜

采用孪生ZnO (Al2 O3 ∶2 % )对靶直流磁控溅射制备高透过率、高电导率的平面ZnO薄膜 (迁移率为 5 .5 6cm2 /V·s,载流子浓度为 4 .5 7× 10 2 0 cm-3 ,电阻率为 2 .4 6× 10 -3 Ω·cm ,可见光范围 (380～ 80 0nm)平均透过率大于 85 % )。用酸腐蚀的方法 ,可以获得绒面效果 ,而反应气压对绒面效果没有影响 ,薄膜的电学特性没有变化 ,绒面对光散射作用增强 ,导致相对于平面ZnO薄膜的透过率要低一些 (可见光范围平均透过率大于 80 % )。     

机械磨抛对CdZnTe薄膜阻变特性的影响

采用磁控溅射法在ITO玻璃上制备了CdZnTe薄膜,探究机械磨抛对CdZnTe薄膜阻变特性的影响。通过对XRD图谱、Raman光谱、AFM显微照片等实验结果分析阐明了机械磨抛影响CdZnTe薄膜阻变特性的物理机制。研究结果表明,磁控溅射制备的薄膜为闪锌矿结构,F43m空间群。机械磨抛提高了CdZnTe薄膜的结晶质量;CdZnTe薄膜粗糙度(Ra)由磨抛前的3.42 nm下降至磨抛后的1.73 nm;磨抛后CdZnTe薄膜透过率和162 cm^-1处的类CdTe声子峰振动峰增强;CdZnTe薄膜的阻变开关比由磨抛前的1.2增加到磨抛后的4.9。机械磨抛提高CdZnTe薄膜质量及阻变特性的原因可能是CdZnTe薄膜在磨抛过程中发生了再结晶。     

Eu:Lu2O3透明闪烁陶瓷的制备与性能

采用湿化学法合成了Eu原子掺量5%的Lu₂O₃陶瓷前驱体,通过SEM、XRD研究了煅烧前后前驱体和1 100 ℃煅烧4 h后粉体的形貌、结构以及物相。结果表明煅烧后的粉体为纳米类球形、高分散且结晶性良好的颗粒。颗粒尺寸为68.5 nm。使用煅烧后的粉体为原料,在1 650 ℃真空烧结30 h制备了高透过率的Eu:Lu₂O₃陶瓷,晶粒尺寸为46 μm,在611 nm处的直线透过率可以达到66.3%。此外对陶瓷的吸收曲线、光致激发和发射光谱特性以及X射线激发发射光谱进行研究。可观察到,Eu:Lu₂O₃陶瓷存在基质和激活离子两类吸收,光致发光光谱和X射线激发发射光谱均可以看出Eu:Lu₂O₃陶瓷存在极强的⁵D₀→⁷F₂跃迁发光,位于611 nm处。对比商业的BGO单晶的X射线发射光谱,可得本实验中制备的陶瓷的光输出为85 000 ph/MeV。Eu:Lu₂O₃陶瓷本身有着高X射线以及高能粒子的阻止能力,结合高光输出特性,表明Eu:Lu₂O₃陶瓷在X射线成像等领域具有巨大的潜在应用价值。     

声学超表面的非对称声分束特性研究

非对称声分束超表面是由人工微单元结构按照特定序列构建的二维平面结构,可将垂直入射的声波分成两束传播方向和分束比自由调控的透射波,在声功能器件设计及声通信领域具有广泛的应用前景.本文系统研究了一种实现非对称声分束的设计理论和实现方法,基于局域声功率守恒条件研究了声分束器的设计理论、阻抗矩阵分布、法向声强分布、声压场分布等...