全文获取类型
收费全文 | 3516篇 |
免费 | 786篇 |
国内免费 | 533篇 |
专业分类
化学 | 1749篇 |
晶体学 | 158篇 |
力学 | 116篇 |
综合类 | 19篇 |
数学 | 150篇 |
物理学 | 1271篇 |
无线电 | 1372篇 |
出版年
2024年 | 18篇 |
2023年 | 80篇 |
2022年 | 121篇 |
2021年 | 162篇 |
2020年 | 152篇 |
2019年 | 153篇 |
2018年 | 124篇 |
2017年 | 131篇 |
2016年 | 192篇 |
2015年 | 180篇 |
2014年 | 222篇 |
2013年 | 397篇 |
2012年 | 230篇 |
2011年 | 236篇 |
2010年 | 179篇 |
2009年 | 220篇 |
2008年 | 236篇 |
2007年 | 205篇 |
2006年 | 227篇 |
2005年 | 204篇 |
2004年 | 190篇 |
2003年 | 144篇 |
2002年 | 123篇 |
2001年 | 85篇 |
2000年 | 87篇 |
1999年 | 72篇 |
1998年 | 67篇 |
1997年 | 63篇 |
1996年 | 54篇 |
1995年 | 42篇 |
1994年 | 40篇 |
1993年 | 35篇 |
1992年 | 34篇 |
1991年 | 18篇 |
1990年 | 17篇 |
1989年 | 21篇 |
1988年 | 16篇 |
1987年 | 12篇 |
1986年 | 5篇 |
1985年 | 11篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 4篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有4835条查询结果,搜索用时 671 毫秒
71.
Survila A. Mockus Z. Kanapeckaitė S. Jasulaitienė V. 《Russian Journal of Electrochemistry》2004,40(8):855-859
Voltammetry and x-ray photoelectron spectroscopy data show micromolar amounts of halides to noticeably affect co-deposition of copper and tin from acidic sulfate solutions containing polyether Laprol 2402C as the surface-active substance. The reduction of Cu(II) slows down and that of Sn(II) accelerates in the series Cl– < Br– < I–. Compounds on the surface of bronze coatings are oxides of Cu(I) and Sn(II) and halides of Cu(I). 相似文献
72.
73.
SyntheticinterestsinhighlyfunctionalizedacyclicandcyclicamineshavecontributedtothewealthofexPerimentalmethodologydeveloPedfortheadditionofcarbanionstothecarbon-nitrogendoublebondofimines.Generally,organometallicreagentsorilltermedi-atesareusedascarbanionsandadditionofallylicorganometallicspeciestothenieconshtutesavaluablemethodforthesynthesisofhomoallylamines.'Amongthese,allyLlithium,'-magnesium,'-zinc,'-boraneandboronate,'-silaneand-stannane'havebeenusedforallylationofdriines.Ontheotherhand,… 相似文献
74.
75.
Synthesis of the Stannatetraphospholanes (tBuP)4SnR2 (R = tBu, nBu, C6H5) and (tBuP)4Sn(Cl)nBu Molecular and Crystal Structure of (tBuP)4Sn(tBu)2 The reaction of the diphosphide K2[tBuP-(tBuP)2-PtBu] 4 with the halogenostannanes (tBu)2SnCl2, (nBu)2SnCl2, (C6H5)2SnCl2 or nBuSnCl3 in a molar ratio of 1 : 1 leads via a [4 + 1]-cyclocondensation reaction to the stannatetraphospholanes (tBuP)4SnR2 3 b–3 d and (tBuP)4Sn(Cl)nBu 3 e , respectively, with the binary 5-membered P4Sn ring system. 3 b was characterized by a single crystal structure analysis; the 5-membered ring exists in a planar conformation. The compounds 3 b–3 e were identified by NMR and also by mass spectroscopy; the 31P{1H}-NMR spectra of 3 b–3 d showed an AA′MM′ (AA′MM′X), 3 e on the other hand an ABCD (ABCDX) spin system. 相似文献
76.
研究了真空条件下SnMe4在MCM-41分子筛表面的接枝反应,并用元素分析、ICP、GC-MS、XRD、FTIR、DRS、13C及119Sn MAS NMR、XPS、BET、TPD、TPR等方法对产物的组成、结构和性质进行了表征.结果表明, 两者可以定量地进行化学反应,将确定数目的甲基锡基团接枝在分子筛表面, 形成SnMe3/MCM-41物种;接枝反应发生在分子筛表面上, 不破坏MCM-41分子筛骨架结构;改性分子筛的BET比表面积有所降低,孔体积变小, 表面性质发生变化.四甲基锡在MCM-41上接枝反应的温度为343 K,比它与HY沸石的反应温度(193 K)高得多,并且产物SnMe3/MCM-41的热稳定性也高于SnMe3/HY. 相似文献
77.
Gar B. Hoflund Steven D. Gardner David R. Schryer Billy T. Upchurch Erik J. Kielin 《Reaction Kinetics and Catalysis Letters》1996,58(1):19-26
The influence of promoters on Pt/SnOx/SiO2 and Au/MnOx low-temperature CO oxidation catalysts has been investigated under stoichiometric reaction conditions with no CO2 added to the feed gas. The performance of Pt/SnOx/SiO2 catalysts is improved significantly by the addition of 1 wt.% Fe but reduced by the addition of 5 wt.%Fe, 1 wt.% Sb, 5 wt.% Sb, 1 wt.% As, 5 wt.%As and 1.8 wt.% P. The performance of Au/MnOx is improved significantly by the addition of 1 at.% Ce but reduced by the addition of 1 at.% Co. For the catalysts and conditions examined, the Au/MnOx catalysts are superior to the Pt/SnOx/SiO2 catalysts with respect to both activity and decay characteristics. 相似文献
78.
Francesco S. Gentile Alexander Platonenko Khaled E. El-Kelany Michel Rérat Philippe D'Arco Roberto Dovesi 《Journal of computational chemistry》2020,41(17):1638-1644
The infrared (IR) and Raman spectra of eight substitutional carbon defects in silicon are computed at the quantum mechanical level by using a periodic supercell approach based on hybrid functionals, an all electron Gaussian type basis set and the CRYSTAL code. The single substitutional C s case and its combination with a vacancy (C sV and C sSiV) are considered first. The progressive saturation of the four bonds of a Si atom with C is then examined. The last set of defects consists of a chain of adjacent carbon atoms C, with i = 1–3. The simple substitutional case, C s, is the common first member of the three sets. All these defects show important, very characteristic features in their IR spectrum. One or two C related peaks dominate the spectra: at 596 cm−1 for C s (and C sSiV, the second neighbor vacancy is not shifting the C s peak), at 705 and 716 cm−1 for C sV, at 537 cm−1 for C and C (with additional peaks at 522, 655 and 689 for the latter only), at 607 and 624 cm−1, 601 and 643 cm−1, and 629 cm−1 for SiC, SiC, and SiC, respectively. Comparison with experiment allows to attribute many observed peaks to one of the C substitutional defects. Observed peaks above 720 cm−1 must be attributed to interstitial C or more complicated defects. 相似文献
79.
80.
R.K.B GoverN.D. Withers S. AllenR.L. Withers J.S.O. Evans 《Journal of solid state chemistry》2002,166(1):42-48
SnP2O7 is a member of the ZrP2O7 family of materials, several of which show unusual thermal expansion behavior over certain temperature ranges and which show a number of displacive phase transitions on cooling from high temperature. Here we describe the structural properties of SnP2O7 from 100 to 1243 K as determined by X-ray and neutron powder diffraction. These studies reveal that SnP2O7 shows two phase transitions in this temperature range. At room temperature the material has a pseudo-cubic 3×3×3× superstructure. Electron diffraction studies show that the symmetry of this structure is P213 or lower. On warming to ∼560 K it undergoes a phase transition to a structure in which the subcell reflections show a triclinic distortion; above 830 K the subcell reflections show a rhombohedral distortion. Significant hysteresis in cell parameters is observed between heating and cooling. The structure of SnP2O7 is discussed with references to other members of the AM2O7 family of materials. 相似文献