多排叶片内部流动以及叶片排与排气系统相互作用研究

本文采用高分辨率格式和多块多网格方法求解雷诺平均Navier-Stokes方程,数值模拟多排叶片内的三维粘性流动;使用数值激盘模拟叶片排的存在,研究叶片排与非轴对称排气部件之间的相互作用以及复杂的内部流动。文中描述了数值方法,给出了NASA透平导叶和单级透平内部流场的数值结果及其与相应实验结果的对比,也给出了多级透平内部流场的数值结果,以及透平与排气部件之间的耦合流场的结果。     

Dihalodimethyltin(IV) complexes of 2‐(pyrazol‐1‐ylmethyl)pyridine

Reaction of dichloro‐ and dibromodimethyltin(IV) with 2‐(pyrazol‐1‐ylmethyl)pyridine (PMP) afforded [SnMe₂Cl₂(PMP)] and [SnMe₂Br₂(PMP)] respectively. The new complexes were characterized by elemental analysis and mass spectrometry and by IR, Raman and NMR (¹H, ¹³C) spectroscopies. Structural studies by X‐ray diffraction techniques show that the compounds consist of discrete units with the tin atom octahedrally coordinated to the carbon atoms of the two methyl groups in a trans disposition (Sn? C = 2.097(5), 2.120(5) Å and 2.110(6), 2.121(6) Å in the chloro and in the bromo compounds respectively), two cis halogen atoms (Sn? Cl = 2.4908(16), 2.5447(17) Å; Sn? Br = 2.6875(11), 2.7464(9) Å) and the two donor atoms of the ligand (Sn? N = 2.407(4), 2.471(4) Å and 2.360(5), 2.455(5) Å). In both cases, the Sn? N(pyridine) bond length is markedly longer than the Sn? N(pyrazole) distance. Copyright © 2003 John Wiley & Sons, Ltd.     

Electrochemical behavior of Li intercalation processes into a Li[NixLi(1/3−2x/3)Mn(2/3−x/3)]O2 cathode

Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂ (X=0.17, 0.25, 0.33, 0.5) compounds are prepared by a simple combustion method. The Rietvelt analysis shows that these compounds could be classified as having the α-NaFeO₂ structure. The initial charge-discharge and irreversible capacity increases with the decrease of x in Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂. Indeed, Li[Ni_0.50Mn_0.50]O₂ compound shows relatively low initial discharge capacity of 200 mAh/g and large capacity loss during cycling, with Li[Ni_0.17Li_0.22Mn_0.61]O₂ and Li[Ni_0.25Li_0.17Mn₀.₅₈]O₂ compounds exhibit high initial discharge capacity over 245 mAh/g and stable cycle performance in the voltage range of 4.8 -2.0 V. On the other hand, XANES analysis shows that the oxidation state of Ni ion reversibly changes between Ni²⁺ and about Ni³⁺, while the oxidation state of Mn ion sustains Mn⁴⁺ during charge-discharge process. This result does not agree with the previously reported ‘electrochemistry model’ of Li[Ni_xLi_(1/3−2x/3)Mn_(2/3−x/3)]O₂, in which Ni ion changes between Ni²⁺ and NI⁴⁺. Based on these results, we modified oxidation-state change of Mn and Ni ion during charge-discharge process.     

ZnSe棱镜折叠波导CO_2激光器的研究

研制了使用ZnSe棱镜折叠的波导CO_2激光器,提出一种CO_2激光—He-Ne激光调整光路的方法,并获得了该种折叠激光器的振荡。进一步的改进可以提高其输出功率而得到实用性的器件。     

光照下meso-四(4-磺基苯基)卟啉(H_2TPPS)形成锌配合物的光-极谱研究

在氨性溶液中,光照射对ZnTPPS的形成影响很大。光-极谱试验表明:光电流(i_p)与浓度(c)间有以下的关系:对Zn(NH_3)_4~(2+),i_p∝C_((Zn)(NH_3)_4)~(2+)_~(1/2),对H_2TPPS,i_p∝C_(H_2TPPS),ZnTPPS络合物还原波的i_p不明显。本文对其差异性和光电流产生的原因做了初步探讨。     

A Hilbert Space Approach to Bounded Analytic Interpolation

We generalize several results on bounded analytic interpolation of Fitzgerald and Horn, which work by majorization by positive definite kernels, to the cases of several complex variables and operator-valued interpolation. Using a lemma of Kolmogorov, we complement a simplification due to Szafraniec in the proofs of the theorems. Received: November 21, 2006. Accepted: August 03, 2007.     

On the bidirectional vortex and other similarity solutions in spherical coordinates

The bidirectional vortex refers to the bipolar, coaxial swirling motion that can be triggered, for example, in cyclone separators and some liquid rocket engines with tangential aft-end injectors. In this study, we present an exact solution to describe the corresponding bulk motion in spherical coordinates. To do so, we examine both linear and nonlinear solutions of the momentum and vorticity transport equations in spherical coordinates. The assumption will be that of steady, incompressible, inviscid, rotational, and axisymmetric flow. We further relate the vorticity to some power of the stream function. At the outset, three possible types of similarity solutions are shown to fulfill the momentum equation. While the first type is incapable of satisfying the conditions for the bidirectional vortex, it can be used to accommodate other physical settings such as Hill’s vortex. This case is illustrated in the context of inviscid flow over a sphere. The second leads to a closed-form analytical expression that satisfies the boundary conditions for the bidirectional vortex in a straight cylinder. The third type is more general and provides multiple solutions. The spherical bidirectional vortex is derived using separation of variables and the method of variation of parameters. The three-pronged analysis presented here increases our repertoire of general mean flow solutions that rarely appear in spherical geometry. It is hoped that these special forms will permit extending the current approach to other complex fluid motions that are easier to capture using spherical coordinates.     

纳米β-Ni(OH)2与球型Ni(OH)2的热性能比较研究

用配位沉淀法合成出纳米级Ni（OH）2，并对其进行XRD，TEM，DSC分析，分析结果表明，所得纳米β-Ni（OH）2为可用作电极材料的β-Ni（OH）2，粒径为30－40nm，且热分解温度比普通球镍低10℃左右，摩尔分解热比普通球镍低4－7kJ，从理论上分析了产生此现象的原因。     

热传导型半导体瞬态问题特征变网格有限元法及其分析

热传导型半导体器件的瞬时状态由四个方程的非线性偏微分方程组的初边值问题所决定，其中电子位势方程是椭圆型的，电子和空穴浓度方程是对流扩散型的，温度方程为热传导型的。本文提出解这类问题的特征变网格有限元法，并进行了理论分析，在一定条件下，得到了某种意义下的最佳L^2误差估计结果。     

The spectrum of BSA(v, 3, λ; α) with α = 2,3

In this article, a kind of auxiliary design BSA^* for constructing BSAs is introduced and studied. Two powerful recursive constructions on BSAs from 3‐IGDDs and BSA^*s are exploited. Finally, the necessary and sufficient conditions for the existence of a BSA(v, 3, λ; α) with α = 2, 3 are established. © 2006 Wiley Periodicals, Inc. J Combin Designs 15: 61–76, 2007