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1.
乌桕类可可脂结晶过程中表现体积变化 总被引:1,自引:0,他引:1
为了解乌桕类可可脂(CTCBE)缓冷结晶横向胀罐爆裂原因,研究CTCBE结晶过程中的膨胀特性,采用流体静力法测试了不同等温结晶条件下CTCBE结晶形成的表观密度和表观体积及其横纵向膨胀状况。结果表明,CTCBE缓冷结晶后形成外部和中部两个晶区。在5-25℃的各等温结晶范围内,当结晶温度增加时,外部结晶区域减小、表观密度变化不大;中部结晶区域增大、表观密度明显减小,CTCBE的表观体积、横向、纵向膨胀率均增大,膨胀横向大于纵向。进一步表明CTCBE在自然缓冷固化的表观体积根本上由其结晶温度决定。为有效防止横向胀罐,自然缓冷固化温度应低于10℃。 相似文献
2.
The reversible nonlinear conduction (RNC) in of high‐density polyethylene/acetylene carbon black composites with different degrees of crosslinking was studied above room temperature and below the melting point of high‐density polyethylene (HDPE). The experimental current density‐electric field strength curves can be overlapped onto a master curve, suggesting that the microscopic mechanisms for the appearance of RNC exist regardless of the ambient temperature and the crosslinking degree of the HDPE matrix. The relationship between the crossover current density and the linear conductivity can be explained in the framework of the dynamic random‐resistor‐network model. According to these results, two electron‐tunneling models are suggested to interpret the microscopic conduction behavior. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1212–1217, 2004 相似文献
3.
Kangseok Lee Sang Eun Shim Byung H. Lee Seong Uk Hong Soonja Choe 《Journal of Polymer Science.Polymer Physics》2004,42(6):1114-1126
The desorption behavior of a surfactant in a linear low‐density polyethylene (LLDPE) blend at elevated temperatures of 50, 70, and 80 °C was studied with Fourier transform infrared spectroscopy. The composition of the LLDPE blend was 70:30 LLDPE/low‐density polyethylene. Three different specimens (II, III, and IV) were prepared with various compositions of a small molecular penetrant, sorbitan palmitate (SPAN‐40), and a migration controller, poly(ethylene acrylic acid) (EAA), in the LLDPE blend. The calculated diffusion coefficient (D) of SPAN‐40 in specimens II, III, and IV, between 50 and 80 °C, varied from 1.74 × 10?11 to 6.79 × 10?11 cm2/s, from 1.10 × 10?11 to 5.75 × 10?11 cm2/s, and from 0.58 × 10?11 to 4.75 × 10?11 cm2/s, respectively. In addition, the calculated activation energies (ED) of specimens II, III, and IV, from the plotting of ln D versus 1/T between 50 and 80 °C, were 42.9, 52.7, and 65.6 kJ/mol, respectively. These values were different from those obtained between 25 and 50 °C and were believed to have been influenced by the interference of Tinuvin (a UV stabilizer) at elevated temperatures higher than 50 °C. Although the desorption rate of SPAN‐40 increased with the temperature and decreased with the EAA content, the observed spectral behavior did not depend on the temperature and time. For all specimens stored over 50 °C, the peak at 1739 cm?1 decreased in a few days and subsequently increased with a peak shift toward 1730 cm?1. This arose from the carbonyl stretching vibration of Tinuvin, possibly because of oxidation or degradation at elevated temperatures. In addition, the incorporation of EAA into the LLDPE blend suppressed the desorption rate of SPAN‐40 and retarded the appearance of the 1730 cm?1 peak. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1114–1126, 2004 相似文献
4.
Tae Young Kim Dong Myung Kim Won Jung Kim Tae Hee Lee Kwang S. Suh 《Journal of Polymer Science.Polymer Physics》2004,42(15):2813-2820
The effect of the triblock copolymer poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] (SEBS) on the formation of the space charge of immiscible low‐density polyethylene (LDPE)/polystyrene (PS) blends was investigated. Blends of 70/30 (wt %) LDPE/PS were prepared through melt blending in an internal mixer at a blend temperature of 220 °C. The amount of charge that accumulated in the 70% LDPE/30% PS blends decreased when the SEBS content increased up to 10 wt %. For compatibilized and uncompatibilized blends, no significant change in the degree of crystallinity of LDPE in the blends was observed, and so the effect of crystallization on the space charge distribution could be excluded. Morphological observations showed that the addition of SEBS resulted in a domain size reduction of the dispersed PS phase and better interfacial adhesion between the LDPE and PS phases. The location of SEBS at a domain interface enabled charges to migrate from one phase to the other via the domain interface and, therefore, resulted in a significant decrease in the amount of space charge for the LDPE/PS blends with SEBS. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2813–2820, 2004 相似文献
5.
6.
A. N. Iyer U. Balachandran L. R. Motowidlo J. G. Hoehn P. Haldar 《Journal of Electronic Materials》1994,23(11):1087-1091
Pb0.4Bi1.8Sr2Ca2.2Cu3Ox (Bi-2223) precursor powder was prepared by a solid-state reaction of carbonates and oxides of lead, bismuth, strontium, calcium,
and copper, and the powder was then used to fabricate silver-clad tapes by the powder-in-tube technique. Transport critical
current density (Jc) values>4×104 A/cm2 at 77K and 2×105 A/cm2 at 4.2 and 27K have been achieved in short tape samples. Long lengths of tape were tested by winding them into pancake coils.
Recently, we fabricated a test magnet by stacking ten pancake coils, each containing three 16m lengths of rolled tape, and
tested it at 4.2, 27 and 77K. A maximum generated field of 2.6 T was measured in zero applied field at 4.2K and the test magnet
generated significant self-field in background fields up to 20 T. The results are discussed in this paper. 相似文献
7.
A. Goyal E. D. Specht Z. L. Wang D. M. Kroeger J. A. Sutliff J. E. Tkaczyk J. A. Deluca L. Masur G. N. Riley 《Journal of Electronic Materials》1994,23(11):1191-1197
Microstructural origins for reduced weak-link behavior in high-Jc melt-processed YBCO, spray pyrolyzed thick films of Tl-1223, metallic precursor Y-124 polycrystalline powder-in-tube (PIT)
wires and PIT Bi-2212/2223 are discussed. Since the materials studied are the highest Jc, polycrystalline, high-Tc superconductors fabricated worldwide, the results provide important guidelines for further improvements in superconducting
properties, thereby enabling practical applications of these materials. It is found that strongly linked current flow within
domains of melt-processed 123 occurs effectively through a single crystal path. In c-axis oriented, polycrystalline Tl-1223
thick films, local in-plane texture has been found to play a crucial role in the reduced weak-link behavior. Formation of
“colonies” of grains with a common c-axis and modest in-plane misorientation was observed. Furthermore, a colony boundary
in general has a varying misorientation along the boundary. Large regions comprised primarily of low angle boundaries were
observed. Percolative transport through a network of such small angle boundaries appears to provide the nonweak-linked current
path. Although powder-in-tube BSCCO 2212 and 2223 also appear to have a “colony” microstructure, there are some important
differences. Colonies in BSCCO consist of stacks of grains with similar c-axis orientation in contrast to colonies in Tl-1223
films where few grains are stacked on top of one another. Furthermore, most grains within a colony in BSCCO have the same
lateral dimensions as that of the colony, resulting largely largely in “twist” boundaries. Further microstructural characterization
of high-Jc PIT 2212 and 2223 is currently underway. In the case of Y-124 wires, weak macroscopic in-plane texture is found. Additional
measurements are underway to determine if a sharper, local in-plane texture also exists. It is found that in three of the
four types of superconductors studied, reduced weak-link behavior can be ascribed to some degree of biaxial alignment between
grains, either on a “local” or a “global” scale. 相似文献
8.
本文目的在于建立确定R ̄d中Hausdorff维数dim和packing维数Dim的两个命题(定理1和定理2),进而寻求R ̄d中Hausdorff维数dim与packing维数Dim相等的条件;这使得我们能够引入分形测度的测度论定义。 相似文献
9.
Ginette Ratovo Jean‐Pierre Souchard Pascale Urizzi Yvon Coulais Franoise Nepveu Etienne Hollande 《应用有机金属化学》2004,18(1):1-8
Pancreatic cancer has an extremely poor prognosis, due, in part, to lack of methods for early diagnosis. The present study was designed to evaluate the potential of labeling low‐density lipoprotein (LDL) with a radionuclide using a lipid chelating agent, bis(stearylamide) of diethylenetriaminepentaacetic acid (L), to detect pancreatic tumors by gamma‐scintigraphy. Previous studies indicated that the difficulty of visualization of pancreatic tumors was due to their poor vascularization. This study compares the ability of two radiotracers, 111In–L–LDL and 153Gd–L–LDL to target highly vascularized rat pancreatic tumors (AR4‐2J) implanted in nude mice. Biodistribution studies showed that the tumor uptake of 111In–L–LDL and 153Gd–L–LDL tracers was twofold and fivefold higher respectively than with the controls (111In citrate and 153Gd citrate respectively). These tracers would thus be suitable for scintigraphic imaging. We show here that LDL could be employed as a delivery system for tracers such as 111In or 153Gd when these two radionuclides are complexed by a lipid‐chelating anchor, and that 111In–L–LDL and 153Gd–L–LDL enabled better visualization of the pancreatic tumor tissues, with a better result with 153Gd–L–LDL. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
10.