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101.
102.
M. Gutowski I. Dabkowska J. Rak S. Xu J.M. Nilles D. Radisic K.H. Bowen Jr 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,20(3):431-439
The photoelectron spectra (PES) of anions of uracil-glycine and uracil-phenylalanine complexes reveal broad features with
maxima at 1.8 and 2.0 eV. The results of ab initio density functional B3LYP and second order M?ller-Plesset theory calculations indicate that the excess electron occupies a
π* orbital localized on uracil. The excess electron attachment to the complex can induce a barrier-free proton transfer (BFPT)
from the carboxylic group of glycine to the O8 atom of uracil. As a result, the four most stable structures of the anion of
uracil-glycine complex can be characterized as the neutral radical of hydrogenated uracil solvated by the anion of deprotonated
glycine. The similarity between the PES spectra for the uracil complexes with glycine and phenylalanine suggests that the
BFPT is also operative in the case of the latter anionic species. The BFPT to the O8 atom of uracil may be related to the
damage of nucleic acid bases by low energy electrons because the O8 atom is involved in a hydrogen bond with adenine in the
standard Watson-Crick pairing scheme.
Received 6 April 2002 Published online 13 September 2002 相似文献
103.
We study the propagation of the light mesons σ,ω,ρ, and a0(980) in dense hadronic matter in an extended derivative scalar coupling model. Within the scheme proposed it is possible
to unambiguously define effective density-dependent couplings at the Lagrangian level. We first apply the model to study asymmetric
nuclear matter with fixed isospin asymmetry, and then we pay particular attention to hypermatter in β-equilibrium. The equation
of state and the potential contribution to the symmetry coefficient arising from the mean-field approximation are investigated.
Received: 16 October 2001 / Accepted: 10 January 2002 相似文献
104.
N.-K. Lee T.A. Vilgis 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,28(4):451-465
We study the elastic properties of single A/B random copolymer chains, with a specific sequence and use them as theoretical
model for so called HP proteins. HP proteins carry hydrophilic (P) and hydrophobic (H) monomers. We predict a rich structure
in the force-extension relations which can be attributed to the information in the sequence. The variational method is used
to probe local minima on the path of stretching and releasing for the chain molecules. At a given force, we find multiple
configurations which are separated by energy barriers. A collapsed globular configuration consists of several domains which
unravel cooperatively. Upon stretching, the unfolding path shows a stepwise pattern corresponding to the unfolding of each
domain. While releasing, several cores can be created simultaneously in the middle of the chain, resulting in a different
path of collapse. The long-range interactions and stiffness of the chain simplify the potential landscape given by the disorder
in sequence.
Received 5 March 2002 / Received in final form 16 May 2002 Published online 13 August 2002 相似文献
105.
3d-metal antimonides: Fe1+x Sb, N+x Sb, Co+x Sb and the (Ni1?y Fe y )Sb solid solution have been studied by the Mössbauer effect method at 57Fe and 119Sn. It was found that the quadrupole interactions at the Fe and Sn nucleus in 3d-metal antimonides are very sensitive to the filling of different crystallographic sites with metal atoms. The metal atoms in trigonal-bipyramidal sites have a strong effect on the quadrupole splitting of 119Sn. They are nearest to anions (Sb or Sn) with the typical axial ratio of c/a = 1.25. The QS(x) dependence of 119 Sn in 3d-metal antimonides in the 0 ≤ x ≤ 0.1 concentration range can be used to determine x – the concentration of transition metal excess relative to the stoichiometric composition. 相似文献
106.
We show that the tenure lengths for managers of sport teams follow a power law distribution with an exponent between 2 and 3. We develop a simple theoretical model which replicates this result. The model demonstrates that the empirical phenomenon can be understood as the macroscopic outcome of pairwise interactions among managers in a league, threshold effects in managerial performance evaluation, competitive market forces, and luck at the microscopic level. 相似文献
107.
高固体分羟基丙烯酸树脂的合成 总被引:1,自引:0,他引:1
以过氧化二苯甲酰(BPO)/过氧化二异丙苯(DCP)(质量比为2:3)为复合引发剂,二甲苯为溶剂,选用适量含羟基单体和分子量调节剂,以减缓树脂合成聚合反应中的自动加速现象,合成了分子量为3000-4000,多分散性指数d〈2的高固体分羟基丙烯酸树脂.该树脂与缩二脲多异氰酸酯(HDI)的配漆实验证明,所得漆膜鲜映性好、丰满度高、色泽好、雾影值低、综合性能较好. 相似文献
108.
We have investigated the free energy of formation for AgxIn1-x and AgxSn1-x liquid binary alloys at temperatures 1173 and 1250 K, respectively. A microscopic theory based on the first order perturbation has been applied. The interionic interaction and a reference liquid are the fundamental components of the theory. The interionic interaction is described by a local pseudopotential. A liquid of hard spheres (HS) of two different effective diametres and charges is used to describe the reference system. The results of the calculations for energy of formation agree very well with the available experimental data. Our calculations also reveal that a simple perturbative approach along with appropriate effective pair potentials can produce nearly quantitative results for the concerned alloys. 相似文献
109.
Hans J. Fahr 《Foundations of Physics Letters》2006,19(5):423-440
According to ideas of Mach, Whitrow, Dirac, or Hoyle, inertial masses of particles should not be a genuine, predetermined
quantity; rather they should represent a relational quantity which by its value somehow reflects the deposition and constellation
of all other objects in their cosmic environment. In this paper we want to pick up suggestions given by Thirring and by Hoyle
of how, due to requirements of the equivalence of rotations and of general relativistic conformal scale invariance, the particle
masses of cosmic objects should vary with the cosmic length scale. We study cosmological consequences of comoving cosmic masses
which co-evolve by mass with the expansion of the universe. The vanishing of the covariant divergence of the cosmic energy-momentum
tensor under the new prerequisite that matter density only falls off with the reciproke of the squared cosmic scale S(t) then leads to the astonishing result that cosmic pressuredoes not fall off adiabatically but rather falls off in a quasi-isothermal
behaviour, varying with S(t) as matter density does. Hence, as a new cosmological fact, it arises that, even in the late phases of cosmic expansion,
pressure cannot be neglected what concerns its gravitational action on the cosmic dynamics. We then show that under these
conditions the cosmological equations can, however, only be solved if, in addition to matter, also pressure and energy density
of the cosmic vacuum are included in the calculation. An unaccelerated expansion with a Hubble parameter falling off with
S(t)−1 is obtained for a vacuum energy density decay according to S(t)−2 with a well-tuned proportion of matter and vacuum pressures. As it appears from these results, a universe with particle masses
increasing with the cosmic sale S(t) is in fact physically conceivable in an energetically consistent manner, if vacuum energy at the expansion of the universe
is converted into mass density of real matter with no net energy loss occuring. This universe in addition also happens to
be an economical one which has and keeps a vanishing total energy. 相似文献
110.
E. Liénard G. Ban J. Blieck D. Durand F. Duval X. Fléchard M. Herbane M. Labalme Y. Lemière F. Mauger A. Méry O. Naviliat-Cuncic D. Rodríguez J. C. Thomas 《Hyperfine Interactions》2006,172(1-3):29-33
We report on the status of the LPCTrap experiment, devoted to measure the β–ν angular correlation in the pure Gamow–Teller
decay of 6He. This measurement is motivated by the search for the presence of tensor type contributions to the weak interaction. The
6He ions are confined in a novel transparent Paul trap. The β particles and the recoil ions are detected in coincidence to
deduce the angular correlation parameter. The commissioning run performed in 2005 has given the proof of principle of this
experiment. Up to 105 coincidences were recorded during a second run in 2006. 相似文献