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951.
Nhat Anh Thi Thieu Minh Canh Vu Dae Hoon Kim Won Kook Choi Sung‐Ryong Kim 《先进技术聚合物》2020,31(10):2351-2359
The composites comprising vertically aligned network of copper nanowires (CuNWs) in the presence of cellulose nanofibers were fabricated by using the freeze‐templating method and the effect of aspect ratio (A/R) of CuNWs on the thermal conductivity of epoxy composites was investigated. The thermal conductivity of epoxy composites increased to 0.79 W m?1 K?1 at 1.12 vol% of high A/R CuNWs loading, corresponding to the thermal conductivity enhancement of 365% as compared to the pure epoxy. The thermal conductivity of vertically aligned higher A/R CuNWs/epoxy, which is 38.5% and 51.9% higher than those of the lower A/R CuNWs and the randomly aligned CuNWs, respectively. The application of the epoxy composites in heat dissipation was demonstrated by the temperature changes of composites on a hot plate with the increase of heating time. These results indicate that the thermally conductive composites in this study could be applied for thermal dissipating materials in electronic devices. 相似文献
952.
953.
Fatma KARA Duygu ADIGÜZEL Ufuk ATMACA Murat ELK Jale NAKTYOK 《Turkish Journal of Chemistry》2020,44(6):1483
A humic substance was obtained from hazelnut husk using an alkali extraction. The chemical and morphological structure of the humic matter was characterized via elemental analysis, Fourier transform infrared spectrometry (FTIR), nuclear magnetic resonance, Brunauer-Emmet-Teller (BET) analysis, scanning electron microscopy (SEM), and thermogravimetric-FTIR (TG-FTIR). In addition, thermal analysis measurements TG analysis-differential thermogravimetry/differential scanning calorimetry (TGA-DTG/DSC) were performed under dynamic air conditions to better determine the origin, physical and chemical structure, and decomposition process of the humic matter. The Kissinger-Akahira-Sunose (KAS) and Flynn-Wall-Ozawa (FWO) methods were used to calculate the kinetic parameters of the high-temperature decomposition process. It was observed that the activation energy values were almost constant at certain conversion and temperature intervals. In addition, the structure of the humic substance at different temperatures was also investigated via FTIR analysis. It was found that the obtained humic substance had a very stable structure and decomposed at a high temperature. The stability of the humic matter can be a useful tool in the environmental quality research of soil. 相似文献
954.
955.
Dongxu Yan Jing Chen Hongpeng Jia 《Angewandte Chemie (International ed. in English)》2020,59(32):13562-13567
Single‐atom noble metals on a catalyst support tend to migrate and agglomerate into nanoparticles owing to high surface free energy at elevated temperatures. Temperature‐induced structure reconstruction of a support can firmly anchor single‐atom Pt species to adapt to a high‐temperature environment. We used Mn3O4 as a restructurable support to load single‐atom Pt and further turned into single‐atom Pt‐on‐Mn2O3 catalyst via high‐temperature treatment, which is extremely stable under calcination conditions of 800 °C for 5 days in humid air. High‐valence Pt4+ with more covalent bonds on Mn2O3 are essential for anchoring isolated Pt atoms by strong interaction. An optimized catalyst formed by moderate H2O2 etching exhibits the best performance and excellent thermal stability of single‐atom Pt in high‐temperature CH4 oxidation on account of more exposed Pt atoms and strong Pt‐Mn2O3 interaction. 相似文献
956.
当调制电子束入射进空间等离子体时,由于电子束本征电磁场在非均匀等离子体中的散射(渡越辐射transition radiation)或者电子束的纵向约束性可以产生电磁波辐射.基于这两种辐射机制,研究了半无界调制电子束从航天器入射进平面分层各向同性非均匀空间等离子体产生的电磁波辐射.结果表明,由背景等离子体非均匀性产生的电磁波辐射强度高于由束的纵向约束性引起的辐射强度通过对电子束的适当调制,可以满足辐射电磁波在局部等离子体谐振区域的共振条件,从而增大辐射强度.研究结果可用于对主动空间等离子体试验数据的分析. 相似文献
957.
地震电磁前兆研究进展 总被引:34,自引:4,他引:30
强震前存在地震电磁异常现象已被大量强震震例所证实,在我国地震电磁前兆已成为地震短临预测的有效手段.地震电磁短临前兆主要包括:地磁场、地电场、电磁辐射、电离层、高能粒子等与地震孕育发生有关的各种异常现象.地震短临电磁前兆及其机理极为复杂,有来自震源信息的局部性前兆,有来自震源所在的区域应力场构造前兆以及与孕震立体环境有关的大尺度动态前兆.孕震过程中产生的电磁效应及其相关现象,通过化学途径、声学途径、电磁途径向空中传播,研究岩石圈-大气层-电离层耦合现象,有利于进一步加深对地震电磁前兆及其机理的认识.发射地震电磁卫星形成天地一体化的监测体系,将促进地震电磁科学研究和地震预测领域的发展. 相似文献
958.
Ioakim K. Spiliopoulos John A. Mikroyannidis 《Journal of polymer science. Part A, Polymer chemistry》1996,34(13):2799-2807
Various unsaturated polyamides and polyesters were prepared from the reactions of 1,4-bis(2-carboxyvinyl)benzene acid chloride with aromatic diamines and bisphenols, respectively. In addition, various unsaturated homo- and copolyesters were synthesized from 4-hydroxycinnamic acid and 4-hydroxybenzoic acid. They were heat-cured to thermally stable resins. The polymers were characterized by inherent viscosity measurements, FT-IR, x-ray, DTA, TMA, TGA, and isothermal gravimetric analysis. The water absorption as well as the solubility behavior of the polymers was also investigated. © 1996 John Wiley & Sons, Inc. 相似文献
959.
Toru Doi Akira Akimoto Akikazu Matsumoto Takayuki Otsu 《Journal of polymer science. Part A, Polymer chemistry》1996,34(3):367-373
Radical copolymerization of N-methylmaleimide (MeMI) as well as other N-alkylmaleimides (RMI) and isobutene (IB) was carried out with 2,2′-azobis(isobutyronitrile) as an initiator at 60°C. The initial rate of the copolymerization (Rp) was dependent on the monomer composition and was maximum at the 40 mol % of MeMI in the feed. A solvent effect on the Rp and the monomer reactivity ratio was observed in this copolymerization system, i.e., copolymerization in chloroform produced a higher Rp and an alternating tendency compared with those in dioxane (rMeMI = 0.14, r1B = 0 in chloroform and rMeMI = 0.47, r1B = 0 in dioxane). The alternating copolymer of RMI and IB shows a high glass transition temperature (Tg) and excellent thermal stability, e.g., the Tg and the thermal decomposition temperature (Td) were 152 and 363°C, respectively, for the alternating copolymer of MeMI and IB. Both the Tg and Td increased as the concentration of the MeMI unit in the copolymers increased. Colorless transparent sheets were obtained from press molding the alternating copolymers. They showed excellent mechanical and optical properties. © 1996 John Wiley & Sons, Inc. 相似文献
960.