Mechanical and thermal properties of green polylactide composites with natural fillers

Green composites of PLA with micropowders derived from agricultural by-products such as oat husks, cocoa shells, and apple solids that remain after pressing have been prepared by melt mixing. The thermal and mechanical properties of the composites, including the effect of matrix crystallization and plasticization with poly(propylene glycol), have been studied. All fillers nucleated PLA crystallization and decreased the cold-crystallization temperature. They also affected the mechanical properties of the compositions, increasing the modulus of elasticity but decreasing the elongation at break and tensile impact strength although with few exceptions. Plasticization of the PLA matrix improved the ductility of the composites.     

Evaluation of the aerobic composting process of winery and distillery residues by thermal methods

The possibility of using thermal analysis for a quick characterization of chemical changes was tested in the organic matter from composting materials. Differential thermal analysis (DTA), thermogravimetry (TG) and the first derivative of the TG (DTG) were calculated in oxidizing conditions on compost samples obtained from three composting piles. The composting piles were made by mixing winery and distillery residues with sewage sludge (pile 1), with cow manure (pile 2) and hen droppings (pile 3). The temperature values in the pile 1 showed a different evolution during the thermophilic stage of the composting process in relation to the piles 2 and 3. The thermophilic stage for pile 1 was 17 days, meanwhile for the piles 2 and 3 were around 80 and 110 days, respectively, and probably pile 1 was not well composted. The curves of ion current of CO₂ have been recorded in order to shed light on changes occurring in organic matter during composting. Particularly DTG curves allowed us to distinguish between well (piles 2 and 3) and poor (pile 1) stabilized organic matter. The energy released was calculated for each sample by integrating the DTA curves and these results are agreed with the previous hypothesis. Information deriving from weight losses, registered by the TG and DTG curves, enables to follow the evolution state of the organic matter and therefore changes in its stability. These data could determine the final point of the composting process of winery and distillery residues and then reduce the time for compost harvest.     

金刚石衬底上GaN HEMT沟道温度建模:各向异性且非均匀热导率的影响

为了改善GaN HEMT的自热效应,集成高热导率的金刚石衬底有助于增强器件有源区的热量耗散。然而,化学气相淀积(CVD)生长的多晶金刚石(PCD)具有柱状晶粒结构,导致了各向异性的材料热导率,且其热导率值与生长厚度有关。为此,通过建模金刚石生长过程中晶粒尺寸的演变过程,计算了金刚石沿面内和截面方向的热导率。基于该PCD热导率模型,利用计入材料非线性热导率的GaN器件热阻解析模型,计算得到了GaN HEMT沟道温度的波动范围,并分析了其与器件结构(栅长、栅宽、栅间距、衬底厚度)和功耗的依赖关系。最后,通过与有限元(FEM)仿真结果对比,分区域提取了GaN HEMT器件中PCD衬底的有效热导率,分别为260~310 W/(m·K)和1 250~1 450 W/(m·K)。本文的计算为预测金刚石衬底上GaN HEMT器件的沟道温度提供了快速、有效的方法。     

热壁条件下油气的热着火现象

设计了高温热壁油气热着火实验系统,对受限空间油气混合气体在热壁条件下的热着火现象进行了实验研究。根据实验结果,详细讨论了油气混合物的着火方式、临界着火温度、着火压力范围以及体积分数、温度的变化规律。实验发现:热壁条件下油气混合物引燃分为油蒸气的热裂解-油气快速氧化反应-油气急速氧化反应3个阶段;油气混合物着火模式为燃烧、热爆燃和热爆炸;油气在汽油自燃点附近开始快速化学反应,热着火临界温度高于汽油自燃点近80 K;温度特征曲线在着火时具有突变性质;热壁温度达到783～873 K时,存在压力范围为2.2～17.6 kPa的三角形油气热着火压力半岛。     

滚滑工况弹流反常温度场的研究

研究了弹流反常温度场的形成机理及影响因素，指出入口温升是压缩功发热和逆流剪切热所致，而出口局部低温是负压缩功吸热的结果，出口温度的再次微幅上升则是压缩功消失后剪切热作用的结果．研究结果表明，入口温升随载荷的增加而增大，随卷吸速度的增加显著升高而几乎与滑滚比无关；在高速小滑滚比工况下，接触区的最高温度有可能出现在入口位置；入口温升增加了材料在工作中经受高温的次数，对其接触疲劳寿命有不利影响；在保证润滑性能的前提下，适当减少供油量可以减小逆流，从而降低入口温升。     

电子封装、QFP和MCM热变形的实验及数值分析

0Introduction Anelectronicpackageisgenerallyconstructedwithanactivesiliconchip,mountisland,gold wires,leadframesandsoldersasshowninFig.1(a).Toprotectfromtheenvironment,thesilicon chipisusuallyencapsulatedinresin.SincethesematerialshavedifferentCTE(coeffic…     

The pentacene films on the glass/ITO surface: structure and optical properties

Abstract

The structure, morphology and optical transmittance spectra of pentacene films on the (glass/ITO) surface were studied. The films were grown by two methods - the thermal vacuum deposition (TVD) and pulsed laser deposition (PLD). The electron diffraction pattern from thermally deposited pentacene films confirms their polycrystalline structure while the diffraction pattern of PLD-coated layers has a diffusion character. The results obtained showed that layers deposited by the TVD method has an optical spectrum that is characteristic for the pentacene film in contrary to the layers deposited by the PLD method. It is found a sensitivity of the optical transmittance of pentacene films to the ammonia action, which may be used for development the optical gas sensor.     

快速热点火熔奥梯铝炸药燃烧转爆轰实验研究

以熔铸型含铝混合炸药熔奥梯铝为对象,研究铸装含铝混合炸药快速热点火后的燃烧转爆轰特性。建立了快速热点火燃烧转爆轰实验平台,由实验装置(加热装置、约束钢管、炸药)、压力测试系统、光纤测速系统组成;加热装置加热15 mm厚45钢钢板,峰值温度大于1 100℃,温升速率为85～95℃/s。开展了快速热点火带壳熔奥梯铝炸药燃烧转爆轰实验,由加热装置加热约束钢管内熔奥梯铝炸药,炸药化学反应阵面压力和传播速度分别由压电性高压压力传感器和光纤探针测定;实测阵面压力约1 GPa,传播速度最大约2 600 m/s。由光纤数据获得炸药化学反应阵面传播轨迹,通过特征线方法获得冲击形成点,半定量给出冲击形成距离大于850 mm;并比较了管体破片质量实测值与炸药完全爆轰时破片平均质量计算值,实测值远小于计算值。综合实测化学反应阵面传播速度和压力、冲击形成距离分析、破片质量比较,可确定熔奥梯铝炸药没有发生完全爆轰,其化学反应状态为爆燃。另外,采用Adams和Pack模型、CJ燃烧模型,都能够半定量的预估冲击形成距离和燃烧波后压力,为实验设计提供依据,但CJ燃烧模型的计算结果更接近于实测值。     

Dynamic and Isothermal Thermogravimetric Degradation of Poly(vinyl Chloride)/Chlorinated Poly(ethylene) Blends

The thermal degradation of poly(vinyl chloride)/chlorinated poly(ethylene) (PVC/CPE) blends of different compositions was investigated by means of dynamic and isothermal thermogravimetric analysis in flowing atmosphere of nitrogen. Kinetic parameters (the apparent activation energy E, and pre-exponential factor Z) were calculated after Flynn-Wall-Ozawa method for the first stage of dynamic degradation of PVC/CPE blends, and after Flynn method for the isothermal degradation. In both cases, there is the compensation dependence between the values E and logZ. The values of compensation ratios as well as the characteristics of TG and DTG curves, confirm the stabilizing effect of CPE on PVC dehydrochlorination. This revised version was published online in July 2006 with corrections to the Cover Date.     

Synthesis,Structure and Thermal Property of a Cobalt Supramolecular Complex Containing N-[（4-Carboxyphenyl）-sulfonyl]glycine

Utilizing N-[(4-carboxyphenyl)-sulfonyl]glycine (abbreviated as cbsglyH3),a new cobalt complex [Co(cbsglyH)(bipy)2]3H2O (bipy = 2,2'-bipyridine) has been synthesized under mild conditions and characterized by IR,elemental analysis,thermogravimetric analysis and X-ray diffraction analysis. It crystallizes in the monoclinic system,space group C2/c with a = 34.978(3),b = 12.0437(11),c = 20.0041(19) ,β = 122.2990(10)°,V = 7123.0(11) 3,Z = 8,C29H28CoN5O9S,Mr = 681.55,μ = 0.593 mm-1,Dc = 1.271 Kg/m3,F(000) = 2816,the final R = 0.0434 and wR = 0.1351. The title complex is a monomeric compound which is further assembled by intermolecular hydrogen bonds into a 3-D supramolecular network. Thermogravimetric analysis illustrates that this complex begins decomposing at 100 ℃ and decompounding completely at 560 ℃.