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31.
锌和锡参与下末端环氧化物的选择性烯丙基化反应 总被引:1,自引:0,他引:1
烯丙基溴和金属辛或锡成功地将末端环氧化合物1一锅法合成高烯丙基醇2和双高烯丙基醇3. 还研究了环氧化合物取代基的影响, 并提出了此烯丙基化的反应途径 . 相似文献
32.
A simple Ni(dppe)Cl2/Ag2O combination has been established as an efficient catalyst system for the homo-coupling of aromatic terminal alkynes. This reaction proceeds under mild conditions and can be applied to alkynone substrates. Various aromatic 1,3-diynes were obtained in good to excellent yields. 相似文献
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34.
A series of controllable amphiphilic block copolymers composed of poly(ethylene oxide)(PEO) as the hydrophilic block and poly(ε-caprolactone)(PCL) as the hydrophobic block with the amino terminal group at the end of the PEO chain(PCL-b-PEO-NH2) were synthesized.Based on the further reaction of reactive amino groups,diblock copolymers with functional carboxyl groups(PCL-b-PEO-COOH) and functional compounds RGD(PCL-b-PEO-RGD) as well as the triblock copolymers with thermosensitive PNIPAAm blocks(PCL-b-PEO-b-P... 相似文献
35.
T. V. Gryaznova Yu. G. Budnikova O. G. Sinyashin 《Russian Journal of Electrochemistry》2007,43(10):1151-1155
An alternative approach to synthesis of electrophilic terminal phosphinidene complexes of tungsten pentacarbonyl with various substituents at the phosphorus atom has been developed. The approach is based on the reaction of the electrochemically generated tungsten pentacarbonyl ion with trivalent phosphorus acyl chlorides. Electrochemical reduction of ethyldichlorophosphines in the presence of α-diimines is a one-step process that forms 1,3,2-diazaphospholenes containing an exocyclic P-C bond. 相似文献
36.
A new one-dimensional copper coordination polymer chain has been prepared and fully characterized by single-crystal X-ray diffraction,elemental analyses and IR spectroscopy. The compound {[Cu2(C2O4)2(inta)4](inta)}n1 crystallizes in the triclinic system,space group P1,with a=8.4722(5),b=10.9825(6),c=11.6128(6),α=104.8050(10),β=102.5740(10),γ= 109.6890(10)o,V=927.18(9)3,Mr=929.79,Z=1,Dc=1.665 g/cm3,F(000)=475,μ=1.231 mm-1,R=0.0453 and wR=0.1185 for 3290 observed reflections (I > 2σ(I)). Of the compound,the Cu center is octahedrally coordinated with oxalate acting as a tetra-dentate ligand coordinated to the copper atom and each inta serving as a terminal ligand by employing only one N-donor to coordinate with the Cu center. An infinite {Cu2(C2O4)2}∞ chain is formed along the c axis. Furthermore,the 1D chains are held together via extensive hydrogen-bonding interactions to generate a three-dimensional network with 1D channels (ca. 5.491×11.507) where inta molecules are filled. 相似文献
37.
Pondikpa Nadjombé Mamatchi Mélila Hodabalo Kamou Essossimna Magamana Annemieke Verbeken K. Atsu Guelly 《印度化学会志》2022,99(6):100407
In order to contribute to the valorisation of wild fungi whose nutritional potential, although considerable, is not sufficiently known in some countries such as Togo, a study has been carried out on Russula species. The diversity of Russula species from Alédjo Wildlife Reserve has been assessed using a focused inventory in woodlands dominated by Isoberlinia doka Craib & Stapf, Isoberlinia tomentosa (Harms) Craib & Stapf, Monotes kerstingii Gilg, Uapaca togoensis Pax and gallery forests dominated by Berlinia grandiflora (Vahl) Hutch & Dalz and Uapaca guineensis Müll. Ethnomycological surveys have been carried out among Tém and Kabyè, two riparian ethnic groups that are mainly represented. Biochemical analyses have been carried out using the AOAC method. Fifteen (15) taxa of edible Russula species are commonly used by Tém and Kabyè people living along the Alédjo Wildlife Reserve among which thirteen (13) taxa have been identified up to species level. R. oleifera is eaten by all interviewed people in both sociolinguistic groups (Fr = 100%) followed by R. compressa (Fr = 92.31%), R. ochrocephala (Fr = 87.18%) among Tém people and R. ochrocephala (Fr = 91.67%), R. compressa (Fr = 83.33%) among Kabyè people. Five (05) new species of edible Russula have been identified for the first time in Togo. The Russula species analysed have been rich in macronutrients with contents ranging from 2.88 g/100 g of dw for fat to 65.83 g/100 g of dw for total carbohydrates. In addition, these Russula species have shown a relatively high mineral content with contents ranging from 405.70 mg/100 g of dw for Ca to 2784 mg/100 g of dw for K. Furthermore, the results have revealed that Russula species analysed are a source of energy with 309.50 Kcal/100 g of dw. The edible Russula species analysed can thus contribute to food security in Togo. 相似文献
38.
该文对苯二氮类和吩噻嗪类镇静安眠药样品的红外光谱数据进行采集,构建了不同数据分类模型并对比了不同波段光谱数据集对其分析准确率的影响。结果表明,借助贝叶斯判别分析的基于全波段数据集的二阶导数模型分类效果优于其他单一模型,对于苯二氮类和吩噻嗪类两个不同类型精神药物的总体分类准确率达92.7%。借助贝叶斯判别分析的基于全波段和指纹区融合数据集的二阶导数融合模型分类效果最佳,对苯二氮类和吩噻嗪类两个不同类型精神药物的总体分类准确率达到100%;对苯二氮类和吩噻嗪类中不同种类精神药物的总体分类准确率则分别达到96.7%和100%。该研究实现了不同类型及同一类型不同种类镇静安眠药的快速准确定性分析,为此类管制类药物走私案件的准确定性提供了一定的技术支持。 相似文献
39.
The title compound, [Mn4O2(O2CMe)6(MeOH)2(dbm)2]·2MeCOOH·2CH2Cl2 (Hdbm = dibenzoylmethane), has been synthesized and structurally determined by single-crystal X-ray diffraction. The crystal belongs to triclinic, space group P(-l), with a = 10.729(3), b = 12.269(3), c =13.085(4) (A), a = 106.367(3), β = 107.643(2), γ = 94.771(2)°, V = 1547.9(7) (A)3, Z = 1,C50H64Cl4Mn4O24, Mr= 1410.57, Dc= 1.513 g/em3, F(000) = 724, Rint = 0.0147, T = 293(2) K and μ = 1.046 mm-1. The fimal R = 0.0359 and wR = 0.0938 for 5791 observed reflections with I > 2( )I).The structure of the complex consists of one [Mn4(μ3-O)2]8+ core with four coplanar Mn atoms disposed in an extended "butterfly-like" arrangement and two O atoms triply bridging each "wing",and the peripheral ligation is provided by six μ2-MeCO2-, two terminalμ2-dbm- groups at the two hydrogen bonding interactions are found within the structure of the compound. 相似文献
40.