Synthesis and Characterization of a Novel Calix[4]arene‐Based Periodic Mesoporous Organosilica

Summary: A new calix[4]arene‐based periodic mesoporous organosilica has been synthesized using tetraethoxysilane (TEOS) and a calix[4]arene‐based silane monomer as the precursors and cetyltrimethylammonium bromide (CTAB) surfactant as the structure‐directing template, and is shown to be capable of visual detection and entrapment of NO₂.

Synthesis of the novel mesoporous organosilica material containing covalently bound tetra‐O‐alkylated calix[4]arene hosts.     

基于小波变换的多尺度图像匹配算法

文中针对基于梯度算子的图像匹配方法通常存在的问题———收敛速度较慢、迭代易落入局部最优点,提出了一种基于小波变换的多尺度图像匹配算法。这一算法利用小波的良好的多尺度特征,先对低分辨率的子图像做匹配,将得到的结果作为初始值用于高分辨率图像的匹配运算,匹配运算都在位移矢量场上进行。实验表明该方法可节省计算时间,且减小迭代落入局部最优点的概率,算法鲁棒性得以提高。     

模板剂在分子筛合成过程中的作用机理

启用分子模拟途径,通过Lennard-Jones势对模板剂分子与分子筛骨架间非成键作用的能学分析,论证n=5、6的双季铵盐［(CH₃)₃N(CH₂)_nN(CH₃)₃］Br₂在ZSM-50分子筛骨架合成过程中所起的模板作用。     

Effect of Templates on the Structure and Stability of Ti-TMS

Mesoporousmaterialsareofgreatinteresttocatalysisbecauseoftheirlargeanduniformporesize(20~100A),whichallowstereo-hinderedmoleculesfacilediffusiontointernalactivesites.Althoughrecenteffectshavesuggestedthatitshouldbepossibletosynthesizemesoporousmateri...     

A POLYNOMIAL ALGORITHM FOR FINDING THE MINIMUM FEEDBACK VERTEX SET OF A 3-REGULAR SIMPLE GRAPH

1IntroductionLetG=(VE)beaconnectedsimplegraph.AsubsetFofvertexsetViscalIedafeedbackvertexsetofGifthegraPhGFisaf0rest.ThecardinaIity0faminimumfeedbackvertexset0fGisdenotedbyf(G).AvertexsubsetJofvertexsetViscaJledallonseparatingindependentsetofG,ifJisanilldependentsetofVandGJisconnected.Thema-xiammcardinalityofnollseparatingindependelltsetofGisden0tedbyz(G)andiscalledthenonseparatingindepelldentnumberofG,AgraphGiscalledacactusifGisc0nnectedandanytwocyclesofGaredisjoint.Avertexvofacon…     

Stable Marriage and Genetic Algorithms: A Fertile Union

We describe a pair of genetic algorithms for solving two stable matching problems. Both stable matching problems we will consider involve a set of applicants for positions and a set of employers. Each applicant and each employer prepares a rank order list of a subset of the actors in the other set. The goal is to find an assignment of applicants to employers in which if applicant a is not assigned to employer b then either a prefers his assignment to b or b prefers its assignment toa . In other words, no applicant/employer pair can both improve their situations by dropping their current assignments in favor of each other. Our goal will be to enumerate the stable matchings. One of the problems we will consider is the well-known stable marriage problem, in which neither applicant nor employer preference lists are linked. In the other problem, we will allow pairs of applicants who form a couple to submit joint rank order lists of ordered pairs of employers.     

相位匹配法在毛细管波导中产生高次谐波的分析

在理论上研究了超短强激光脉冲与毛细管中惰性气体相互作用产生高次谐波的最佳相位匹配条件,在计算中发现了特定级次 相位匹配中截止驱动光强的存在。分析表明要想使高次谐波获得相位匹配,需要超短脉宽的驱动脉冲以及电离能大的气体工作介质。讨论了毛细管波导中的强场高次谐波选择性并指出了改善谐波选择性的措施。     

微波消解ICP-AES法测定高速工具钢中锰、磷、镍、铜、铬、钒

高速工具钢为高碳高合金工具钢,常温下样品酸溶分解较为困难。本文利用微波消解提高溶样的温度和压力,在王水、氢氟酸和硫酸介质中使样品充分消解,再用饱和硼酸溶液络合过量的氢氟酸,基体匹配消除铁基体的影响,ICP-AES法同时测定锰、磷、镍、铜、铬、钒的含量。测定高速工具钢标样,测定值与标样值相吻合,本方法的精密度在0.55%～4.06%。加标回收率在95.6%～114.8%,满足测定要求。     

Novel molecularly hybridized polyethylene/silica composite materials: Polymerization of ethylene with supported titanocenes by mesoporous silicates

A novel molecularly hybridized polyethylene/silica composite thin film was obtained by the gas‐phase polymerization of ethylene with a titanocene‐mounted mesoporous silica layer on a mica plate with mesoscopic pores arranged on the film surface. However, the use of titanocene‐mounted hexagonal domains of mesoporous silica on a glass plate for the gas‐phase polymerization of ethylene resulted in the formation of an islanded polyethylene/silica hybridized material. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 4821–4825, 2000     

On the number of partial Steiner systems

We give a simple proof of the result of Grable on the asymptotics of the number of partial Steiner systems S(t,k,m). © 2000 John Wiley & Sons, Inc. J Combin Designs 8: 347–352, 2000