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81.
Yu Na Lim Soo Kyung Chae Woongbin Yim Ji‐Yong Park Woojin Yoon Hoseop Yun Eunha Kim Seung Uk Son Hye‐Young Jang 《应用有机金属化学》2019,33(3)
The reaction of [(domppp) Pd (OAc)2] [domppp = 1,3‐bis (di‐o‐methoxyphenylphosphino)propane] and imidazolium‐functionalized carboxylic acids containing various anions (Br?, PF6?, SbF6? and BF4?) resulted in the formation of nano‐sized Pd (II) aggregates under template‐free conditions. The rate of formation of aggregates can be modulated by changing the anion, affecting the rate of polymerization of CO and olefins without fouling. Herein, we describe the analysis of Pd (II) catalysts by dynamic light scattering, atomic force microscopy, X‐ray photoelectron spectroscopy and X‐ray crystallography, and co‐ and terpolymerization results including the catalytic activity, and bulk density and molecular weight of polymers. 相似文献
82.
Ultrathin Mn Doped Ni-MOF Nanosheet Array for Highly Capacitive and Stable Asymmetric Supercapacitor
Dengchao Zheng Hao Wen Xun Sun Xin Guan Jie Zhang Wenli Tian Hao Feng Dr. Hongjing Wang Prof. Yadong Yao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(71):17149-17155
In this study, we demonstrate that an Mn-doped ultrathin Ni-MOF nanosheet array on nickel foam (Mn0.1-Ni-MOF/NF) serves as a highly capacitive and stable supercapacitor positive electrode. The Mn0.1-Ni-MOF/NF shows an areal capacity of 6.48 C cm−2 (specific capacity C: 1178 C g−1) at 2 mA cm−2 in 6.0 m KOH, outperforming most reported MOF-based materials. More importantly, it possesses excellent cycle stability to maintain 80.6 % capacity after 5000 cycles. An asymmetric supercapacitor device utilizing Mn0.1-Ni-MOF/NF as the positive electrode and activated carbon as the negative electrode attains a high energy density of 39.6 Wh kg−1 at 143.8 Wkg−1 power density with a capacitance retention of 83.6 % after 5000 cycles. 相似文献
83.
Anuja Datta Pedro E. Sanchez‐Jimenez Yonatan Calahorra Canlin Ou Suman‐Lata Sahonta Marco Fornari Sohini Kar‐Narayan 《Advanced functional materials》2017,27(29)
Ferroelectrics are important technological materials with wide‐ranging applications in electronics, communication, health, and energy. While lead‐based ferroelectrics have remained the predominant mainstay of industry for decades, environmentally friendly lead‐free alternatives are limited due to relatively low Curie temperatures (T C) and/or high cost in many cases. Efforts have been made to enhance T C through strain engineering, often involving energy‐intensive and expensive fabrication of thin epitaxial films on lattice‐mismatched substrates. Here, a relatively simple and scalable sol–gel synthesis route to fabricate polycrystalline (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 nanowires within porous templates is presented, with an observed enhancement of T C up to ≈300 °C as compared to ≈90 °C in the bulk. By combining experiments and theoretical calculations, this effect is attributed to the volume reduction in the template‐grown nanowires that modifies the balance between different structural instabilities. The results offer a cost‐effective solution‐based approach for strain‐tuning in a promising lead‐free ferroelectric system, thus widening their current applicability. 相似文献
84.
Nano to micro-sized patterns were formed on a flexible polymer substrate using a flexible UV imprint stamp. A 6 in. diameter flexible UV nanoimprint template was fabricated using PVC hot embossing and DLC coating. Using the UV nanoimprint process with the DLC coated PVC template, nano to micro-sized patterns were clearly formed on the flexible PET substrate without a residual layer, due to the antistiction properties and high mechanical hardness of the DLC coating. By depositing a Cr layer on the imprinted resist pattern and lifting it off, Cr metal patterns were fabricated on the PET substrate. 相似文献
85.
86.
对空中目标物体实时跟踪目前主要采用雷达探测的方法,但时常会受到电磁场与电磁波的干扰,降低了探测的准确性,为解决此类问题,提出了一种基于空中视觉实时跟踪系统的解决方案.该方案适用于小范围空中动态物体的跟踪,包括动态目标的差值提取,二值图像的滤波和模板图像的实时更新,以及动态目标的特征提取、云台控制.为提高系统的准确检测性,提出了一种基于改进的动态模板匹配与帧间差分相结合的空中目标检测方法.该方法有效地解决了电磁场干扰、环境变化使动态目标无法捕捉的问题,根据实验表明,该系统能够很好地检测到空中动态物体,具有很好的鲁棒性、实时性和清晰度. 相似文献
87.
从相位域假目标调制的角度提出了一种针对弹载合成孔径雷达的欺骗干扰信号产生方法。首先,干扰机根据侦察系统提供的弹载合成孔径雷达平台参数,将假目标模板按散射单元划分距离向单元,计算距离向单元内各散射单元对应的多普勒频率、多普勒频率的和函数、相位及幅度信息;其次,对截获的弹载合成孔径雷达信号按距离单元进行相位延时调整、假目标相位调制;然后,利用假目标模板获取的多普勒信号幅度信息进行雷达散射截面重建;最后,对各距离单元干扰信号求和后转发。仿真结果表明:由该方法产生的干扰信号能够形成期望的假目标,是一种有效的干扰方法。 相似文献
88.
89.
Abbas Shockravi Esmael Rostami Ali Dehjurian Rahim Tohidi Samad Bavili Tohidi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):535-541
Bis(dibenzosulfoxo)-27,30,35,38-tetramethyl-24-crown-6, bis(dibenzosulfoxo)-21,24,29,32-tetramethyl-18-crown-4, dibenzosulfoxo-15,18-dimethyl-12-crown-3 and dibenzosulfoxo-12,15-dimethyl-9-crown-2 macrocycles are synthesized by the reaction of 2,2′-sulfinyl-bis(4-methyl phenol)and 1,2-dibromoethane and diethyleneglycol di-p-toluenesulfonate. 相似文献
90.
One‐dimensional fullerene nanostructures with well‐defined morphology have been prepared by a controllable method. Fullerene molecules, such as C60 derivatives and endohedral metallofullerenes, are introduced into the pores of anodic aluminum oxide (AAO) templates under a direct current (DC) electric field. Then several nanostructures such as porous‐wall and solid‐wall fullerene nanowires and nanotubes were fabricated in the pores. The morphology of the fullerene nanostructures is well controllable, and the fullerene nanotubes can be further fabricated through filling nickel atoms inside to form fullerene‐metal composite structures. The results provide, in principle, a step toward broader applications of fullerene‐related materials in nanoscience and nanotechnology. 相似文献