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91.
P. Ekwall 《Colloid and polymer science》1988,266(3):279-282
Previous studies of the occurrence of acid soaps in systems containing a longchain sodium soap and the corresponding fatty acid, and the study of phase equilibria in the system sodium octanoate — octanoic acid — water, performed by our group at the beginning of the 1960s, show that the isotropic liquidL
2-phase of the last mentioned system in its whole region of existence is situated in that part in which acid soaps occur. This provides an explanation for the fact that theL
2-phase itself contains acid sodium octanoates in all regions. TheL
2-phase has its origin in the water-free melt of fatty acid and neutral soap in which these components react with each other under the formation of an acid soap. When water is added to the system, this water-free acid soap is transformed into different hydrated acid soaps. In a large region of concentration, there is an extremely close relation between theL
2-phase and the liquid-crystalline lamellarD-phase, which itself consists of hydrated acid soaps. At its outermost water-rich tip, theL
2-phase is in equilibrium with theL
1-phase of the system, just above the+LAC, that is, with the most dilute aqueous soap solution in which acid soap still may be formed in aqueous environment. Formation of acid soap is a fundamental requirement for the existence of this isotropic liquidL
2-phase. 相似文献
92.
Summary The effects of concentration, separation and spectral similarity as factors influencing the accuracy of iterative target testing
factor analysis (ITT-FA) are investigated for three component systems by the application of analysis of variance (ANOVAR).
ANOVAR is applied over a range of peak separations to map the changing effects of the three factors with increasing overlap.
Two error responses were measured and analysed, (a) Relative cluster error (RCE) a measure of the error over all peaks in
a cluster and (b) Relative peak error (RPE) the error of an individual peak. Multicomponent analysis (MCA) a method requiringa priori spectral information, is used as a referee method for ITT-FA. 相似文献
93.
The brightness of the X‐ray source in a W/Al‐film target used for X‐ray projection microscopy was studied by an approach using the Monte Carlo simulation. Since continuous X rays generated in a thin film have a specific angular distribution of emission, the brightness of the continuous X‐ray source cannot simply be estimated on the assumption that the angular distribution is homogeneous. The newly developed approach using the Monte Carlo simulation enables the evaluation of the effective source size, angular distribution, and brightness of a continuous X‐ray source with sufficient accuracy that it leads to the optimum design of a high‐brightness X‐ray source for uses such as X‐ray projection microscopy. The Monte Carlo calculations were performed for W(Δz)/Al (200 µm)‐film targets with different thicknesses of W film, Δz, under bombardment of 60 kV electrons. The results have suggested an optimum design consisting of a W (2 µm)/Al (200 µm)‐film target as most promising for providing an X‐ray source of higher brightness than the W (5 µm)/Al (200 µm)‐film target, which has already been in practice for X‐ray projection microscopy. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
94.
A constrained form of the Weber problem is formulated in which no path is permitted to enter a prespecified forbidden region of the plane. Using the calculus of variations the shortest path between two points which does not intersect is determined. If is unconstrained distance, we denote the shortes distance along a feasible path by . The constrained Weber problem is, then: given points and positive weights wj, j = 1,2,…,n, find a point such that is a minimum.An algorithm is formulated for the solution of this problem when is Euclidean distance and is a single circular region. Numerical results are presented. 相似文献
95.
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99.
Competitive location problems can be characterized by the fact that the decisions made by others will affect our own payoffs. In this paper, we address a discrete competitive location game in which two decision-makers have to decide simultaneously where to locate their services without knowing the decisions of one another. This problem arises in a franchising environment in which the decision-makers are the franchisees and the franchiser defines the potential sites for locating services and the rules of the game. At most one service can be located at each site, and one of the franchisees has preferential rights over the other. This means that if both franchisees are interested in opening the service in the same site, only the one that has preferential rights will open it. We consider that both franchisees have budget constraints, but the franchisee without preferential rights is allowed to show interest in more sites than the ones she can afford. We are interested in studying the influence of the existence of preferential rights and overbidding on the outcomes for both franchisees and franchiser. A model is presented and an algorithmic approach is developed for the calculation of Nash equilibria. Several computational experiments are defined and their results are analysed, showing that preferential rights give its holder a relative advantage over the other competitor. The possibility of overbidding seems to be advantageous for the franchiser, as well as the inclusion of some level of asymmetry between the two decision-makers. 相似文献
100.
Abstract Solid solutions Ca1-xGdxF2+x for 3 × 10?7≤ x ≤10?1 have been studied by electron paramagnetic resonance (EPR) and ionic thermal currents (ITC). The EPR experiments show the presence of two single-ion sites a cubic and a tetragonal Gd3+ center which co-exist with comparable abundances for intermediate impurity concentrations. The cubic center predominates at very low and high concentrations. Seven different relaxation processes have been identified from the ITC spectra and the variation of their intensity vs. x was measured. The absolute concentrations of the cubic and nn Gd3+ dipoles were calculated. The scavenging of interstitial fluorines by the neutral clusters explains both the abundance of cubic sites at high concentration and the variety of orientable clusters detected by ITC. 相似文献