本质安全型防爆摄像仪的研发和应用

高清4G公网防爆摄像仪系统是为石油化工等高危防爆环境研制的便携移动防爆摄像系统。如何在高清4G模块高发射功率、多储能元件的前提下实现设备的总体防爆指标以满足国家标准是本文解决的重点问题。基于防爆理论,通过提高设备防爆电容设计门限和降低电路容值设计的电容管理手段,对整体设备的储能元件进行了极限防爆限制,优化设计了4G-LTE无线摄像模块的最低储能电容解决方案;利用双半波振子天线列阵技术实现天线设备的发射功率限制硬件保护,采用软件保护手段实现双重防爆保护,从设计原理上保证了研发的高清4G摄像仪满足《GB 3836.1-2000》防爆要求。在保证防爆性能和设备功能的前提下,设备电容容量降低了50%,设备远场电场强度9%。     

粗调和细调相结合的标准CMOS低噪声环形压控振荡器

本文提出了一种基于65nm CMOS标准工艺、采用粗调和细调相结合的低噪声环形压控振荡器。论文分析了环形振荡器中的直接频率调制机理,并采用开关电容阵列来减小环形压控振荡器的增益从而抑制直接频率调制效应。开关电容采用电容密度较高的二维叠层MOM电容使该压控振荡器与标准的CMOS工艺兼容。所设计压控振荡器的频率范围为480MHz～1100MHz,调谐范围为78%,测试得到输出频率为495MHz时的相位噪声为-120dBc/Hz@1MHz。该压控振荡器在1.2V的偏压下的功耗为3.84mW,相应的优值(FOM)为-169dBc/Hz。     

Determination of generation lifetime fromC-t transients under linear voltage ramp bias

When a linear voltage ramp is applied to the gate of a MOS capacitor, a capacitancetime (C-t) transient is observed. The MOS capacitor is biased into strong inversion before applying the voltage ramp in order to eliminate surface generation. FromC-t transient curve obtained experimentally the minority carrier generation lifetime in semiconductor can be determined. The experimental results show that for the same sample the lifetimes extracted fromC-t curves under varying voltage sweep rates are close each other, and they are consistent with the lifetimes extracted by saturation capacitance method.     

n型4H-SiCMOS电容的特性

在n型4H-SiC外延层上，采用H2, O2合成的办法，热生长30nm的SiO2层，并制备出Al栅MOS电容，完成了C-V特性的测试和分析工作，根据测试结果得出了SiO2与4H-SiC外延层的界面特性，并计算出n型4H-SiC外延层的掺杂浓度. 结果表明H2, O2合成热生长的SiO2与4H-SiC外延层之间具有较好的界面特性，界面态密度较小. n型4H-SiC外延层的掺杂均匀，浓度为1.84e17cm-3.     

一种带有开关电流源的低相噪压控振荡器

提出一种带有开关电流源的电感电容压控振荡器（LC VCO）。该技术通过反馈电容将电感电容压控振荡器的输出耦合到电流源,形成了电流源的开关特性,从而减小了电感电容压控振荡器的相位噪声。提出的电感电容压控振荡器采用华虹 NEC的0.18μm SiGe BiCMOS工艺,工作频率为5.7 GHz,相位噪声为-113.0 dBc/Hz@1MHz,功耗为2.3 mA。在其他性能相同的情况下,提出的电感电容压控振荡器的振荡频率比典型的电感电容压控振荡器的相位噪声小4.5 dB。     

采用新型La0.07Sr0.93SnO3电极制备外延透明BiFe0.95Mn0.05O3铁电薄膜电容器

本文使用脉冲激光沉积的方法在SrTiO3(STO)单晶衬底上采用一种新型的透明导电氧化物材料La0.07Sr0.93SnO3(LSSO)薄膜作为电极材料制备了BiFe0.95Mn0.05O3(BFMO)铁电薄膜电容器.XRD表征结果证实BF-MO/LSSO/STO外延异质结具有很好的单晶质量.光透过率的测试结果表明在500~2500nm的波长范围内,整个异质结的透光率与单纯STO衬底基片相似.在波长500nm附近BFMO出现吸收边,通过对吸收边进行(hνα)2-hν曲线拟合得到BFMO的直接光学带隙约为2.8eV.利用Pt作为上电极,我们测得了饱和的电滞回线,剩余极化Pr~60μC/cm2.     

Efficient Piezoelectric Energy Harvesting from a Discrete Hybrid Bismuth Bromide Ferroelectric Templated by Phosphonium Cation

Bismuth containing hybrid molecular ferroelectrics are receiving tremendous attention in recent years owing to their stable and non-toxic composition. However, these perovskite-like structures are primarily limited to ammonium cations. Herein, we report a new phosphonium based discrete perovskite-like hybrid ferroelectric with a formula [Me(Ph)₃P]₃[Bi₂Br₉] ( MTPBB ) and its mechanical energy harvesting capability. The Polarization-Electric field (P-E) measurements resulted in a well-defined ferroelectric hysteresis loop with a remnant polarization value of 2.1 μC cm⁻². Piezoresponse force microscopy experiments enabled visualization of the ferroelectric domain structure and evaluation of the piezoelectric strain coefficient (d₃₃) for an MTPBB single crystal and thin film sample. Furthermore, flexible devices incorporating MTPBB in polydimethylsiloxane (PDMS) matrix at various concentrations were fabricated and explored for their mechanical energy harvesting properties. The champion device with 20 wt % of MTPBB in PDMS rendered a maximum peak-to-peak open-circuit voltage of 22.9 V and a maximum power density of 7 μW cm⁻² at an optimal load of 4 MΩ. Moreover, the potential of MTPBB -based devices in low power electronics was demonstrated by storing the harvested energy in various electrolytic capacitors.     

Role of FTFSI Anion Asymmetry on Physical Properties of AFTFSI (A=Li,Na and K) Based Electrolytes and Consequences on Supercapacitor Application

This study compares the physicochemical properties of six electrolytes comprising of three salts: LiFTFSI, NaFTFSI and KFTFSI in two solvent mixtures, the binary (3EC/7EMC) and the ternary (EC/PC/3DMC). The transport properties (conductivity, viscosity) as a function of temperature and concentration were modeled using the extended Jones-Dole-Kaminsky equation, the Arrhenius model, and the Eyring theory of transition state for activated complexes. Results are discussed in terms of ionicity, solvation shell, and cross-interactions between electrolyte components. The application of the six formulated electrolytes in symmetrical activated carbon (AC)//AC supercapacitors (SCs) was characterized by cyclic voltammetry (CV), galvanostatic cycling with potential limitation (GCPL), electrochemical impedance spectroscopy (EIS) and accelerated aging. Results revealed that the geometrical flexibility of the FTFSI anion allows it to access and diffuse easily in AC whereas its counter ions (Li⁺, Na⁺ or K⁺) can remain trapped in porosity. However, this drawback was partially resolved by mixing LiFTFSI and KFTFSI salts in the electrolyte.     

润湿特性对超级电容器储能动力学的影响机理

润湿特性对超级电容器储能性能有着至关重要的影响。借助分子动力学模拟,本文研究了润湿特性对超级电容器储能动力学行为的影响。以石墨烯和晶体铜作为疏电解液和亲电解液电极材料。结果表明,在充电过程中,亲电解液铜电极呈现出非对称的U型微分电容曲线,负极电容是正极的～5.77倍,不同于经典双电层理论Gouy-Chapman-Stern(对称U型)和疏电解液型。该现象与离子自由能阻力分布密切相关,负极自由能阻力远小于正极(～2倍)和疏电解液电极,进而有利于强化双电层结构对电极电压的响应能力,导致更高微分电容。通过微分离子电荷密度,本文再现了微分电容演变规律,并发现改善润湿性会显著降低双电层厚度。最后,我们指出润湿性直接影响储能微观机理,将电荷储存机制从离子吸附和交换共同主导(疏电解液)转变到离子吸附主导(亲电解液)。本文所得结论揭示了润湿特性对储能动力学行为影响的原子层级机理,对超级电容器材料设计、构筑与润湿特性调控具有重要指导意义。     

等离子体光谱光源技术的进展

光谱光源是光谱仪器和光谱技术的核心,等离子体光源是原子发射光谱技术的活跃领域之一,电感耦合等离子体(ICP)已成功地应用于原子发射光谱和无机质谱仪器。由于ICP光源采用氩气作为工作气体,耗量较大,降低氩气用量成为近些年来原子光谱技术研究和改进的重要目标。为此目的,已研究过各种低耗氩ICP光源,非氩气ICP光源,微波等离子体光源,射频电容耦合等离子体光源等。综述了近年这些等离子体发射光源的结构,分析性能及特点,以及它们所用工作气体情况。并归纳总结出,评价各种等离子体发射光谱光源应包括:等离子体温度(激发温度,气体温度),电子密度,工作气体种类及用量,元素检出限,光源的稳健性及经济方面等。