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111.
The change of the superstructure of different polyethylenes during uniaxial deformation is investigated. The method used is small-angle scattering with synchrotron radiation. For branched polyethylene (Lupolen 1840D) the whole deformation range is analyzed. Beginning with superstructure of the lamellar cluster type, the superstructure partly disappears on a time scale of a few minutes and the fibrillar structure is built up. The degree of destruction and rebuilding depends on the drawing temperature. For very high molecular weight polyethylene (GUR) a reversible change of the superstructure at higher deformation ratios and at different temperatures is observed. The superstructure of (ethylene—hexene) copolymers (TIPELIN) at high draw ratios depends on the drawing temperature and is almost independent of the side group content. Interfibrillar microcracks parallel to the draw direction are produced in samples with a low side group content for draw ratios λ ≥ 1.5. 相似文献
112.
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114.
Shayesteh S. Farjami B. Soltani M. A. Solimany 《International Journal of Infrared and Millimeter Waves》2002,23(12):1691-1697
We present and discuss infrared magnetoplasma reflectivity and surface polariton modes in Ga1–xNxAs. It assumed that the sample is characterized by a magnetoplasma dielectric tensor. Surface polariton dispersion for two component magnetoplasma was calculated from reflectivity spectra data. We detect transverse optic phonon of GaN sublattice in 470 cm-1. The origin of sharp feature in p-polarization reflectivity about 300 cm–1 as well as LO phonon frequency of GaAs sublattice is due to Brewster mode. An interesting feature of surface modes in Voigt geometry is nonreciprocalicity, which means that the frequency changes when the direction of propagation is reversed. Also, the infrared magnetoplasma reflectivity of GaNAs should be providing determination of the electrons and heavy holes effective mass and carrier's concentration. 相似文献
115.
用于曲面精密检测的新型光纤三角传感器研究 总被引:1,自引:1,他引:0
基于光纤传感技术和三角测量方法,提出了一种用于曲面检测的新型光纤三角传感器。根据所设计的轮辐式接收光纤结构,可以在测量曲面与传感头间位移时,首先获取被测点处微面元的倾斜信息,以便对传感器测量值进行实时误差修正,从而解决了被测表面倾斜对坐标测量带来的影响。该传感器还能有效地消除环境光干扰、光源波动、表面反射率变化等对测量带来的影响。建立了传感器测量的数学模型。理论分析和初步的实验结果证明了系统的有效性和实用性。该传感器系统不稳定性好于0.3%,横向分辨率好于8μm,高度分辨率好于0.1μm。 相似文献
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118.
Monocrystalline 6H-SiC thin films have been epitaxially grown on off-axis 6H-SiC {0001} substrates in the temperature range
of 1623–1873 K via chemical vapor deposition. The growth rate was a strong function of the growth temperature and the reactant
gas concentration. The activation energies for growth were 64 kJ/mole and 55 kJ/mole for the (0001) Si face and the (0001)
C face, respectively. The concentration of growth pits in the films increased as a function of decreasing deposition temperature,
increasing concentration of reactant gases and increasing off-axis orientation. Beta-SiC islands were also observed in the
epilayers when the (SiH4 + C2H4)/H2 ratio was ≥2.5:3000. 相似文献
119.
A. I. Vanin 《Journal of Applied Spectroscopy》1997,64(2):242-245
Light scattering by groups of spherical particles is considered. It is shown that the structure of the groups and their orientational
distribution can be judged from the spectrum and polarization of the scattered light.
Syktyvkar State University, 55, Oktyabr'skii Ave., Syktyvkar, 167001, Russia. Translated from Zhurnal Prikladnoi Spektroskopii,
Vol. 64, No. 2, pp. 228–231, March–April, 1997. 相似文献
120.
There is a high correlation between molecular surface area (TSA) of triorganotin and triorganolead compounds and their toxicity towards a bacterium (Escherichia coli) and an alga (Selenastrum capricornutum). Parallel attempts to correlate other Group IVA organometals incorporating silicon or germanium were unsuccessful. It was further demonstrated, however, that a high correlation was obtainable between certain series of compounds with the same organic substituent but different metal centers involving all Group IVA elements. In both instances, the inability to obtain a quantitative structure-activity relationship (QSAR) for all systems studied appears to be a function of the solubility of the compounds. While organotin TSA values have been found to correlate well with their toxicities toward various organisms, this study clearly suggests that this type of QSAR can be readily extended to include other organometal systems, provided that there is no solubility problem and the toxicity is a function of the hydrophobicity of the organometal compounds. 相似文献