A PENNY-SHAPED CRACK IN A MAGNETOELECTROELASTIC LAYER UNDER RADIAL SHEAR IMPACT LOADING

This paper analyzes the dynamic magnetoelectroelastic behavior induced by a penny- shaped crack in a magnetoelectroelastic layer.The crack surfaces are subjected to only radial shear impact loading.The Laplace and Hankel transform techniques are employed to reduce the prob- lem to solving a Fredholm integral equation.The dynamic stress intensity factor is obtained and numerically calculated for different layer heights.And the corresponding static solution is given by simple analysis.It is seen that the dynamic stress intensity factor for cracks in a magnetoelec- troelastic layer has the same expression as that in a purely elastic material.And the influences of layer height on both the dynamic and static stress intensity factors are insignificant as h/a>2.     

用蒙特卡罗方法和MATLAB计算冷屏内壁表面辐射光线落入探测器芯片的比例

介绍了用蒙特卡罗方法和MATLAB计算圆形冷屏内壁表面辐射落入探测器芯片比例的一种解决方案。该 方案基于三维空间中的方向数概念,首先利用MATLAB命令生成冷屏内壁表面上的随机点,再赋予该点一组随机方向数,获得 一条随机直线方程,以判断它是直接投向芯片平面还是经反射后投向芯片平面。对于反射的情况,根据镜面反射的性质及解析几 何公式,生成该直线在冷屏内壁上的反射光线,并判断它们是否落在探测器芯片区域。经统计后,可算出冷屏各部分落入芯片表面 的辐射光线在冷屏内壁表面发射出来的总光线数中所占的比例。该方法具有编程简单和方便实用等特点。     

水面舰艇的红外辐射及红外隐身技术分析

概述了红外隐身技术的基本原理,通过分析水面舰艇对红外隐身的要求,研究了水面舰艇红外隐身技术所采取的措施,介绍了红外隐身技术在水面舰艇上的应用和发展趋势。     

分子束外延InAlSb/InSb晶体的质量研究

InAlSb/InSb薄膜材料的晶体质量会直接影响器件的性能。提高薄膜材料的晶体质量可以有效降低器件的暗电流,提高探测率和均匀性等。主要报道了掺铝锑化铟分子束外延技术的初步研究结果。通过采用多种测试方法对InAlSb分子束外延膜的晶体质量进行了分析,找出了影响晶体质量的因素,提高了InAlSb分子束外延的技术水平。实验结果表明,通过优化生长温度、束流比、升降温速率以及退火工艺等生长条件,可以获得高质量的InAlSb分子束外延膜。     

基于标准黑体的物体表面发射率计算方法研究

红外测温仪器的精度和被测物体表面的发射率对测量物体红外辐射特性的准确性影响很大。为了提高物体表面发射率的计算精度,先通过标准黑体对红外热像仪进行标定。然后,利用标定好的红外热像仪测量温度,计算出被测物体表面的发射率。将基于神经网络的红外热像仪标定方法应用到目标发射率的求解方法中,有效地消除了热像仪的系统误差。测试装置简单,测试结果准确。同时,温度和发射率的精确测量为红外隐身材料的研制奠定了基础。     

Significant Enhancement of the Capacity and Cycling Stability of Lithium-Rich Manganese-Based Layered Cathode Materials via Molybdenum Surface Modification

Lithium-rich manganese-based layered cathode materials are considered to be one of the best options for next-generation lithium-ion batteries, owing to their ultra-high specific capacity (>250 mAh·g⁻¹) and platform voltage. However, their poor cycling stability, caused by the release of lattice oxygen as well as the electrode/electrolyte side reactions accompanying complex phase transformation, makes it difficult to use this material in practical applications. In this work, we suggest a molybdenum surface modification strategy to improve the electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂. The Mo-modified Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ material exhibits an enhanced discharge specific capacity of up to 290.5 mAh·g⁻¹ (20 mA·g⁻¹) and a capacity retention rate of 82% (300 cycles at 200 mA·g⁻¹), compared with 261.2 mAh·g⁻¹ and a 70% retention rate for the material without Mo modification. The significantly enhanced performance of the modified material can be ascribed to the formation of a Mo-compound-involved nanolayer on the surface of the materials, which effectively lessens the electrolyte corrosion of the cathode, as well as the activation of Mo⁶⁺ towards Ni²⁺/Ni⁴⁺ redox couples and the pre-activation of a Mo compound. This study offers a facile and effective strategy to address the poor cyclability of lithium-rich manganese-based layered cathode materials.     

Extraction of Phenolic and Flavonoid Compounds from Mung Bean (Vigna radiata L.) Seed Coat by Pressurized Liquid Extraction

Mung bean seed coat (MBC) is a by-product of the mung bean processing industry. It contains a large number of phenolic compounds with therapeutic anti-inflammatory, anti-diabetic and antioxidant properties. This research aimed to investigate the optimum conditions for phenolic and flavonoid extraction from MBC by pressurized liquid extraction (PLE). Response surface methodology (RSM) was used to study the effects of temperature (80–160 °C), pressure (1200–1800 psi) and ethanol concentration (5–95%) on total phenolic content (TPC), total flavonoid content (TFC) and 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) scavenging activity (ABTS). Scale-up extraction was also performed. The optimum conditions for extraction were 160 °C, 1300 psi and 50% ethanol. Under optimum conditions, the TPC was 55.27 ± 1.14 mg gallic acid equivalent (GAE)/g MBC, TFC was 34.04 ± 0.72 mg catechin equivalent (CE)/g MBC and ABTS scavenging activity was 195.05 ± 2.29 mg trolox equivalent (TE)/g MBC. The TFC and ABTS scavenging activity of the extracts obtained at the pilot scale (10 L) was not significantly different from the laboratory scale, while TPC was significantly increased. The freeze-dried MBC extract contained vitexin and isovitexin 130.53 ± 17.89, 21.21 ± 3.22 mg/g extract, respectively. In conclusion, PLE was able to extract phenolics, flavonoids with ABTS scavenging activity from MBC with the prospect for future scale-up for food industry.     

Quantum Computational Investigation of (E)-1-(4-methoxyphenyl)-5-methyl-N′-(3-phenoxybenzylidene)-1H-1,2,3-triazole-4-carbohydrazide

The title compound was synthesized and structurally characterized. Theoretical IR, NMR (with the GIAO technique), UV, and nonlinear optical properties (NLO) in four different solvents were calculated for the compound. The calculated HOMO–LUMO energies using time-dependent (TD) DFT revealed that charge transfer occurs within the molecule, and probable transitions in the four solvents were identified. The in silico absorption, distribution, metabolism, and excretion (ADME) analysis was performed in order to determine some physicochemical, lipophilicity, water solubility, pharmacokinetics, drug-likeness, and medicinal properties of the molecule. Finally, molecular docking calculation was performed, and the results were evaluated in detail.     

Pilot-Scale Optimization of Supercritical CO2 Extraction of Dry Paprika Capsicum annuum: Influence of Operational Conditions and Storage on Extract Composition

Supercritical carbon dioxide extraction was used to extract carotenoids from dry paprika Capsicum annuum. Studies regarding the effect of process parameters, including pressure (25–45 MPa), temperature (40–60 °C), and time (10–110 min), were carried out using response surface methodology. It was found that under optimal conditions (pressure of 45 MPa, temperature of 50 °C, and time of 74 min), the extract yield was 10.05%, and the total content of carotenoids in the extract was 4.21%, in good agreement with the predicted values (10.24% and 4.24%, respectively). Composition analysis showed that paprika extract mainly consisted of linoleic acid. There was no significant difference between the fatty acid content of the extracts obtained by SC-CO₂ extraction and n-hexane Soxhlet extraction. For functional purposes, the effect of storage conditions and time on the quality of paprika extract was also specified.     

Semiempirical Potential in Kinetics Calculations on the HC3N + CN Reaction

The reaction between the cyano radical CN and cyanoacetylene molecule HC3N is of great interest in different astronomical fields, from star-forming regions to planetary atmospheres. In this work, we present a new synergistic theoretical approach for the derivation of the rate coefficient for gas phase neutral-neutral reactions. Statistic RRKM calculations on the Potential Energy Surface are coupled with a semiempirical analysis of the initial bimolecular interaction. The value of the rate coefficient for the HC3N + CN → H + NCCCCN reaction obtained with this method is compared with previous theoretical and experimental investigations, showing strengths and weaknesses of the new presented approach.