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941.
942.
An automatic system based on multisyringe flow injection analysis (MSFIA) and lab-on-valve (LOV) flow techniques for separation and pre-concentration of 226Ra from drinking and natural water samples has been developed. The analytical protocol combines two different procedures: the Ra adsorption on MnO2 and the BaSO4 co-precipitation, achieving more selectivity especially in water samples with low radium levels. 相似文献
943.
Computational study of structure,electronic, and microscopic charge transport properties of small conjugated diketopyrrolopyrrole‐thiophene molecules 下载免费PDF全文
Maria V. Makarova Sergey G. Semenov Olga A. Guskova 《International journal of quantum chemistry》2016,116(20):1459-1466
π‐Conjugated small molecules containing diketopyrrolopyrrole (DPP) and thiophene moieties represent a modern class of functional materials that exhibit promising charge transport properties and therefore have great potential as building blocks of active elements of electronic devices. As a starting point of this computational study, the molecular structure, electronic characteristics, and reorganization energies associated with electron or hole transfer are considered. Prediction of molecular crystal packing is followed by the calculation of couplings between adjacent molecules and detection of the effective charge transfer pathways. Finally, the rates of charge transfer process are evaluated. The obtained results shed light not only on the properties of materials containing low‐molecular species but also serve as a benchmark for further classical force‐field simulations of DPP‐based polymers. 相似文献
944.
针对传输函数求解船载投弃式仪器信道分布参数模型误差较大的问题, 提出了一种求解其数据传输信道时频响应的方法.时域响应采用时域有限差分(Finite Difference Time Domain, FDTD)法, 求得信道上任意位置的时域响应, 频域响应采用BLT(Baum-Liu-Tesche)方程结合电磁拓扑理论, 对信道的关键节点进行频域分析.最后测试了信道的时频域波形, 并与理论仿真结果进行对比, 结果表明:在仪器的工作频率内, 理论仿真与试验结果一致, 为进一步地研究终端电路的设计及传输方案的改进提供了理论基础. 相似文献
945.
传统激光标刻技术已在实际工业生产中普遍应用,但其系统最优标刻性能控制参数存在寻找及设置较为困难、繁琐等问题。针对该问题,本文设计了一种基于嵌入式网络激光标刻模式的新型激光标刻控制模型,并在该模型下通过相关数据预处理算法分析单一标刻影响因素对激光标刻性能的影响;再通过对实验数据的数理统计分析得出二值图像的标刻性能变化规律,最终得出在该材质及类似组成工件下的激光标刻的最优参数快速选择模型和性能最优值域。研究结果表明,该模型为最优激光标刻性能控制参数的快速选择提供了可靠的方法,为进一步研究激光标刻性能影响参数提供了重要参考。 相似文献
946.
Nanoporous thin films of Cd1−xCuxS (0≤x≤0.06) were grown on a heated glass substrate employing a home-made spray pyrolysis technique. The influences of [Cu]/[Cd] and the annealing in the range 300–500 °C on the structural and morphological properties of the films were investigated by X-ray diffraction (XRD), Fourier transformation infrared spectroscopy (FTIR), field emission scanning electron microscope (FE-SEM) and atomic force microscopy (AFM). The influences of Cu doping ratio, solution flow rate, and the deposition time on the optical properties and photocatalytic activity of these films are also reported. The films are of polycrystalline nature and hexagonal structure. Increasing the Cu doping ratio and annealing temperature improve the (1 0 1) preferential orientation. The crystallite size is ranged from 23.82 to 32.11 nm. XRD and FTIR reveal the formation of CdO in the 6% Cu-doped CdS film annealed at 400 °C and in all films annealed at 500 °C. The pure CdS film is of a porous structure and the close-packing and porosity of the films increase with increasing Cu%. Also, the pore diameter can be controlled from 50 to 15 nm with the increase of Cu content. The films showed transmittance below 70%. The optical band gap of the films is decreased from 2.43 to 1.82 eV with increasing Cu% and flow rate/deposition time. Additionally, the refractive indices and dispersion parameters of the films are also affected by the deposition conditions. Cu doping enhanced the films' photostability as well as the photocatalytic removal of methylene blue (MB). 相似文献
947.
焊接过程是典型的复杂过程,应用模糊逻辑建立焊接参数推理系统可快速实现焊接工艺参数设计.近似推理机制是模糊系统研究和开发中的一个重要组成部分,在现有的相似性推理方法的基础上,融合经典的合成规则推理技术,提出一种新的基于合成规则的相似性推理方法.以CO_2保护焊焊接规范参数设计为背景介绍模糊推理在焊接领域的应用,运行结果表明,采用方法建立的模糊推理模型具有较高的推算精度,能够满足焊接工艺参数设计的要求. 相似文献
948.
??In this paper, we estimate parameters of gamma life distribution
and normal life distribution by EM algorithm based on Type-II hybrid censored data. The
covariance matrices are derived as well. Some numerical examples are also presented for
illustration. 相似文献
949.
For solving saddle point problems, SOR-type methods are investigated by many researchers in the literature. In this short note, we study the GMSSOR method for solving saddle point problems and obtain the optimal parameters which minimize the spectral (or pseudo-spectral) radii of the iteration matrices. 相似文献
950.
Sonoporation—transient plasma membrane perforation elicited by the interaction of ultrasound waves with microbubbles—has shown great potential for drug delivery and gene therapy. However, the heterogeneity of sonoporation introduces complexities and challenges in the realization of controllable and predictable drug delivery. The aim of this investigation was to understand how non-acoustic parameters (bubble related and bubble-cell interaction parameters) affect sonoporation. Using a customized ultrasound-exposure and fluorescence-imaging platform, we observed sonoporation dynamics at the single-cell level and quantified exogenous molecular uptake levels to characterize the degree of sonoporation. Sonovue microbubbles were introduced to passively regulate microbubble-to-cell distance and number, and bubble size. 1 MHz ultrasound with 10-cycle pulse duration and 0.6 MPa peak negative pressure were applied to trigger the inertial collapse of microbubbles. Our data revealed the impact of non-acoustic parameters on the heterogeneity of sonoporation. (i) The localized collapse of relatively small bubbles (diameter, D < 5.5 μm) led to predictable sonoporation, the degree of which depended on the bubble-to-cell distance (d). No sonoporation was observed when d/D > 1, whereas reversible sonoporation occurred when d/D < 1. (ii) Large bubbles (D > 5.5 μm) exhibited translational movement over large distances, resulting in unpredictable sonoporation. Translation towards the cell surface led to variable reversible sonoporation or irreversible sonoporation, and translation away from the cell caused either no or reversible sonoporation. (iii) The number of bubbles correlated positively with the degree of sonoporation when D < 5.5 μm and d/D < 1. Localized collapse of two to three bubbles mainly resulted in reversible sonoporation, whereas irreversible sonoporation was more likely following the collapse of four or more bubbles. These findings offer useful insight into the relationship between non-acoustic parameters and the degree of sonoporation. 相似文献