虚拟实时服务:构架、算法及演进路径

提出了一种基于虚拟实时服务的协议构架,可有效发掘用户提出通信请求之前的“负时间轴”上的空闲时频资源或可再生能源,将用户可能感兴趣的内容以多播的方式预先推送到终端的存储器中,从而以非实时的通信提供虚拟实时服务,在确保服务质量的前提下大幅度提升频谱和能量效率.对终端缓存内容的选择算法进行了标准化,从而允许基站在本地预测用户已缓存的内容,并判断当前是否应发起推送和推送哪条内容;提出了虚拟实时服务涉及的若干关键算法,也给出了虚拟实时服务的演进途径及主要开放问题,旨在为相关新兴产业的技术发展提供参考.     

一种地形条件下电波传播入射余角估计算法

入射余角是利用抛物方程模型研究地形条件下电波传播问题的重要参数,但该参数估计具有单次快拍、信号相干和实时性要求高的特点,传统的估计算法难以同时满足上述要求.针对上述问题,提出了基于单次快拍的空间平滑旋转不变性的信号参数估计(Estimating Signal Parameters via Rotational Invariance Techniques, ESPRIT)算法.直接采用单次数据的前后向空间平滑子阵构造centro-Hermitian伪协方差矩阵以实现信号解相干,应用酉变换将复数域的奇异值分解转换为实数域求解,利用ESPRIT算法代替多重信号分类算法估计入射余角.仿真结果表明:该算法能够实现电波传播入射余角的快速估计,准确反映地形起伏对入射余角的影响,与现有算法相比提高了实时性和估计精度.     

空间相关的二维海杂波仿真与混沌评估

在舰载雷达设计和性能评估的过程中,海杂波的仿真模拟是必需的。根据实际雷达回波的信号形式,使用ZMNL法产生距离和方位均统计相关的二维海杂波数据。混沌特性可以用来描述实测海杂波数据,因此使用分形维数和最大Lyapunov指数来评估仿真数据与实测数据的相似程度,从非线性角度描述了二维仿真海杂波的实用性。     

A Novel Chemo‐selective Epoxidation across Acrylate Ester: Synthesis of New Water‐Soluble Forskolin Analogues

While removing the TBDMS group from OH protection, a novel epoxidation reaction occurred across acrylate ester attached to a forskolin fragment. Besides spectroscopic data, the epoxide formation was confirmed by ring opening with a secondary amine. This unique epoxidation reaction, to our knowledge, is not known in the literature. This reaction led us to discover a simple deblocking protocol. The epoxide and the desired Michael substrates were used to introduce imidazole into forskolin.     

Mild conversion of propargylic alcohols to α,β-unsaturated enones in ionic liquids (ILs); a new ‘metal free’ life for the Rupe rearrangement

A mild and selective transition metal free protocol for the conversion of propargylic alcohols to cyclic and acyclic α,β-unsaturated enones via the Rupe rearrangement is reported. The method utilizes the Brønsted acidic ionic liquid [BMIM-SO₃H][OTf] as catalyst and [BMIM][PF₆] as solvent and offers the potential for recycling and reuse of the IL solvent. The feasibility to synthesize bicyclic fused cyclopentenone derivatives via a Rupe → Aldol → Nazarov sequence utilizing this protocol has also been demonstrated.     

湿式催化氧化处理含高浓度甲醛的草甘膦废水

草甘膦结晶母液经蒸发或纳滤浓缩回收后,产生大量含有高浓度甲醛的废水,常规的废水处理方法难以达到回用或排放要求.以过量溶液浸渍法制备的Pt-Bi-CeO2/AC为催化剂,采用湿式催化氧化法处理2.5%的HCHO溶液,HCHO去除率高达99.9%以上,COD去除率达到96.6%.采用Pt-Bi-CeO2/AC催化剂对含低浓度草甘膦(PMG,50 mg/L)的生产废水直接进行湿式催化氧化处理,催化剂使用23次后,HCHO去除率稳定在85%左右,COD去除率稳定在87%左右,催化剂具有良好的稳定性.湿式催化氧化处理后的废水可直接回用于PMG生产.采用固定床湿式催化氧化装置处理HCHO溶液以及PMG生产废水,处理效果也非常理想,连续使用720 h,催化剂的稳定性能良好.通过XRD、N2吸附-脱附、HRTEM、ICP-OES和XPS等分析手段对催化剂进行了系统表征.     

Application of oxetane ring opening toward stereoselective synthesis of zincophorin fragment

A stereoselective synthesis of the C1–C11 fragment of zincophorin was achieved by using an intramolecular oxetane ring opening reaction as the key step. The oxetane moiety was synthesized by employing a desymmetrization protocol developed at our group and a non-Evans syn aldol as the key steps toward the synthesis.     

Stereoselective total synthesis of penaresidin A starting from d-galactal

A stereoselective total synthesis of penaresidin A has been accomplished involving Sharpless asymmetric epoxidation, regioselective ring-opening of epoxide, azetidine formation via S_N2 reaction, Jung’s protocol, and Julia–Kocienski olefination. This approach has successfully demonstrated the synthetic utility of d-galactal in the construction of azetidine core of the natural product.