基于某变电站L90保护误动作分析

针对某变电站内线路正常运行时突发差动保护动作,后期进行认真检查核对后,发现是一起误保护动作过程,实际上L90保护出厂时自身相关参数返回时间过长而导致的误动作。     

基于μC/OS-II生物脱氮工艺中多参数实时检测

为实现对生物脱氮工艺中多参数的实时检测,以及解决常规化学检测过程中带来的污染和耗时问题。应用了一种基于电化学和嵌入式系统,可同时对水温、pH值、氨氮3个相关参数进行实时检测,并对理论值和实测值进行数据分析对比。实验结果表明,该系统实时性良好、稳定可靠,且满足了该工艺实时检测要求。     

高速PCB设计中的差分等长处理及仿真验证

在进行高速PCB(Printed Circuit Board)设计时,通常需要对差分信号线的相对时延进行控制,以满足信号完整性要求,因此,如何处理差分线的等长,是需要解决的一个问题。通过分析不同相对时延对差分及共模信号波形的影响,得出相对时延对信号的影响及与信号的上升/下降时间有关,并给出了确定信号上升/下降时间的方法,最后对DSP(Digital Signal Processor)和DDR3(Double Data Rate Tree)内存之间的信号进行了仿真分析,验证了前述分析结果的正确性。     

时域平面近场散射测量研究

时域平面近场散射测量是一种在近场区域进行散射测量的技术,可以有效地进行宽带的散射测量,具有超宽带测试、可以获得时域散射场、空间利用率高等特点,针对时域平面近场散射测量技术体系,在时域近场测量的理论基础上,提出了系统组建方案,论证了系统的可行性,开展了针对典型目标的验证测试,并对测量结果进行了初步的误差分析.证明了时域平面近场散射测量的有效性.     

电缆放电事件建模及其特性测试研究

参考人体行走电压的测试标准IEC 61340-4-5,搭建了电缆由线轴上绕下并在地板上拖拽积累的电压的测试系统,测量了六类非屏蔽网线的电压波形.基于实测电缆电压波形,提出了电缆电压的RC等效电路模型,并分析了模型参数对电缆电压时域波形的影响.进行了电缆充电后对金属靶的放电实验,测量了电缆放电事件的电流波形、瞬态电场和瞬态磁场波形,分析了电缆放电事件对电子设备的影响.根据测量的电缆放电事件的电流波形,对比了GJB 151B中CS 115电缆束注入脉冲激励传导敏感度的电流波形,二者电流波形有一定的相似性,但是对于较长电缆在电流的强度和宽度方面都会大于CS 115规定的限值.因此,提出了电缆放电事件的防护方法,并对相关标准的改进方面提出了初步建议.     

Simultaneously Probing Two Ultrafast Condensed‐Phase Molecular Symmetry Breaking Events by Two‐Dimensional Infrared Spectroscopy

In condensed phases, a highly symmetric gas‐phase molecule lowers its symmetry under perturbation of the solvent, which is vital to a variety of structural chemistry related processes. However, the dynamical aspects of solvent‐mediated symmetry‐breaking events remain largely unknown. Herein, direct evidence for two types of solvent‐mediated symmetry‐breaking events that coexist on the picosecond timescale in a highly symmetric anion, namely, hexacyanocobaltate, is presented: 1) an equilibrium symmetry‐breaking event in which a solvent‐bound species having lowered symmetry undergoes a population exchange reaction with the symmetry‐retaining species; 2) a dynamic symmetry‐breaking event that is composed of many dynamic population‐exchange reactions under fluctuating solvent interactions. Ultrafast two‐dimensional infrared spectroscopy is used to simultaneously observe and dynamically characterize these two events. This work opens a new window into molecular symmetry and structural dynamics under equilibrium and non‐equilibrium conditions.     

Flexizyme‐Mediated Genetic Reprogramming As a Tool for Noncanonical Peptide Synthesis and Drug Discovery

Noncanonical peptides occur frequently in Nature, and often display high bioactivity. However, the lack of tractable systems for the synthesis of diverse libraries of such peptides has thus far hampered their development as drugs. Genetic reprogramming techniques, in which noncanonical amino acids may be incorporated into peptides, have largely removed this limitation. This Concept article outlines the development of these techniques with an emphasis on drug discovery.     

On the structure of split Leibniz triple systems

We study the structure of arbitrary split Leibniz triple systems with a coherent 0-root space. By developing techniques of connections of roots for this kind of triple systems, under certain conditions, in the case of T being of maximal length, the simplicity of the Leibniz triple systems is characterized.     

Quality by design: A systematic and rapid liquid chromatography and mass spectrometry method for eprosartan mesylate and its related impurities using a superficially porous particle column

The present work describes the systematic development of a robust, precise, and rapid reversed‐phase liquid chromatography method for the simultaneous determination of eprosartan mesylate and its six impurities using quality‐by‐design principles. The method was developed in two phases, screening and optimization. During the screening phase, the most suitable stationary phase, organic modifier, and pH were identified. The optimization was performed for secondary influential parameters—column temperature, gradient time, and flow rate using eight experiments—to examine multifactorial effects of parameters on the critical resolution and generated design space representing the robust region. A verification experiment was performed within the working design space and the model was found to be accurate. This study also describes other operating features of the column packed with superficially porous particles that allow very fast separations at pressures available in most liquid chromatography instruments. Successful chromatographic separation was achieved in less than 7 min using a fused‐core C₁₈ (100 mm × 2.1 mm, 2.6 μm) column with linear gradient elution of 10 mM ammonium formate (pH 3.0) and acetonitrile as the mobile phase. The method was validated for specificity, linearity, accuracy, precision, and robustness in compliance with the International Conference on Harmonization Q2 (R1) guidelines. The impurities were identified by liquid chromatography with mass spectrometry.