Poole-Frenkel effect in amorphous poly(p-phenylene sulfide)

The conductivity of poly(p-phenylene sulfide) (PPS) amorphous samples sandwiched between metallic electrodes has been studied as a function of applied voltage, temperature, and electrode material. The voltage (U) dependence of the currents for electric fields within the range 10³–10⁶ V/cm exhibits exp βU^1/2 behavior with β = β_Schottky below the glass transition temperature (T_g ≊ 90°C), and β = β_{Poole-Frenkel} above T_g. Coordinated temperature measurements of dc currents with different metallic contacts and thermally stimulated currents (TSC) indicate, however, that the conductivity at T < T_g is consistent with the so-called “anomalous” Poole-Frenkel effect rather than the Schottky effect. Consequently, the p-type conductivity in amorphous PPS is proposed to be a bulk-limited process due to ionization of two different types of acceptor centers in the presence of neutral hole traps. © 1996 John Wiley & Sons, Inc.     

25FS管莫尔条纹的成因及对策

本文详细介绍了技术质量部对用户厂家反映我公司25FS管莫尔条纹的问题进行的深入探究,发现其产生的三大主要物理原因,并作了适当的数学说明,并提出了相应的对策.     

基于优势效应理论的双绞线简化建模

在对双绞线电磁干扰进行研究中,一些学者建立了精确的干扰模型,但并不适合工程应用.本文根据电磁兼容优势效应理论,推导出双绞线传导干扰主要由差模电流引起,辐射干扰主要由共模电流引起.分别利用广义二端口网络模型和电流元分析方法建立双绞线串扰和辐射的简化模型,从而有效估算双绞线串扰电压和对外辐射场的大小,为工程人员采取有效措施抑制互连设备电磁干扰提供了理论帮助.     

Mg0.3Fe2.7GeTe2 单晶的磁性及霍尔效应研究

Fe3GeTe2 是一种具有稳定长程磁有序的准二维范德瓦尔斯磁性材料, 范德瓦尔斯材料的稳定性和可调性使其在自旋电子器件的应用方面具有巨大潜力. 本文用助熔剂法生长了 Mg 原子掺杂Fe2 位的 Mg0.3Fe2.7GeTe2单晶样品, 并对 Mg 掺杂Fe3GeTe2 的结构、磁性和输运性质的影响进行了研究. 磁性数据表明 Mg 掺杂后铁磁转变温度不变, 但样品的饱和磁矩减小. 输运性质的测量中观察到各向异性的反常霍尔效应, 与Fe3GeTe2 相比, Mg掺杂后的反常霍尔电阻率减小, 同时各向异性发生了变化.     

纳米吸波材料的物理实质及研究进展

吸波材料是隐身技术的关键材料,纳米材料由于其特殊的量子尺寸效应和隧道效应等产生的优良的电磁波吸收性能而受到世界各国的重视．本文简单介绍了吸波材料的工作原理,进而阐述了纳米吸波材料吸收电磁波的物理实质．详细介绍了纳米涂敷型吸波材料和纳米结构型吸波材料的研究现状,并对纳米吸波材料的发展趋势进行了展望．     

Rosmanol and Carnosol Synergistically Alleviate Rheumatoid Arthritis through Inhibiting TLR4/NF-κB/MAPK Pathway

Callicarpalongissima has been used as a Yao folk medicine to treat arthritis for years in China, although its active anti-arthritic moieties have not been clarified so far. In this study, two natural phenolic diterpenoids with anti-rheumatoid arthritis (RA) effects, rosmanol and carnosol, isolated from the medicinal plant were reported on for the first time. In type II collagen-induced arthritis DBA/1 mice, both rosmanol (40 mg/kg/d) and carnosol (40 mg/kg/d) alone alleviated the RA symptoms, such as swelling, redness, and synovitis; decreased the arthritis index score; and downregulated the serum pro-inflammatory cytokine levels of interleukin 6 (IL-6), monocyte chemotactic protein 1 (MCP-1), and tumor necrosis factor α (TNF-α). Additionally, they blocked the activation of the Toll-like receptor 4 (TLR4)/nuclear factor κB (NF-κB)/c-Jun N-terminal kinase (JNK) and p38 mitogen-activated protein kinase (MAPK) pathways. Of particular interest was that when they were used in combination (20 mg/kg/d each), the anti-RA effect and inhibitory activity on the TLR4/NF-κB/MAPK pathway were significantly enhanced. The results demonstrated that rosmanol and carnosol synergistically alleviated RA by inhibiting inflammation through regulating the TLR4/NF-κB/MAPK pathway, meaning they have the potential to be developed into novel, safe natural combinations for the treatment of RA.     

介观化学体系中的动力学尺度效应

以生命和表面催化体系为对象,研究了介观化学体系中内涨落对体系非线性动力学行为的调控作用。内涨落可以诱导随机振荡,其强度在体系处于最佳尺度时会出现一个甚至多个极大值,并且在耦合体系中会得到进一步增强,表现为尺度共振效应、尺度选择效应和双重尺度效应,揭示了介观化学体系中尺度效应的新机制。     

微波作用下卤素交换氟化制备氟代苯甲醛及二苯甲酮类化合物

在微波作用下,采用高效催化剂体系,于中等极性非质子溶剂中经卤素交换氟化高效制备了系列含氟芳香醛(酮)类化合物,产品收率53·3%~92·6%,反应时间较常规加热最多可缩短80%以上。采用中等极性反应溶剂,还可突出表现出微波对反应促进的“非热效应”,从而大大拓宽了氟化反应溶剂的选择范围。     

热散焦效应对甲烷后向受激喇曼散射的影响

The conversion efficiency of stimulated Raman scattering (SRS) in CH4 is studied by using a single longitudinal mode second-harmonic Nd:YAG laser (532 nm, linewidth 0.003 cm-1, pulse-width (FWHM) 6.5 ns).Due to the heat release from vibrationally excited particles, SRS processes often suffer from the thermal defocusing effect (TDE). In view of 6.5 ns laser pulse width is much shorter than the vibrational relaxation time of CH4 molecules, TDE can only affect the SRS processes afterwards. In the cases of low laser repetition, TDE will be not serious, because it will be removed by the thermal diffusion in Raman medium before the next pulse arrives. At the laser repetition rate 2 Hz, CH4 pressure 1.1 MPa and pump laser energy 95 m J, the quantum conversion efficiency of backward first-Stokes (BS1) has attained 73%. This represents the highest first-stokes conversion efficiency in CH4. Furthermore, due to the relaxation oscillation, the BS1pulses are narrowed to about 1.2 ns. As a result, the BS1 peak power turns out to be 2.7 times that of the pump. Its beam quality is also much better and is only slightly affected by TDE. This reason is that BS1 represents a wave-front-reversed replica of the pump beam, which can compensate the thermal distortions in Raman amplify process. Under the same conditions, but pump laser repetition rate as 10 Hz, the conversion efficiency of BS1 goes down to 36% due to TDE. From this study, we expect that a well-behaved 630 nm Raman laser may be designed by using a closed CH4/He circulating-cooling system, which may have some important applications.     

Ca2+和Mn2+共掺杂Ba1-xSrxTiO3固溶体的制备及其电学性能研究

(Ca, Mn)-codoped Ba1-xSrxTiO3 (BST) solid solution, i.e. Ba0.4Sr0.5Ca0.08Mn0.02TiO3, was successfully synthesized via sol-gel process. The product was characterized by TG-DTA thermal analyses, XRD, TEM.The effects of both curing temperature and applied voltage on the resistance, etc. were investigated. It showed that the structure of BST was unable to be changed even though it was codoped by Ca2+ and Mn2+. TEM photographs demonstrated the influence of curing temperature on the morphologies of the tested samples. The dependence of resistance on the curing temperature illustrated that (Ca, Mn)-codoped BST was capable of exhibiting the positive temperature coefficient (PTC) effect at low frequency; nevertheless,it might display the negative temperature coefficient (NTC) effect at other frequencies. The relationships between the resistance and applied voltage revealed that the resistance property of (Ca, Mn)-codoped BST appeared at low frequencies, but its property of capacitive reactance might present at high frequency. These findings mean that the electrical property of BST can be adjusted by codoping method. These phenomena can be explained by the grain boundary resistance effect, Heywang model and ion polarization theory.