实验与理论研究G-四链体中鸟嘌呤自由基阳离子脱质子反应

G-四链体传输空穴的特殊性质使其有望应用于发展分子电子器件.由于鸟嘌呤自由基阳离子（G^·+）脱质子反应会中断空穴传递,影响传递效率,我们对G-四链体AG₃（T₂AG₃）₃中G^·+脱质子过程展开了理论与实验的研究.根据瞬态紫外可见吸收光谱,确定了脱质子产物是G（N（2）-H）^·;通过测量不同温度下G^·+脱N（2）-H质子的速率常数,得到脱质子活化能为20.0±1.0 kJ/mol.进而,采用显性水和连续溶剂化模型相结合的方法模拟G-四链体中G^·+脱质子环境,在M062X/6-31G（d）水平上得到了脱质子势垒（26.4 kJ/mol）.结合实验值,理论计算的势能面描述了G-四链体中G^·+脱N2-H的过程.这些结果为G-四链体在电子器件方面的应用提供了重要依据和指导.     

线性调频步进信号的三种合成方法的对比与分析

首先介绍基于合成距离包络,时域合成和频域合成技术的三种合成距离高分辨线性调频步进信号的方法.在此基础上,对这三种方法在运算量和性能上进行比较,并分析了运动对它们的影响.最后分析了它们在SAR/ISAR中的运用.仿真结果证明了本文分析的正确性.     

Effect of Quinoline on the Phospholipid Profile of Curvularia lunata and Its Microbial Detoxification

Quinoline is an N-heterocyclic compound commonly found in wastewater, especially that derived from coal processing, chemical, and pharmaceutical industries. In the present study, the microscopic fungus Curvularia lunata IM 4417, which is known to degrade various xenobiotics, was used. The aim of the research was to study the elimination of quinoline and its influence on fungal phospholipids, which are considered to be excellent indicators of environmental monitoring. Quinoline biodegradation products and phospholipid contents were analyzed using gas chromatography–mass spectrometry and liquid chromatography–tandem mass spectrometry. C. lunata IM 4417 degraded quinoline, which led to the formation of conjugates of glucose with hydroxylated derivatives of the compound. Toxicity tests (Artoxkit M and Microtox assay) indicated that the elimination of lower concentrations of quinoline was efficient and led to a reduction in sample toxicity. The presence of quinoline also significantly affected the profile of fatty acids and phospholipids. The addition of quinoline to a culture of C. lunata IM 4417 caused an increase in the content of phosphatidylcholine (PC) and a decrease in the amount of phosphatidylethanolamine (PE), two major structural lipids. Additionally, decreases in the contents of phosphatidylinositol (PI) and phosphatidylserine (PS), which are responsible for tolerance to toxic substances, cell viability, and signal transduction, were noted. Thus, it can be concluded that the presence of quinoline modifies the membrane composition, and this change may be an important indicator of the presence of N-heterocyclic compounds or other toxins in the environment.     

中低变质程度煤显微组分结构的13 C-NMR研究

利用13C-NMR核磁共振技术对中低变质程度煤显微组分（镜质组和惰质组）的分子结构进行了研究,计算了5种煤9个显微组分的13C-NMR结构参数,获得了样品的结构特征及变化规律。结果表明,惰质组结构中芳构化程度要高于镜质组;脂碳数量则少于镜质组,芳环上的烷烃侧链也没有镜质组长;随着煤变质程度的提高,煤分子中芳构化程度不断提高,但惰质组的芳香度随变质程度变化的规律明显不如镜质组;在中低变质阶段,对煤化进程起主导作用的的是芳构化作用而不是环缩合作用,但在惰质组中脂碳断裂形成芳环的现象不明显。惰质组中含氧官能团的总量要低于同等变质程度的镜质组。     

北京市企业景气波动的实证分析

根据北京市统计局提供的企业景气指数和企业家信心指数的历史数据,利用假设检验的统计方法,对北京市的经济景气状况进行分析,为经济发展的预测和宏观调控政策提供了有力的依据.     

温度与碱浓度对FeO4^2-/FeO2^-体系电化学行为的影响

研究了影响Fe（OH）3进行酸式电离反应的因素，在多种浓度和温度条件下的NaOH浓溶液中采用SnO2-Sb2O3／Ti电极，研究FeO4^2-/FeO2^-体系的电化学氧化还原反应参数及其变化趋势，结果证实该体系发生电化学氧化还原反应的最佳碱溶液浓度范围为12—14mol／L，最佳温度范围为295～315K．阐明了在实验条件下FeO4^2-/FeO2^-氧化还原体系中存在由FeO4^2-/FeO2^-构成的氧化还原电对，而FeO2不直接与FeO2构成氧化还原电对；并给出了FeO4^2-/FeO2^-氧化还原体系的Latimer图．     

Theory of the resonance escape factors of plasma resonance lines basing on the exact Voigt profile

In this paper, based on the exact Voigt profile we obtained, we derive the theory of resonance escape factors of plasma resonance lines, for both Lorentzian profile and Voigt profile. The oscillator strength, the number density of the absorbing atoms in the ground state, and the optical depth in the line center are discussed. As an example, the helium He I 1083.0 nm, lithium Li I 670.970 nm and carbon C I 111.74 nm are discussed for infrared, visible and ultraviolet regions. The results we calculated are in good agreement with the experimental results. These calculations will be significant in the theoretical analysis of plasma.      

石油测井仪器的稳定性评价方法

为了评价石油测井食品的工作稳定性，将石油测井过程描述为温度剖面图，指出用3个独立的例行试验结果体现石油测井食品工作稳定性存在较大的局限性，为此提出了以多应力试验为核心内容的稳定性评价新方法，在此基础上给出了确定平均稳定工作时间（MWTURE）的方法。以双应力试验为例，说明了评价石油测井食品工作稳定性的具体过程。     

锥形梯度折射率棒透镜中的光线轨迹

本文据据变分法,导出了锥形梯度折射率棒透镜中一种典型光线的轨迹方程。计算结果表明,光线轨迹主要由入射光束的光斑尺寸、倾角和透镜的结构决定。     

基于主动信息服务的信息共享传播技术

信息共享传播方法的结构在本质上可分为两种：信息交换结构与信息广播结构，而主动信息服务作为一种强有力的信息传播方式得到了广泛关注。文中简要探讨了信息分发的基本方法和主动信息服务的关键技术，包括信息的个性化特征与用户肖像模型、元数据信息标引与XML、信息发布与信息过滤技术、以及信息的分布式存储与个性化信息仓储及其意义。