全文获取类型
收费全文 | 3561篇 |
免费 | 540篇 |
国内免费 | 429篇 |
专业分类
化学 | 3352篇 |
晶体学 | 41篇 |
力学 | 20篇 |
综合类 | 22篇 |
数学 | 4篇 |
物理学 | 532篇 |
无线电 | 559篇 |
出版年
2024年 | 3篇 |
2023年 | 61篇 |
2022年 | 85篇 |
2021年 | 133篇 |
2020年 | 148篇 |
2019年 | 152篇 |
2018年 | 110篇 |
2017年 | 138篇 |
2016年 | 200篇 |
2015年 | 218篇 |
2014年 | 213篇 |
2013年 | 318篇 |
2012年 | 292篇 |
2011年 | 194篇 |
2010年 | 184篇 |
2009年 | 201篇 |
2008年 | 206篇 |
2007年 | 234篇 |
2006年 | 185篇 |
2005年 | 223篇 |
2004年 | 160篇 |
2003年 | 142篇 |
2002年 | 115篇 |
2001年 | 69篇 |
2000年 | 73篇 |
1999年 | 54篇 |
1998年 | 72篇 |
1997年 | 72篇 |
1996年 | 44篇 |
1995年 | 44篇 |
1994年 | 30篇 |
1993年 | 32篇 |
1992年 | 24篇 |
1991年 | 22篇 |
1990年 | 11篇 |
1989年 | 13篇 |
1988年 | 11篇 |
1987年 | 9篇 |
1986年 | 4篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 6篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1976年 | 2篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1972年 | 2篇 |
排序方式: 共有4530条查询结果,搜索用时 109 毫秒
191.
This paper describes a simple method for the synthesis of water-soluble, silver nanoparticle-encapsulated β-cyclodextrin by phase transfer of silver nanoparticles from organic to aqueous phase using β-cyclodextrin as a capping agent. β-Cyclodextrin–silver nanoparticle inclusion complex was purified, characterised by spectroscopic and microscopic analyses and tested in vitro against Pseudomonas aeruginosa, Staphylococcus aureus, Serratia marcescens, Escherichia coli and Klebsiella pneumoniae. The silver nanoparticle-encapsulated β-cyclodextrin inclusion complex displayed considerable antimicrobial activity and stability. 相似文献
192.
Hossein Reza Darabi Abbas Darestani Farahani Mohammad Hashemi Karouei Kioumars Aghapoor Rohoullah Firouzi Rainer Herges 《Supramolecular chemistry》2013,25(9):653-657
A new E,E-stilbenophane was synthesised and characterised. The crystal structure of this cyclophane shows that this molecule has a cup-shaped structure, which hosts a phenyl ring of neighbouring molecule as guest in its cavity with a π–π distance of about 3.7 Å. Moreover, the NMR spectra and theoretical analysis (gauge-independent atomic orbitals (GIAO) and quantum theory of atoms in molecules (QTAIM)) suggest that the silver recognition by E,E-stilbenophane host molecules is based on cation–π interactions in which the π-electrons of the double bonds play a major role. 相似文献
193.
194.
195.
A new copper and silver‐mediated cyanation of aryl iodides with DDQ as a cyanide source is achieved, providing nitriles with good yields. This new approach represents a safe method leading to aryl nitriles. 相似文献
196.
采用两步法合成了 sod 基系列分子筛(EMT、FAU、SOD),并通过离子交换法引入 Ag+得到载银分子筛,通过 X 射线衍射(XRD)、扫描电子显微镜(SEM)证明离子交换前后分子筛骨架结构和晶粒尺寸没有发生明显变化;通过红外光谱(IR)、热重(TG)证明制得的载银分子筛具有良好的稳定性;对获得的载银分子筛进行了Ag+释放实验与抗菌能力测试,考察了分子筛种类和晶粒尺寸对抗菌性能的影响。结果表明具有笼状结构的FAU与EMT分子筛因可储存更多的Ag+而具有更好的抗菌性能,而具有超笼结构的 FAU 分子筛抗菌性能最优。通过对比不同晶粒尺寸载银 FAU 分子筛抗菌数据发现,晶粒尺寸为 100 nm 的载银FAU分子筛因外表面丰富的抗菌活性位点以及其内部可以储存并不断释放 Ag+而具有最优的抗菌性能和抗菌寿命。而晶粒尺寸为10 nm的载银FAU分子筛由于晶粒尺寸较小、外比表面积大、扩散路径短,Ag+的释放速率最快,抗菌效率最高。 相似文献
197.
合成了2个配位聚合物{[Cd(btaa)(phen)(CH3COO)]·H2O}n(1)和{[Ag2(btaa)(4,4-bpy)2](NO3)·2H2O}n(2)(Hbtaa=1H-苯并三氮唑-1-乙酸,phen=1,10-邻菲啰啉,4,4-bpy=4,4-联吡啶),采用单晶X-射线、红外光谱、元素分析和热重分析对配合物进行了表征。配合物1中的镉离子通过1H-苯并三氮唑-1-乙酸根桥连成一位螺旋链状结构。在配合物2中,银离子被4,4-联吡啶连接成一维链状结构,这些一维链通过1H-苯并三氮唑-1-乙酸根桥连以及Ag···Ag作用和π-π堆积连接成一维梯子状结构。此外,还研究了配合物1的荧光性质。 相似文献
198.
Determination of Trichloroacetic Acid (TCAA) Using CdO Nanoparticles Modified Carbon Paste Electrode
In this paper, the electrochemical behavior of a carbon paste electrode modified with CdO nanoparticles as a potential electrocatalyst for the reduction of trichloroacetic acid (TCAA) was investigated using cyclic voltammetry and double‐potential step chronoamperometry. The modified electrode showed a great enhancement in cathodic peak current with respect to reduction of TCAA in acidic aqueous solution. Using this increment, a quantitative method was developed for the determination of TCAA in aqueous solution. The detection limit and linear dynamic range of TCAA are 2.3×10?6 M and 2.3×10?4–3×10?6 M, respectively. 相似文献
199.
The combination of coumarin derivative (7-(1,3-dithiolan-2-yl)-9,10-dihydroxy-6H-benzofuro[3,2-c]chromen-6-on), (DC)–titanium dioxide nanoparticles (TiO2) and ionic liquid (IL) yields nanostructured electrochemical sensor, formed a novel kind of structurally uniform and electrocatalytic activity material. This new ionic liquid–TiO2 nanoparticles modified carbon paste electrode (IL–CTP) due to its enhanced conductivity presented very large current response from electroactive substrates. The modified electrode was characterized by different methods including a scanning electron microscope (SEM), electrochemical impedance spectroscopy (EIS) and voltammetry. A pair of well-defined quasi reversible redox peaks of coumarin derivative was obtained at the modified carbon paste electrode (DC/IL–CTP) by direct electron transfer between the coumarin derivative and the CP electrode. Dramatically enhanced electrocatalytic activity was exemplified at the DC/IL–CTP electrode, as an electrochemical sensor to study the electro oxidation of levodopa (LD) and carbidopa (CD). Based on differential pulse voltammetry (DPV), the oxidation of LD and CD exhibited the dynamic range between 0.10– 900.0 μM and 20.0–900.0 μM respectively, and the detection limit (3σ) for LD and CD were 41 nM and 0.38 μM, respectively. DPV was used for simultaneous determination of LD and CD at the DC/IL–CTP electrode, and quantitation of LD and CD in some real samples (such as tablets of Parkin-C Fort and Madopar, Sinemet, water, urine, and human blood serum) by the standard addition method. 相似文献
200.
Navjeet Kaur Pooja Grewal Pranshu Bhardwaj Meenu Devi Neha Ahlawat Yamini Verma 《合成通讯》2013,43(22):3058-3100
The heterocyclic chemistry field has been revolutionized using transition metal catalyst in recent years. Various research groups have focused on the development of general protocols to achieve better functional group compatibilities and greater levels of molecular complexity under mild reaction conditions using easily available starting substrates. These methods afford many advantages as compared to alternative pathways involved in the synthesis of heterocyclic compounds. In this review article, we have concentrated on the synthesis of nitrogen-containing five-membered heterocylces in the presence of silver catalyst. 相似文献