Effect of pH on Poly(acrylic acid) Solution Polymerization

The free-radical redox-initiated aqueous solution polymerization of fully and partially neutralized acrylic acid was carried out at room temperature under full exposure to air. The effect of neutralization degree on the polymerization rate and product properties was studied. Increasing neutralization of the reaction mixture with sodium hydroxide resulted in greater conversion of acrylic acid to sodium acrylate. The rate of polymerization, determined from a gravimetric off-line water removal technique, was shown to decrease significantly with decreasing degree of neutralization. Molecular weight also decreased with decreasing degree of neutralization. The glass transition temperature and hydrophilicity of the polymer product decreased with increasing degree of neutralization. In-line infrared monitoring was also used to monitor the reaction progress and was shown to be an effective tool for this purpose.     

LS解法和Fisher方程行波系统的定性分析

提出了求解非线性发展方程的新方法——LS解法.LS解法是基于(G’/G)展开法和扩展的双曲正切函数展开法.并引入了Poincar定性理论的思想,然后以Fisher方程为例进行了试验.通过定性分析首先获得了Fisher方程行波系统积分曲线的性质,然后解得了Fisher方程作为耗散系统时单调减少的波前解和作为扩张系统时单调递增的波前解.一些试验结果与Ablowitz所得结果一致.也得到了Fisher方程作为扩张系统时的新结果.LS解法是在定性理论指导下,在已获知解曲线性质的情况下进行精确求解的,求解目标明确.LS解法揭示了线性系统也可以用作辅助方程来求解非线性系统.     

高压电场作用下乙醇-水溶液体系变化红外光谱分析

本文报道了用红外光谱分析电磁场作用下乙醇 水溶液体系变化情况。分析结果表明 :当乙醇溶液受到 2 0kV·cm- 1 的交变电磁场处理 (5 0Hz)时 ,分子之间的氢键缔合先增大后减少 ;高乙醇含量溶液受到同样强度电场较长时间处理时 ,有乙醇发生氧化反应 ,从红外谱中可看到νCO 峰及ν(OH) (H2 O) 峰的出现 ;经处理后的溶液自然放置 7天再测定 ,其红外谱图基本保持不变。文中对各出现变化的峰进行了分析 ,并对其机理进行了推导     

Synergistic effects on iodine release in potassium iodide solution by combination of ultrasound and visible light irradiations

Iodine release in potassium iodide solution has been investigated under the irradiations of ultrasound and visible light respectively and simultaneously. We have observed that the amount of iodine liberated under the combined irradiation of ultrasound and visible light is larger than the sum of that under the respective irradiations of ultrasound and visible light, indicating a synergistic effect of ultrasound and visible light irradiations. Based on the investigation of the reaction kinetics of iodine liberated, we have ascribed the synergistic effect to the perfect stirring of the photochemical reactor induced by the applying simultaneous ultrasound. The ideal stirring can result in the homogenization of the primary light effect in the whole reaction medium, which induces the acceleration of the photochemical reaction. On behavior of our knowledge, there are few reports on the investigations of utilizing the combination of ultrasonic energy and light energy to accelerate the reaction yield and rate as well as the kinetics of the reaction.     

一种迭代格式的有限元并行算法*

本文提出了一种求解有限元方程的迭代格式的并行算法.该方法在线性代数方程迭代解法的基础上,引进并行运算步骤;并且运用加权残数方法,通过选择适当的权函数,推导了该并行算法的有限元基本格式.该方法在西安交通大学BLXSI-6400并行计算机上程序实现.计算结果表明它能有效地提高运算速度,减少计算时间,是一种有效的求解大型结构有限元方程的并行算法.     

Positive solutions of singular boundary value problem of negative exponent Emden—Fowler equation

This paper investigates the existence of positive solutions of a singular boundary value problem with negative exponent similar to standard Emden-Fowler equation. A necessary and sufficient condition for the existence of C[0, 1] positive solutions as well as C¹[0, 1] positive solutions is given by means of the method of lower and upper solutions with the Schauder fixed point theorem.     

一类常微分方程组周期解构造的耦合方法

本文通过建立一类常微分方程组的耦合泛函微分方程组，解决其周期解的构造问题．     

GLOBAL CLASSICAL SOLUTIONS WITH SMALL INITIAL TOTAL VARIATION FOR QUASILINEAR HYPERBOLIC SYSTEMS

By means of the continuous Glimm functional,a proof is given on the global existence ofclassical solutions to Cauchy problem for general first order quasilinear hyperbolic systems withsmall initial total rariation.     

一类非线性发展方程的精确解

利用hirota双线性法,得到(3+1)维孤子方程、(3+1)维KP-Boussinesq方程、(2+1)维修正Caudrey-Dodd-Gibbon-Kotera-S awada方程、Hirota-Satsuma浅水波方程的精确解,并做出一部分解的图形,进一步研究解的结构和性质.     

The Two-dimensional Electromagnetic Scattering from Periodic Chiral Structures and Its Finite Element Approximation

In this paper, we consider the electromagnetic scattering from periodic chiral structures. The structure is periodic in one direction and invariant in another direction. The electromagnetic fields in the chiral medium are governed by the Maxwell equations together with the Drude-Born-Fedorov equations. We simplify the problem to a two-dimensional scattering problem and we show that for all but possibly a discrete set of wave numbers, there is a unique quasi-periodic weak solution to the diffraction problem. The diffraction problem can be solved by finite element method. We also establish uniform error estimates for the finite element method and the error estimates when the truncation of the nonlocal transparent boundary operators takes place.