Schiff碱配合物模拟酶催化性能的温度效应研究

研究了新型Schiff碱双锰配合物在模拟酶催化亚碘酰苯单加氧化环已烷反应及 被亚碘酰苯氧化破坏反应中的温度效应。结果表明，在模拟酶催化反应体系中同时 存在催化环已烷单加氧反应及催化剂的氧化破坏反应；催化反应速率及氧化破坏反 应速率均随反应温度升高有规律地增大，但氧化破坏反应比催化反应对反应温度更 敏感；催化反应总产率一般随反应温度升高而降低；最适宜的反应温度为25 ℃。     

The Self-catalytic Esterification Reaction of O-Phosphoryl Serine Derivative

O-Phosphoryl serine derivative can perform serf-catalytic esterification reaction in the mixture of CH3OH and CHCl3 at the room temperature. The phosphoryl group participation was the key step of the esterification. This type of reactions were proposed through an intermediate of mixed phosphoric-carboxylic anhydride that might provide a clue to the function of the phosphoryl group in the phosphorylated enzymes and in the prebiotic synthesis of protein.     

Photocurrent generation in multilayer self-assembly films fabricated from water-soluble poly(phenylene vinylene)

A novel, water-soluble, cationic PPV derivative poly[(2,5-bis(3-bromotrimethylammoniopropoxy)-phenylene-1,4-divinylene)-alt-1,4-(2,5-bis(2-(2-hydroxyethoxy)ethoxy))phenylene vinylene] (BH-PPV) has been synthesized by a Heck coupling reaction. Multilayered assemblies of the BH-PPV and the sodium salt of hexa(sulfobutyl)fullerenes (C(60)-HS) were fabricated successfully by an alternate deposition technique. The multilayer structures were studied by UV/Vis spectroscopy, small angle X-ray diffraction, and atomic force microscopy. The photoinduced charge transfer property of the self-assembled multilayer film was also measured by a three-electrode cell technique. A steady and rapid cathodic 5.5 microA cm(-2) photocurrent response was measured as the irradiation of the multilayer film was switched on and off. Importantly, the response of on/off cycling is prompt and reproducible. A possible mechanism for the electron-transfer process is proposed.     

Supramolecular approaches to generate libraries of chelating bidentate ligands for homogeneous catalysis

The process of catalyst discovery and development relying on combinatorial methods has suffered so far from the difficult access to structurally diverse and large libraries of ligands, in particular the structurally more complex class of bidentate ligands. A completely new approach to streamline the difficult ligand synthesis process is to use structurally less complex monodentate ligands that self-assemble in the coordination sphere of a metal center through noncovalent attractive ligand-ligand interactions to generate bidentate, chelating ligands. When complementary attractive ligand-ligand interactions are employed, it is even possible to generate libraries of defined chelate-ligand catalysts by simply mixing two different monomeric ligands. This Minireview summarizes the first approaches and results in this new field of combinatorial homogeneous catalysis.     

Controllable growth of chains and grids from polyoxomolybdate building blocks linked by silver(I) dimers

Molecular growth processes utilizing a beta-octamolybdate synthon and {Ag2} dimers are described and the directing influence of "encapsulating" cations and coordinating solvent is also demonstrated. The growth of two 1D chains, (nBu4N)2n[Ag2Mo8O26]n (1) and (nBu4N)2n[Ag2Mo8O26(CH3CN)2]n (2), is achieved when nBu4N+ ions are used, and the diameter of the chains can be expanded by the coordination of CH3CN solvent (2). The formation of a type of gridlike structure in which 1D chains are crossed-over each other in alternatively packed layers is achieved in DMSO as the solvent; DMSO acts as a linking group to give (nBu4N)2n[Ag2Mo8O26(dmso)2]n (3), which, similar to 1 and 2, still incorporates the Bu4N+ ions that exert an "encapsulating" influence. However, in (HDMF)n[Ag3(Mo8O26)(dmf)4]n (4) the relatively bulky Bu4N+ ions are exchanged for protonated DMF cations, thereby allowing the chains to condense to a 2D array. The building block concept is further enforced by the isolation of a "monomeric" unit (Ph4P)2[Ag2Mo8O26(dmso)4] (5), which is isolated when the Ph4P+ ions are so "encapsulating" as to prevent aggregation of the {Ag-Mo8-Ag} building blocks. The nature of the AgAg dimers in each of the compounds 1-4 is examined by DFT calculations and the interplay between these Ag-Ag interactions and the structure types is described.     

A new class of low-molecular-weight amphiphilic gelators

A new powerful class of low-molecular-weight amphiphilic compounds has been synthesized and their structure-property relationships with respect to their gelation ability of organic solvents have been investigated. These compounds are able to gel organic solvents over a broad range of polarity. Especially polar solvents such as valeronitrile and gamma-butyrolactone can be gelled even at concentrations far below 1 wt %. It was found that the gelation ability of these asymmetrically substituted p-phenylendiamines depends on a well-balanced relation of the terminal head group, the units involved in hydrogen bonding (amide or urea groups), and on the length of the alkyl chain. With this class of new gelators it is possible to tailor thermal and mechanical properties in different organic solvents and open various application possibilities.     

一种高增益的宽带低噪声放大器的设计

采用SANAN公司的0.25μm E-Mode pHEMT工艺,基于ADS仿真,设计了一款工作频率为2.0～4.2 GHz的两级级联的宽带LNA芯片。芯片采用电阻偏压的方式,实现了3.3 V单电源供电。同时,设计了一种改进型的RLC并联负反馈结构,实现了宽带匹配。仿真结果表明,该LNA在2.0～4.2 GHz频段内,最大增益为30.9 dB,增益平坦度为±0.6 dB左右,输入回波损耗小于-9 dB,输出回波损耗小于-12 dB;噪声系数为(1.2±0.14) dB;系统稳定性因子K在全频带内大于2.8;芯片面积为0.78 mm×2.2 mm。     

智慧水文应用数字孪生5G专网用户自运营管理实践研究--以曲靖市5G智慧水文面店示范站项目为例

中国移动助力云南省曲靖市落地5G智慧水文面店示范站项目实践,融合5G、北斗、云计算、物联网、数字孪生等新技术,基于中国移动OneLink平台和OneNET平台定制开发了曲靖水文5G数字孪生运用管理云平台,提供软硬件总集成服务成功打造曲靖市5G+智慧水文面店示范站。该实践树立了5G专网用户自运营管理的成功标杆,为水文行业以及对5G专网用户自运营管理有需求的政府及企事业单位起到成功案例借鉴复制作用。     

基于无人机影像的电网绝缘子自爆识别

电网因其在电能传输方面的关键性作用,在我国民生项目建设领域一直扮演着至关重要的角色。电网杆塔上的绝缘子一旦发生自爆(也称“缺陷”),绝缘子会自动剥落,输电线路就会产生安全隐患,严重时会降低输电线路的运行寿命,甚至会引发供电中断,发生大范围的停电事故,造成巨大的财产损失。目前,主流的巡检方法为人工巡检,该方法不仅耗时耗力,而且也存在一定主观出错率,已不适用于目前电路巡检的实际情况。本设计采用YOLO V5网络模型,对无人机航拍影像中绝缘子串及绝缘子自爆进行自动识别。首先通过平移、翻转、裁剪等,对航拍绝缘子影像数据集进行数据增广,并对增广后的数据集在LabelImg中进行标注,然后利用YOLO V5网络模型对绝缘子串及绝缘子自爆进行识别,最后采用PyQt5框架在PyCharm中设计了绝缘子自爆识别的系统界面,对模型进行调用,实现了绝缘子串及绝缘子自爆识别。本设计采用从网络上下载、国家电网提供、数据增广所得到的500张无人机航拍影像作为数据集,对所得数据集进行人工标注,再使用YOLO V5网络模型进行训练和测试,结果表明YOLO V5网络模型对绝缘子串具有较高的识别精度,最高识别精度为90.2%,对绝缘子自爆的最高检测精度为80.8%。这说明了YOLO V5网络模型在绝缘子串识别方面有较好的表现,但是由于训练集中绝缘子自爆的样本影像数量有限,所以该网络模型对绝缘子的自爆识别存在一定局限性,本实验能够部分代替人力实现电网绝缘子智能巡检,提高了检测效率。