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971.
The molecular order within the hydrophobic core of membranes of the diene lipid di-tetradecadienoylphosphatidylcholine was studied by means of infrared spectroscopy on multibilayer assemblies which orient macroscopically on the surface of an attenuated total reflection crystal. The relative humidity and temperature were used as variable parameters to demonstrate that there were profound differences in the melting transition of lipids possessing predominantly cis and trans diene groups. The cis isomer undergoes the phase transition at a vapor pressure which is increased by 0.15 GPa when compared with that of the trans isomer. The methylene wagging band progression gives no indication of differences between the acyl chain conformation of the cis and trans forms in the gel state. The frequencies of a number of absorption bands of the diene groups reveal that these moieties are predominantly in the s-trans conformation to accommodate a favorable packing within the bilayer. The linear dichroism of selected in-plane and out-of-plane vibrations of the diene groups gives indications of the biaxial ordering of these moieties. We present the basic equations for the quantitative analysis of IR dichroism data of lamellar structures in terms of transverse and longitudinal molecular order parameters. It turns out that the planes of the rigid diene groups orient preferentially in a perpendicular direction with respect to the bilayer surface and parallel to each other forming in this way a layer of well-aligned diene groups in the bilayer center. This finding is confirmed by the results of X-ray measurements. We suggest that the partial interdigitation of the diene groups of the sn-1 acyl chains promotes the formation of the inverse HII phase and/or enables the formation of covalent bonds between both the monolayers upon polymerization of diene lipids. 相似文献
972.
Omar De la Cruz Eric Hall Paul Howard Kyriakos Keremedis Jean E. Rubin 《Mathematical Logic Quarterly》2003,49(1):57-71
This is a continuation of [2]. We study the Tychonoff Compactness Theorem for various definitions of compactness and for various types of spaces (first and second countable spaces, Hausdorff spaces, and subspaces of ?K). We also study well ordered Tychonoff products and the effect that the multiple choice axiom has on such products. 相似文献
973.
多维正态分布均值在序约束下的假设检验 总被引:1,自引:0,他引:1
在序限制下的统计推断是统计分析中的一个重要领域,保序回归理论在这个领域中起着关键性的作用。多维保序回归是一维保序回归的推广,本文给出了k=2,p=2时多维保序回归的求解方法。令Xij,j=1,2…,n是来自总体为二维正态分布N(μi,Λ)的样本,这是μi是未知的,Λ是已知的,i=1,2。令μ=(μ1,μ2),-={(μ1,μ2)|μ1,μ∈R^2,}-0={(μ1,μ2)|μ1≤μ2,μ1,μ2∈R^2}。μ1≤μ2表示μ2-μ1的每一个分量为非负。本文也讨论了假设检验问题H0:μ∈-0,H1:μ∈-0=---0(H0是零假设)。 相似文献
974.
Fabio Paronetto 《Journal of Differential Equations》2006,226(2):525-540
We give an existence and uniqueness result for a linear abstract evolution equation of second order with some coefficient in front of the second temporal derivative which may degenerate to zero and change sign. 相似文献
975.
矩形校正公式的误差分析 总被引:1,自引:0,他引:1
This paper presents truncation errors among Corrector Formula for left Rectangular rule and Corrector Formula for middle Rectangular rule respectively.It also displays an analysis on convergence order of compound corrector formulas for rectangular rule.Examples of numerical calculation have validated theoretical analysis. 相似文献
976.
Worst allocations of policy limits and deductibles 总被引:1,自引:1,他引:0
In the literature, orderings of optimal allocations of policy limits and deductibles were established with respect to a policyholder’s preference. However, from the viewpoint of an insurer, the orderings are not enough for the purpose of pricing. In this paper, by applying the equivalent utility premium principle, we study worst allocations of policy limits and deductibles for an insurer, which give rise to the maximum fair premiums. Closed-form solutions are derived. Then we present a result concerning the optimality in a general risk-sharing scheme, by which we obtain optimal allocations for policyholders directly from worst allocations for an insurer. Several results in Cheung [Cheung, K.C., 2007. Optimal allocation of policy limits and deductibles. Insurance Math. Econom. 41, 382–391] are generalized here. 相似文献
977.
利用高阶累积量实现数字调制信号的自动识别 总被引:9,自引:0,他引:9
通信信号的自动调制识别在截获信号处理方面是一个十分重要的课题。本文针对数字调制信号的识别问题,提出了一种基于高阶累积量的分类特征,该特征有效地抑制高斯白噪声的影响,能实现对2ASK、4ASK、4PSK、2FSK、4FSK等五种数字调制信号的识别。论文进行了理论推导,并用仿真实验和实际采集数据进行了验证。 相似文献
978.
The application of unsteady computational fluid dynamics (CFD) codes to aeroelastic calculations leads to a large number of degrees of freedom making them computationally expensive. Reduced‐order models (ROMs) have therefore been developed; an ROM is a system of equations which is able to reproduce the solutions of the full set of equations with reasonable accuracy, but which is of lower order. ROMs have been the focus of research in various engineering situations, but it is only relatively recently that such techniques have begun to be introduced into CFD. In order for the reduced systems to be generally applicable to aeroelastic calculations, it is necessary to have continuous time models that can be put into discrete form for different time steps. While some engineering reduction schemes can produce time‐continuous models directly, the majority of methods reported in CFD initially produce discrete time or discrete frequency models. Such models are restricted in their applicability and in order to overcome this situation, a continuous time ROM must be extracted from the discrete time system. This process can most simply be achieved by inverting the transformation from continuous to discrete time that was initially used to discretize the CFD scheme. However an alternative method reported in literature is based on continuous time sampling, even when this is not used for the initial discretization of the CFD code. This paper focuses on one particular method for ROM generation, eigensystem realization algorithm (ERA), that has been used in the CFD field. This is implemented to produce a discrete time ROM from a standard CFD code, that can be used to investigate methods for obtaining continuous ROMs and the limitations of the resulting models. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
979.
Random‐walk models are a versatile tool for modelling dispersion of both passive and active tracers in turbulent flow. The physical and mathematical foundations of stochastic Lagrangian models of turbulent diffusion have become more and more solid over the years. An important aspect of these types of models that has not received much attention is the behaviour of the particles near boundaries. Often, a simple stochastic, numerical scheme is used. Because turbulent mixing in the vertical direction is much more complicated than in the two horizontal directions, it is in the vertical direction that a simple numerical scheme, such as the Euler scheme, may cause problems. In this paper our main goal is the development of an efficient 3D particle transport model that can be used in stratified flow. For this type of situation the vertical direction is of special interest. First, a closer look is taken at some considerations that should be regarded when choosing a numerical scheme. Specifically schemes are investigated that can be used in the vertical direction, where the diffusion coefficient is varying in that direction. Experiments are performed regarding the accuracy of different numerical schemes in various situations. The behaviour of the particles near an impermeable layer interface is investigated. The stochastic Heun and Runge–Kutta schemes turn out to be very attractive for this type of model. For the simulation of the transport of various physical quantities, such as salinity, heat, silt, oxygen, or bacteria, different types of models are available. In this case we will take a closer look at the modelling of the transport of pollutants from point sources (either instantaneous or continuous transport). For this purpose a 3D particle transport model has been developed that is especially suited for stratified situations such as can be found in estuaries. The main idea is to use a simple numerical scheme for the horizontal directions and a higher‐order method for the vertical direction. The results play an important role in making specific choices for this type of particle transport model. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
980.
Volker John 《国际流体数值方法杂志》2006,50(7):845-862
This paper studies the efficiency of two ways to treat the non‐linear convective term in the time‐dependent incompressible Navier–Stokes equations and of two multigrid approaches for solving the arising linear algebraic saddle point problems. The Navier–Stokes equations are discretized by a second‐order implicit time stepping scheme and by inf–sup stable, higher order finite elements in space. The numerical studies are performed at a 3D flow around a cylinder. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献