Integrated chemical sensor array platform based on a light emitting diode, xerogel-derived sensor elements, and high-speed pin printing

We report a new, solid-state, integrated optical array sensor platform. By using pin printing technology in concert with sol-gel-processing methods, we form discrete xerogel-based microsensor elements that are on the order of 100 μm in diameter and 1 μm thick directly on the face of a light emitting diode (LED). The LED serves as the light source to excite chemically responsive luminophores sequestered within the doped xerogel microsensors and the analyte-dependent emission from within the doped xerogel is detected with a charge coupled device (CCD). We overcome the problem of background illumination from the LED reaching the CCD and the associated biasing that results by coating the LED first with a thin layer of blue paint. The thin paint layer serves as an optical filter, knocking out the LEDs red-edge spectral tail. The problem of the spatially-dependent fluence across the LED face is solved entirely by performing ratiometric measurements. We illustrate the performance of the new sensor scheme by forming an array of 100 discrete O₂-responsive sensing elements on the face of a single LED. The combination of pin printing with an integrated sensor and light source platform results in a rapid method of forming (∼1 s per sensor element) reusable sensor arrays. The entire sensor array can be calibrated using just one sensor element. Array-to-array reproducibly is <8%. Arrays can be formed using single or multiple pins with indistinguishable analytical performance.     

The investigation of the (p,ρ,T) and (ps,ρs,Ts) properties of {(1−x)CH3OH + xLiBr} for the application in absorption refrigeration machines and heat pumps

The (p,ρ,T) and (p_s,ρ_s,T_s) properties of {(1−x)CH₃OH + xLiBr} over a wide range of state parameters are reported for the first time. The experiments were carried out in a constant volume piezometer over a temperature range from 298.15 K to 398.15 K, at 0.08421, 0.13617, 0.19692, 0.23133 and 0.26891 mole fractions and from atmospheric pressure up to 60 MPa. The experimental uncertainties are ΔT=±3 mK for temperature, Δp=±5·10⁻² MPa for high pressure and Δp=±5·10⁻⁴ MPa for atmospheric pressure, Δρ=±3·10⁻² kg · m⁻³ for density. An equation of state was derived for correlation of the experimental data of the solutions.     

A polypyrrole/polymethylene pattern on gold using a micro-contact printing technique

A micro-contact printing technique was used to fabricate a polypyrrole/polymethylene pattern on a gold surface. ω-(N-Pyrroyl)undecanethiol (PyC₁₁SH) acts as ink for the generation of a pyrrole-terminal monolayer patterned on gold. This monolayer-patterned surface functions as a resist for the selective growth of polymethylene by catalytic decomposition of diazomethane on the gold surface. It also functions as a monomer for the electrochemical polymerization of pyrrole on the PyC₁₁SH monolayer-patterned surface. The polypyrrole/polymethylene pattern was fabricated by an electrochemical polymerization method. The polypyrrole was grown on the pyrrole-patterned surface by potential scanning between 0.0 and 1.2 V vs. Ag wire. The thickness of the polypyrrole growth increases with the increasing number of cycles. The structural features of the patterned surface can be determined by scanning electron microscopy and atomic force microscopy. Electronic Publication     

全自动电脑横机控制系统的设计

介绍了一种全自动电脑横机控制系统的新型分层体系设计.在该体系中,花型准备系统是基于Windows的开放式编程系统,通过编译自动生成编织指令数据文件,提供了独有的可扩充布纹库.下位NC硬件控制系统无需操作系统支持,便可完成对整个编织过程的实时监控,故障诊断,修改编织参数及测试执行部件等功能.新型的分层体系实现了上、下位机的功能独立,并保持了良好的人机交互界面和便捷的操作性,真正实现了全自动和智能化设计.     

MPOF切割机温度控制系统的设计

微结构聚合物光纤(MPOF)是一种新型的聚合物光纤,其主要特征是在包层中有形状、大小、排列不同的空气孔.因为材料的特性,聚合物光纤的切割以及端面处理要比石英光纤复杂得多,尤其对于具有微结构的聚合物光纤更是如此.影响光纤切割质量的因素很多,其中切割时切割机的温度是决定光纤切割质量的关键.因此,设计了一种以单片机作为核心部件的切割机温度精确控制系统.该系统工作稳定,性能可靠,能够满足实验需要.     

基于纹理的图像字符自动定位技术对比研究

随着信息技术的迅速发展,基于内容的图像检索技术引起了研究者的广泛关注.自动抽取图像/视频的语义内容是图像/视频检索中研究的重点和难点.本文通过分析多种字符定位技术,给出了基于纹理分析的字符定位算法的一般框架.对各种基于纹理分析的字符定位方法进行了对比研究,尤其深入地研究了纹理特征提取,分类器设计及边界位置确定对定位结果的影响.最后通过预分类的方法对算法进行改进,实验结果表明,该方法在保持正确定位率基本不变的情况下,可以大幅度提高处理速度.     

基于支持向量机的凝血功能诊断模型

使用凝血四项指标诊断凝血功能是临床的常规检查,但根据经验进行诊断正确率不高.剔除临床上最重要的指标FIB后,建立支持向量机模型诊断的正确率和根据凝血四项指标诊断的正确率没有显著差异,100次模拟的平均正确率分别达到了95.4496%和95.5039%.     

Solution processable PEDOT:PSS based hybrid electrodes for organic field effect transistors

We report high performance solution processed conductive inks used as contact electrodes for printed organic field effect transistors (OFETs). Poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) electrodes show highly improved very low sheet resistance of 65.8 ± 6.5 Ω/square (Ω/□) by addition of dimethyl sulfoxide (DMSO) and post treatment with methanol (MeOH) solvent. Sheet resistance was further improved to 33.8 ± 8.6 Ω/□ by blending silver nanowire (AgNW) with DMSO doped PEDOT:PSS. Printed OFETs with state of the art diketopyrrolopyrrole-thieno[3,2-b]thiophene (DPPT-TT) semiconducting polymer were demonstrated with various solution processable conductive inks, including bare, MeOH treated PEDOT:PSS, single wall carbon nanotubes, and hybrid PEDOT:PSS-AgNW, as the source and drain (S/D) electrode by spray printing using a metal shadow mask. The highest field effect mobility, 0.49 ± 0.03 cm² V⁻¹ s⁻¹ for DPPT-TT OFETs, was obtained using blended AgNW with DMSO doped PEDOT:PSS S/D electrode.     

Direct Toner Printing: A Versatile Technology for Easy Fabrication of Flexible Miniaturized Electrodes

We reported here three simple, low cost and easy to accomplish strategies for the fabrication of microelectrodes and other conductive patterns using ordinary office laser‐printers. In this work, toner patterns were directly printed onto the flexible substrate, acting as a mask to create the intended conductive design. To highlight the versatility of such technology, toner‐printed patterns were employed in two diverse ways: one in which the patterned toner had the exact design of the electrode and other employing a reverse toner‐printed pattern. The first one was used for the adaptation of the well‐known printed circuit board (PCB) fabrication technique, but using direct toner printing (DTP) in an already conductive flexible substrate. The second was employed for the two remaining strategies: one based on the deposition of conductive film, followed by lift‐off process; and another based on drop‐casting of a conductive ink into the formed toner cavities, followed by thermal cure. As proof‐of‐concept, all three DTP strategies were used for the fabrication of miniaturized gold electrodes in polyimide substrate, and electrochemical performance of each obtained electrode was evaluated by cyclic voltammetry. Insights about DTP technology, alignment issues, advantages, limitations and resolution of each presented approach were provided. Finally, direct toner printing showed to be a simple, affordable and quite promising technology for the fabrication of low cost point‐of‐care electrochemical devices using flexible platforms.     

现代检测技术在数控机床中的应用

介绍现代检测技术及检测装置在数控机床中的应用,详细分析位置检测装置在数控机床中的重要作用,归纳总结检测元件发生故障的原因,以达到经验共享的目的。