全文获取类型
收费全文 | 16640篇 |
免费 | 2620篇 |
国内免费 | 1140篇 |
专业分类
化学 | 2874篇 |
晶体学 | 55篇 |
力学 | 1018篇 |
综合类 | 131篇 |
数学 | 3023篇 |
物理学 | 4607篇 |
无线电 | 8692篇 |
出版年
2024年 | 62篇 |
2023年 | 162篇 |
2022年 | 238篇 |
2021年 | 325篇 |
2020年 | 497篇 |
2019年 | 482篇 |
2018年 | 440篇 |
2017年 | 627篇 |
2016年 | 745篇 |
2015年 | 764篇 |
2014年 | 1128篇 |
2013年 | 1186篇 |
2012年 | 1092篇 |
2011年 | 1274篇 |
2010年 | 910篇 |
2009年 | 981篇 |
2008年 | 1109篇 |
2007年 | 1089篇 |
2006年 | 1031篇 |
2005年 | 801篇 |
2004年 | 701篇 |
2003年 | 748篇 |
2002年 | 605篇 |
2001年 | 547篇 |
2000年 | 499篇 |
1999年 | 397篇 |
1998年 | 322篇 |
1997年 | 255篇 |
1996年 | 199篇 |
1995年 | 163篇 |
1994年 | 116篇 |
1993年 | 138篇 |
1992年 | 117篇 |
1991年 | 87篇 |
1990年 | 71篇 |
1989年 | 82篇 |
1988年 | 52篇 |
1987年 | 48篇 |
1986年 | 37篇 |
1985年 | 42篇 |
1984年 | 47篇 |
1983年 | 18篇 |
1982年 | 28篇 |
1981年 | 22篇 |
1980年 | 28篇 |
1979年 | 31篇 |
1978年 | 12篇 |
1977年 | 12篇 |
1975年 | 6篇 |
1973年 | 9篇 |
排序方式: 共有10000条查询结果,搜索用时 687 毫秒
11.
Design and development of a two‐dimensional system based on hydrophilic and reversed‐phase liquid chromatography with on‐line sample treatment for the simultaneous separation of excreted xenobiotics and endogenous metabolites in urine
下载免费PDF全文
![点击此处可从《Biomedical chromatography : BMC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Diego García‐Gómez Encarnación Rodríguez‐Gonzalo Rita Carabias‐Martínez 《Biomedical chromatography : BMC》2015,29(8):1190-1196
In the present work we describe a two‐dimensional liquid chromatographic system (2D‐LC) with detection by mass spectrometry (MS) for the simultaneous separation of endogenous metabolites of clinical interest and excreted xenobiotics deriving from exposure to toxic compounds. The 2D‐LC system involves two orthogonal chromatographic modes, hydrophilic interaction liquid chromatography (HILIC) to separate polar endogenous metabolites and reversed‐phase (RP) chromatography to separate excreted xenobiotics of low and intermediate polarity. Additionally, the present proposal has the novelty of incorporating an on‐line sample treatment based on the use of restricted access materials (RAMs), which permits the direct injection of urine samples into the system. The work is focused on the instrumental coupling, studying all possible options and attempting to circumvent the problems of solvent incompatibility between the RAM device and the two chromatographic columns, HILIC and RP. The instrumental configuration developed, RAM‐HILIC‐RPLC‐MS/MS, allows the simultaneous assessment of urinary metabolites of clinical interest and excreted compounds derived from exposure to toxic agents with minimal sample manipulation. Thus, it may be of interest in areas such as occupational and environmental toxicology in order to explore the possible relationship between the two types of compounds. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
12.
基于传统AI-EBG结构,提出了一种小尺寸的增强型电磁带隙结构,实现了从0.5~9.4 GHz的宽频带-40 dB噪声抑制深度,且下截止频率减少到数百MHz,可有效抑制多层PCB板间地弹噪声。文中同时研究了EBG结构在高速电路应用时的信号完整性问题,使用差分信号方案可改善信号完整性。 相似文献
13.
A new asymmetric Salamo‐based ligand H2L was synthesized using 3‐tert‐butyl‐salicylaldehyde and 6‐methoxy‐2‐[O‐(1‐ethyloxyamide)]‐oxime‐1‐phenol. By adjusting the ratio of the ligand H2L and Cu (II), Co (II), and Ni (II) ions, mononuclear, dinuclear, and trinuclear transition metal (II) complexes, [Cu(L)], [{Co(L)}2], and [{Ni(L)(CH3COO)(CH3CH2OH)}2Ni] with the ligand H2L possessing completely different coordination modes were obtained, respectively. The optical spectra of ligand H2L and its Cu (II), Co (II) and Ni (II) complexes were investigated. The Cu (II) complex is a mononuclear structure, and the Cu (II) atom is tetracoordinated to form a planar quadrilateral structure. The Co (II) complex is dinuclear, and the two Co (II) atoms are pentacoordinated and have coordination geometries of distorted triangular bipyramid. The Ni (II) complex is a trinuclear structure, and the terminal and central Ni (II) atoms are all hexacoordinated, forming distorted octahedral geometries. Furthermore, optical properties including UV–Vis, IR, and fluorescence of the Cu (II), Co (II), and Ni (II) complexes were investigated. Finally, the antibacterial activities of the Cu (II), Co (II), and Ni (II) complexes were explored. According to the experimental results, the inhibitory effect was found to be enhanced with increasing concentrations of the Cu (II), Co (II), and Ni (II) complexes. 相似文献
14.
Hisatoyo Morinaga Natsumi Ogawa Mayu Sakamoto Hiroshi Morikawa 《Journal of polymer science. Part A, Polymer chemistry》2019,57(24):2466-2473
The thiol‐ene reaction between trans‐limonene oxide (trans‐LO) and ethane‐1,2‐dithiol in the presence of triethylborane affords a bio‐based bis‐functional epoxide (bis‐trans‐LO). The crosslinking reaction of bis‐trans‐LO with branched polyethyleneimine (BPEI; Mn = 600; BPEI600) at a feed ratio of bis‐trans‐LO/BPEI600 = 57/43 (wt/wt) yields the corresponding network polymer with Td10 (10% thermal decomposition temperature) of 304.7 °C in 98% yield. In contrast, negligible amounts of network polymer are obtained by the reaction of bis‐LO (bis‐functional epoxide derived from cis and trans‐LO) and BPEI600 regardless of the feed ratio. The mechanical strengths as measured by direct tensile tests of the network polymers derived from bis‐trans‐LO and BPEI600,1800 (Mn = 600 and 1800) were approximately 16 and 11 times higher than that of bis‐LO and BPEI1800, respectively. The tensile shear strengths of the metal‐to‐metal adhesive bonds induced by bis‐trans‐LO and BPEI600,1800 were 9.5 and 14.1 MPa, respectively. DMA revealed that the storage modulus of the network polymer derived from bis‐trans‐LO and BPEI1800 in the rubber region was higher than that of the material prepared from bis‐LO and BPEI1800, indicating higher crosslink density of the bis‐trans‐LO/BPEI1800 system. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 2466–2473 相似文献
15.
1-read/1-write (1R1W) register file (RF) is a popular memory configuration in modern feature rich SoCs requiring significant amount of embedded memory. A memory compiler is constructed using the 8T RF bitcell spanning a range of instances from 32 b to 72 Kb. An 8T low-leakage bitcell of 0.106 μm2 is used in a 14 nm FinFET technology with a 70 nm contacted gate pitch for high-density (HD) two-port (TP) RF memory compiler which achieves 5.66 Mb/mm2 array density for a 72 Kb array which is the highest reported density in 14 nm FinFET technology. The density improvement is achieved by using techniques such as leaf-cell optimization (eliminating transistors), better architectural planning, top level connectivity through leaf-cell abutment and minimizing the number of unique leaf-cells. These techniques are fully compatible with memory compiler usage over the required span. Leakage power is minimized by using power-switches without degrading the density mentioned above. Self-induced supply voltage collapse technique is applied for write and a four stack static keeper is used for read Vmin improvement. Fabricated test chips using 14 nm process have demonstrated 2.33 GHz performance at 1.1 V/25 °C operation. Overall Vmin of 550 mV is achieved with this design at 25 °C. The inbuilt power-switch improves leakage power by 12x in simulation. Approximately 8% die area of a leading 14 nm SoC in commercialization is occupied by these compiled RF instances. 相似文献
16.
ZnO基薄膜晶体管的研究 总被引:2,自引:1,他引:1
ZnO是一种宽带隙的光电半导体材料,能应用于很多领域,如可用在压敏变阻器、声表面波器件、气敏元件、紫外光探测等。ZnO也可以作为有源层应用于薄膜晶体管(TFT)中。ZnO基薄膜晶体管具有以下突出优势:对于可见光部分平均具有80%以上的透射率,迁移率可以高达36cm2/V·s,开/关电流比大于106,可在较低温度(甚至室温)下制备。基于这些优点,ZnOTFT具有取代有源矩阵液晶显示器中常规a-SiTFT的趋势。同时对ZnOTFT的研究也推动了透明电子学的发展。本文阐述了ZnOTFT优越的电学性能,指出了其目前尚存在的不足,并对其发展前景进行了展望。 相似文献
17.
18.
With the proliferation of mobile computing technologies, location based services have been identified as one of the most promising
target application. We classify mobile information service domains based on feature characteristics of the information sources
and different patterns of mobile information access. By carefully examining the service requirements, we identify the dynamic
data management problem that must be addressed for effective location based services in mobile environments. We then devise
a general architecture and cost model for servicing both location independent and location dependent data. Based on the architecture
and cost model, we propose a set of dynamic data management strategies that employs judicious caching, proactive server pushing
and neighborhood replication to reduce service cost and improve response time under changing user mobility and access patterns.
Detail behavior analysis helps us in precisely capturing when and how to apply these strategies. Simulation results suggest
that different strategies are effective for different types of data in response to different patterns of movement and information
access.
Shiow-yang Wu is an associate professor of the Department of Computer Science and Information Engineering at National Dong Hwa University,
Hualien, Taiwan, R.O.C. He received the BS and MS degrees in computer engineering from National Chiao Tung University, Hsinchu,
Taiwan, ROC, and the PhD degree in computer science from the University of Texas at Austin in 1984, 1986, and 1995, respectively.
His research interests include data/knowledge bases, mobile computing, distributed processing, intelligence information systems,
and electronic commerce.
Kun-Ta Wu was born in Taipei, Taiwan, R.O.C., in 1976. He received the B.S. degree in computer science from Soochow University, Taipei,
Taiwan, R.O.C., in 1999 and the M.S. degree in computer science and information engineering from National Dong Hwa University,
Hualien, Taiwan, R.O.C., in 2001.
Currently, he is an Assistant Researcher in the Domestic Division at Science and Technology Information Center, National Science
Council, R.O.C., as a member of Information Gathering and Analysis Group of National Information and Communication Security
Taskforce. His research interests include mobile computing, wireless network and information security. 相似文献
19.
2.5GHz低相位噪声CMOS LC VCO的设计 总被引:5,自引:2,他引:3
用0 .35μm、一层多晶、四层金属、3.3V的标准全数字CMOS工艺设计了一个全集成的2 .5 GHz L C VCO,电路采用全差分互补负跨导结构以降低电路功耗和减少器件1/ f噪声的影响.为了减少高频噪声的影响,采用了在片L C滤波技术.可变电容采用增强型MOS可变电容,取得了2 3%的频率调节范围.采用单个16边形的对称片上螺旋电感,并在电感下加接地屏蔽层,从而减少芯片面积,优化Q值.取得了在离中心频率1MHz处- 118d Bc/ Hz的相位噪声性能.电源电压为3.3V时的功耗为4 m A. 相似文献
20.
拖曳天线的运动感应电磁噪声对其收信深度及接收性能占据主导作用,其中横向振动与纵向振动是主要的,同时扭转振动也不可忽略.建立了磁场天线的扭转振动模型,得到了流体圆周切变力作用下磁场天线的扭转振动响应,分析了扭转振动感应电磁噪声的产生机理,给出了计算公式及仿真结果.研究结果为水下电磁噪声的深入研究提供了理论基础. 相似文献