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排序方式: 共有123条查询结果,搜索用时 15 毫秒
1.
Yakhvarov D. G. Budnikova Yu. H. Tazeev D. I. Sinyashin O. G. 《Russian Chemical Bulletin》2002,51(11):2059-2064
The material of the sacrificial anode has a substantial effect on the nature and yield of the target products of electrochemical phosphorylation of organic halides by white phosphorus in the presence of the nickel complexes with 2,2"-bipyridine. The use of the zinc anode results in the products with tricoordinated phosphorus, viz., triorganylphosphines, the reaction on the aluminum anode affords triorganylphosphine oxides, and the presence of Mg2+ ions in the reaction mixture provides the transformation of white phosphorus into cyclic phosphines (PhP)5. 相似文献
2.
Dr. Aleksandra Mitrović Stefan Wild Vicent Lloret Michael Fickert Dr. Mhamed Assebban Dr. Bence G. Márkus Prof. Ferenc Simon Dr. Frank Hauke Dr. Gonzalo Abellán Prof. Andreas Hirsch 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(10):3361-3366
Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P-MAS NMR, and X-ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG-GC-MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer-like reaction. 相似文献
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运用高选择比的特别配方来释放MEMS可变电容制作工艺中的牺牲层,以保护上级板金属铝层,同时很好地释放牺牲层磷硅玻璃。探讨了上级板的粘附问题,对工艺中影响成品率的关键因素残余应力进行了模拟,当温度T为350℃时,平面应力P为811.6 MPa;当温度T为500℃时,平面应力P为1 185.9 MPa。分析了残余应力对上级板的影响和对悬臂梁的等效弹性系数的影响。 相似文献
6.
Najwa Sbei Belen Batanero Fructuoso Barba Beya Haouas Mohamed Lamine Benkhoud Isidoro Barba 《Tetrahedron》2018,74(16):2068-2072
A new series of 3,4-disubstituted quinazolin-2-ones, with potential T-type calcium channel antagonist activity, and new 4-methylene-quinazolin-2-ones, promising catalysts as N-heterocyclic olefins, have been prepared in good yield by a simple reaction between 2-aminobenzophenone, or 2-aminoacetophenone, and cyanomethyl anion electrogenerated by acetonitrile reduction at a graphite electrode, followed by the addition of different organic isocyanates and subsequent heterocyclization. 相似文献
7.
This article reviews the current status of high-density capacitor for volatile memory devices. The dielectric properties for both the Ta2O5 film and the (Ba, Sr)TiO3 (BST) dielectric materials using either the metal organic chemical vapor deposition (MOCVD) or the atomic layer deposition (ALD) are reviewed briefly. New challenges of dielectric material for the next generation, and serious problems emerged during integration to date using Ta2O5 and BST. The material characteristics of many electrode materials for the high dielectric materials are introduced. We present the basic properties and integration issued for MOCVD-ruthenium (Ru). The second part of this review summarized the failure mechanisms from barrier properties of previously reported diffusion barriers and emphasizes new design concepts of diffusion barrier for high-density memory devices. Finally, the future direction for a diffusion barrier to advance high-density memory capacitors is suggested. 相似文献
8.
牺牲层腐蚀二维数值模拟与仿真 总被引:1,自引:0,他引:1
建立了基于扩散方程的二维腐蚀模型,并给出相应的边界条件.为求解二维扩散方程,分别给出了有限差分显式和隐式求解算法.得到了每一时刻溶液在具体位置的浓度值,再由Topography模型计算腐蚀前端面的腐蚀情况得到腐蚀前端行进轮廓线.编程实现了对多种不同牺牲层几何结构以及组合结构腐蚀过程的仿真,最后实验验证了模拟的真实性. 相似文献
9.
对不同结构,即直沟道结构、冒泡结构和组合沟道结构的氢氟酸牺牲层腐蚀进行了研究.以往的牺牲层腐蚀模型和实验结果不能很好地吻合.以往的模型和实验结果的误差随着腐蚀时间的增加而增大.本文提出了一个修正模型,在修正模型中:HF的扩散系数是浓度和温度的函数;腐蚀速率常数是温度的函数;此外还考虑了腐蚀产物对腐蚀过程的影响.对于组合沟道结构,对腐蚀前端形状的描述采用了一个新的数学模型.实验结果和以往的模型以及修正模型进行了对比,结果表明修正模型能够和实验结果吻合得很好. 相似文献
10.
Mateusz Kuczyski Mateusz uba Tomasz Mikoajczyk Bogusaw Pieroyski Agnieszka Jasiecka-Mikoajczyk Lech Smoczyski Piotr Soowiej Pawe Wojtacha 《Molecules (Basel, Switzerland)》2021,26(15)
Traditional wastewater purification processes are based on a combination of physical, chemical, and biological methods; however, typical electrochemical techniques for removing pollutants require large amounts of electrical energy. In this study, we report on a process of wastewater purification, through continuous anodic dissolution of iron anode for aerated Cu/Fe galvanic cell in synthetic Na2SO4 wastewater solution. Electrochemical experiments were conducted by means of a laboratory size electrolyzer, where electrocoagulation along with electrooxidation phenomena were examined for wastewater containing Acid Mixture dye. The above was visualized through the employment of electrochemical (cyclic voltammetry and ac impedance spectroscopy techniques) along with instrumental spectroscopy analyses. 相似文献