一种改进的单位根检验程序

原假设的合理设定是单位根检验的首要问题,至今尚无学者对此进行深入研究。通过剖析以往单位根检验原假设设定存在的缺陷,在同时考虑原假设的可信度和检验可靠性的前提下,本文提出了单位根检验原假设的一种合理的设定策略及改进的检验程序。     

Computer Simulations on the Channel Membrane Formation by Nonsolvent Induced Phase Separation

The formation of channel membrane of polystyrene‐block‐poly(4‐vinyl pyridine) block copolymer is studied by computer simulations with the nonsolvent induced phase separation (SNIPS) method. Dissipative particle dynamics is employed to study the microphase separation process and the SNIPS mechanism. Simulation results indicate that polymer concentration has a significant effect on the membrane structure. Channel membranes form in the copolymer concentration range of 44–58%. Block ratio plays an important role in shaping the membrane structure. Solvent exchange rate also affects the degree of microphase separation at each evolution stage of simulation. The time evolution of morphologies shows that the microphase separation processes happen with the following sequences: the polymer self‐assembled and many small pores appear, then they form irregular cavities and cross‐link gradually, finally the channel membrane forms. These results throw light on the formation mechanism of polymer membranes and provide insightful guidance for future membrane design and preparation.     

Selection of adequate optimization criteria in chromatographic separations

Computer-assisted optimization of chromatographic separations is still a fruitful activity. In fact, advances in computerized data handling should make the application of systematic optimization strategies much easier. However, in most contemporary applications, the optimization criterion is not considered to be a key issue (Vanbel, J Pharm Biomed, 21:603–610, 1999). In this paper, an update of the importance of selecting adequate criteria in chromatographic separation is presented.     

Transport of biomolecules in asymmetric nanofilter arrays

We propose a theoretical model for describing the electric-field-driven migration of rod-like biomolecules in nanofilters comprising a periodic array of shallow passages connecting deep wells. The electrophoretic migration of the biomolecules is modeled as transport of point-sized Brownian particles, with the orientational degree of freedom captured by an entropy term. Using appropriate projections, the formulation dimensionality is reduced to one physical dimension, requiring minimal computation and making it ideal for device design and optimization. Our formulation is used to assess the effect of slanted well walls on the energy landscape and resulting molecule mobility. Using this approach, we show that asymmetry in the well shape, such as a well with one slanted and one vertical wall, may be used for separation using low-frequency alternating-current fields because the mobility of a biomolecule is different in the two directions of travel. Our results show that, compared to methods using direct-current fields, the proposed method remains effective at higher field strengths and can achieve comparable separation using a significantly shorter device.     

Microstructural effects on the 1/f α noise of thin aluminum based films

The 1 /f^α noise was measured on a variety of Al-based thin metal films with widely varying microstructure using an ac bridge technique. The magnitude of the current noise in response to a small, non-destructive ac signal was found to vary several orders of magnitude between 0.01 and 10 Hz and was correlated to the microstructural differ-ences of the films. These differences have a strong affect on film lifetimes as measured in an accelerated electromigration test. Variation in microstructure was accomplished by different deposition temperatures and annealing parameters, and verified using TEM micrographs. Following fabrication, the current noise magnitude was measured and found to be sensitive to film width and grain size. The use of this technique to discriminate differences in film microstructure is discussed along with the correlations between ex-cess noise and the quality of the thin film as a metallic interconnection.     

Modelling of multifrequency IRMPD for laser isotope separation

The process of infrared multiple photon dissociation (IRMPD) of molecules is of great fundamental importance and has practical significance, such as isotope separation etc. Unfortunately, a clear insight into the process has been hindered by the bewildering array of important variables affecting MPD. The dissociation probability γ (φ) i.e. the yield has been found to be a sensitive function of laser fluence φ along with numerous other parameters like laser frequency, gas pressure etc. We have shown that in single frequency IRMPD, an accurate quantitative characterization of the dissociation probability can be adequately expressed by a ‘power law’ model with two fitting parameters namely critical fluence, φ_c and multiphoton order,m. This model was exploited in analysing our MPD results on various systems. However, the small isotope shift encountered in heavy elements and the sticking phenomenon observed in small light molecules restrict respectively the separation factor and the dissociation yield. These problems can effectively be tackled by irradiation with multifrequency laser beams which can be chosen appropriately on the basis of spectroscopic features. Based on our success in single frequency model, multifrequency IRMPD is modelled by a functional form containing the product of power law terms for individual fluences on irradiation frequencies. This model is successfully benchmarked with our experimental results on multifrequency LIS of tritium. Such knowledge can be utilized for appropriate separation process design, evaluation and optimization.     

Maximization of yield of C-13 isotope by multiphoton dissociation of Freon-22 using high average power TEA CO2 laser

Selective multi-photon dissociation (MPD) of Freon-22 (CF₂HC1) molecules has been carried out using a TEA CO₂ laser at various CO₂ laser lines (9P(20)-9P(26)) in order to maximize the yield of C-13 isotope in the product (C₂F₄) at an enrichment factor of 100. The effects of laser pulse tail due to the presence of N₂ in the laser mixture on the enrichment factor and yield of C-13 are investigated. It is found that the addition of a small amount of N₂ is possible in the laser mixture without a significant drop in the yield at desired enrichment factor. Addition of a small amount of N₂ improves the laser efficiency considerably. At a given pulse energy, a slight change in the near field intensity distribution of a laser severely affects the selectivity of C-13 isotope. The computed far-field intensity distributions of the measured near-field intensities show marked spatial variation in the focal spots that leads to a drop in selectivity. For macroscopic production of C-13 isotope a simple and novel multi-pass cavity has been designed and tested to focus the energy repeatedly keeping the optimum fluence constant at each focal spot.     

宽开通信侦察中多信号盲分离应用研究

宽开通信侦察系统可以大大提高搜索速度,提高信号的截获概率,但如何快速有效地分离出同时截获的多信号是一个急待解决的难题,盲分离技术为多信号分离提供了一种新的思路,实验结果表明盲分离技术在宽开通信侦察中的有效性,并显示出它在通信侦察中的广阔前景。     

基于CI接口的机卡分离条件接收系统设计与实现

通过比较实现CA系统的3个技术方案，引入DVB—CI公共接口概念并给出了CA系统中CI接口设计的框图，对公共接口协议作了简述，在此基础上完成CI接口的硬件设计和软件开发实现，简要介绍了对公共接口的扩展应用。     

开态热载流子应力下的n-MOSFETs的氧化层厚度效应

在最大衬底电流条件下(Vg=Vd/2),研究了不同氧化层厚度的表面沟道n-MOSFETs在热载流子应力下的退化.结果表明, Hu的寿命预测模型的两个关键参数m与n氧化层厚度有着密切关系.此外,和有着线性关系,尽管不同的氧化层厚度会引起不同的模型参数,但是如果对于不同厚度的氧化层,采用不同的m与n,Hu的模型仍然成立.在这个结果的基础上,Hu的寿命预测模型能用于更薄的氧化层.