数字电视播出系统的可靠性研究综述

数字电视播出系统的可靠性直接反映整个系统的质量优劣，是确保能否进行安全、可靠的电视播出的关键。为了保障电视播出的安全与可靠性，必须对硬盘化播控系统进行双机熬备扮和使用有RAID技术的硬盘播出系统的数据备份设计；同时还介绍了数字电视播出播出系统软件的设计要求和数字电视设备的寿命分析。     

金铝键合寿命评价方法研究

由于金属间化合物的生成,会使金铝键合的接触电性能受到影响.从金属间化合物生成这一单一失效机理出发,以失效物理为理论基础,通过恒定高温加速和高温步进加速试验,针对不同温度下的金铝键合寿命做出评价,并给出键合寿命评价流程.     

水对锂交换低硅铝比八面沸石吸附性能的影响

研究了变压吸附空气分离制氧吸附剂——锂交换低硅铝比八面沸石LiLSX中残留水及从外部引入的水对吸附性能的影响.研究表明，在水合LiLSX经脱附后，当残留的水分子数目为0～32（个分子/晶胞）时， N2或O2的吸附量下降显著.原因是N2和O2的吸附主要依赖于处在SIII位置的32个锂离子.当水分子与SIII位置的Li＋结合时，就会阻碍N2或O2的吸附.而从外部引入的水分子与脱附残留的水分子相比，在相同水含量时对吸附量的影响较小，这是由于吸附位置的不均匀性以及水分子在沸石中的扩散行为所引起.在水扩散进入LiLSX内部的过程中，一部分水分子可以吸附在能量较低的位置上而不是吸附到最强的SIII位置上.     

Determination of lead, copper and manganese by graphite furnace atomic absorption spectrometry after separation/concentration using a water-soluble polymer

In this study, a water-soluble polymer, polyvinylpyrrolidinone (PVP) having chelating functionalities was used for the preconcentration and separation of traces of Pb, Cu, Ve and Mn prior to their determination by graphite furnace atomic absorption spectrometry. For this purpose, the sample and the PVP solutions were mixed and the metal bound polymer was precipitated by adding the mixture onto acetone. The precipitate was separated by decantation and dissolved with water. By increasing the ratio of the volumes of sample to water used in dissolving the precipitate, the analyte elements were concentrated as needed. The concentration of trace elements was determined using graphite furnace atomic absorption spectrometry. The analyte elements in matrix free aqueous solutions were quantitatively recovered. The validity of the proposed method was checked with a standard reference material (NIST SRM 1577b bovine liver) and spiked fruit juice, sea water and mineral water samples. The analytical results were found to be in good agreement with certified and added values. Detection limits (3δ) were 1.7, 3.6 and 4.1 μg l⁻¹ for Pb, Cu and Mn, respectively, using 10 μl of sample volume. The method is novel and can be characterized by rapidity, simplicity, quantitative recovery and high reproducibility.     

Chiralcel OD-RH手性柱拆分卡维地洛对映体

采用Ch iralcelOD-RH(纤维素3,5-二甲基苯基氨基甲酸酯)手性固定相高效液相色谱法研究了乙腈-高氯酸钠缓冲盐体系对卡维地洛的手性拆分情况,讨论了流动相的各个因素(有机相的种类和比例、缓冲盐浓度、酸度等)对手性拆分的影响。在乙腈-高氯酸钠缓冲盐(pH 5.5,50 mmol/L)的体积比为35∶65的色谱条件下,卡维地洛对映体获得了基线分离。     

三元Co-Cu-Pb偏晶合金的快速凝固组织形成规律研究

在自由落体条件下实现了三元Co-Cu-Pb合金的液相分离与快速凝固. 实验发现,随液滴直径减小,Co₅₁Cu₄₇Pb₂合金液滴发生由枝晶→两层壳核→枝晶组织的转变,Co₄₇Cu₄₄Pb₉合金液滴的组织形态由壳核组织演化为均匀组织. 两种合金的快速凝固组织均由α(Co),(Cu)和(Pb)固溶体三相组成,α(Co)和(Cu)相主要以枝晶方式生长,(Pb)相分布在(Cu)枝晶间. 关键词： 液相分离 偏晶合金 快速凝固 自由落体     

Charge correlations in cobaltates La2–xSrx CoO4

We report on an elastic neutron scattering study of the charge correlations in La_2–xSr_x CoO₄ with x = 1/3, 0.4 and 0.5. We found that the checkerboard charge ordering correlations present in the x = 0.5 sample persist in the x = 0.4 and 1/3 materials. These checkerboard charge ordering correlations are robust and explain the occurrence of nano‐phase separation in layered cobaltates for Sr‐concentrations away from half‐doping. The half‐integer reflections then arise from the nanometer‐sized hole‐rich regions (blue areas in title figure) instead of the undoped ones (red areas in title figure). The appearance of nano‐phase separation is an important ingredient for understanding the formation of hour‐glass shaped magnetic excitation spectra in La_2–xSr_x CoO₄.

Nano‐phase separation in La_2–xSr_x CoO₄ (schematically). Red areas: undoped La₂CoO₄ islands, blue areas: checkerboard charge ordered regions; black, green and blue balls represent nonmagnetic Co³⁺ ions, magnetic Co²⁺ ions and oxygen ions, respectively; green arrows indicate Co²⁺ spins [1, 2].     

单层传声器阵列重建相干声场的近场声全息方法研究

针对传声器阵列两侧存在相干声源的非自由声场重建问题,提出基于球面谐波函数扩展近场声全息理论的相干声场重建方法。该方法在已知测量面两侧声源几何位置时,使用单层传声器阵列获取测量面处的声压分布,通过最小二乘法获得与目标声源和干扰噪声源响应对应的最优球波函数扩展项数和最优系数向量,结合测点位置的空间坐标进行声波分解,并分别重建出各声源在测量面上的声压分布。为了验证方法的有效性,分别给出了相干噪声源为球形声源和非球形声源的仿真验证,并在全消声室内对双扬声器产生的相干声场的重建进行了实验验证。结果表明:该方法对球形声源和非球形声源干扰下的声场重建都具有较好的效果,球形声源干扰下的重建精度更高。     

螺旋轴流式多相泵流动参数设计值探讨

本文在对螺旋轴流式多相泵高速试验的基础上,通过三级多相泵输送性能情况来分析动态参数进口冲角、相对液流角和比转速在设计时对增压单元参数的影响,从而改进增压单元的设计,使多相泵能具有更好的输送性能。     

直链淀粉手性固定相对8种外消旋硫代缩水甘油醚的直接拆分

利用高效液相色谱进行不对称拆分是十分有效的方法,其中多糖类手性固定相是非常重要的一种,它主要包括纤维素和淀粉两大类,Ｏｋａｍｏｔｏ等［１～３］合成了大量的纤维素和直链淀粉的衍生物,并将其涂敷在大孔硅胶表面,从而制备了手性拆分能力较强的多种固定相,这类...