Synthesis and mesomorphic properties of n-butyl-4- [4-((4-n-alkoxyl-tetrafluorophenyl)ethynyl)benzyloxy]benzoates

A homologous series of n-butyl-4-[4-((4-n-alkoxyl-tetrafluorophenyl)ethynyl)benzyloxy]benzoates have been synthesized.Their phase transition temperatures have also measured by polarizing textural observation and confirmed by DSC.     

Synthese und Struktur von Silber(II)-tetrafluoroaurat(III) Ag[AuF4]2

Synthesis and Structure of Silver(II) Tetrafluoroaurate(III) Ag[AuF₄]₂ Intensive green single crystals of Ag[AuF₄]₂ can be obtained by heating up micro crystalline Ag[AuF₄]₂ in autoclaves (p(F₂) ～ 200 bar, T ～ 400°C, t ～ 14 d). It crystallizes monoclinic, space group P2₁/n ? C; (No. 14) with a = 522.3(1), b = 1101.3(3), c = 550.5(2) pm, β = 94.98(3), Z = 2 and is isotypic with Pd[AuF₄]₂.     

Ba2BiV3O11 mit Bismut in geschlossener Koordination

Ba₂BiV₃O₁₁ containing Bismuth within closed Coordination A new barium bismuth oxovanadate, Ba₂BiV₃O₁₁, was prepared and investigated by X-Ray single crystal technique. It crystallizes with monoclinic symmetry space group C—P2₁/a, lattice constants a = 24.6473; b = 7.7347; c = 5.6375 Å, β = 103.16°; Z = 4. Octahedra arround Bi³⁺, tetrahedra and double tetrahedra arround V⁵⁺ form a tunnel structure. The tunnel positions are occupied by Ba(2).     

Synthesis, Structure and Characterization of [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O40(H2)]·4H2O

An organic-inorganic compound [Cu(2,2'-bpy)2][{Cu(2,2'-bpy)2}2W12O4o(H2)]·4H2O (Mr = 4048.00) was prepared from the hydrothermal reaction of Na2WO4·2H2O, CuCl2·2H2O,2,2'-bipyridine (2,2'-bpy) and H2O at 160 ℃ for 4 days. The compound crystallizes in the monoclinic system, space group P21/n with a = 18.9196(8), b = 20.4212(8), c = 21.8129(9)(A), β=96.992(3)°, V= 8365.0(6) (A)3, Dc= 3.214 g/cm3, Z = 4,μ(MoKα) = 17.269 mm-1 and F(000) = 7324.Of the 119837 total reflections, 17315 were unique (Rint = 0.0489). The final R = 0.0385 and wR =0.0770 for 11142 observed reflections with I ＞ 2σ(I). Single-crystal X-ray diffraction reveals that the structure is composed of [{Cu(2,2'-bpy)2}2W12O40(H2)]2- anions, discrete [Cu(2,2'-bpy)2]2 cations and lattice water molecules, and the anion is made up of a {W12O40(H2)}6- α-Keggin core decorated with two {Cu(2,2'-bpy)2}2 groups through bridging oxygen atoms.     

信息时代的铌酸锂晶体:进展与展望

铌酸锂晶体具有非线性效应、电光效应、声光效应、光折变效应、压电效应与热释电效应等多种物理特性,在表面声波器件、光电器件、声光器件等方面获得广泛的应用.经历了六十多年的发展,铌酸锂晶体历久弥新,随着材料特性的不断开发,新功能、新器件、新应用层出不穷,尤其是铌酸锂单晶薄膜在薄膜滤波器、集成光电器件等领域的性能具有明显优势,...     

Exploration of the Crystal Structure and Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(SO4)3

Praseodymium sulfate was obtained by the precipitation method and the crystal structure was determined by Rietveld analysis. Pr₂(SO₄)₃ is crystallized in the monoclinic structure, space group C2/c, with cell parameters a = 21.6052 (4), b = 6.7237 (1) and c = 6.9777 (1) Å, β = 107.9148 (7)°, Z = 4, V = 964.48 (3) ų (T = 150 °C). The thermal expansion of Pr₂(SO₄)₃ is strongly anisotropic. As was obtained by XRD measurements, all cell parameters are increased on heating. However, due to a strong increase of the monoclinic angle β, there is a direction of negative thermal expansion. In the argon atmosphere, Pr₂(SO₄)₃ is stable in the temperature range of T = 30–870 °C. The kinetics of the thermal decomposition process of praseodymium sulfate octahydrate Pr₂(SO₄)₃·8H₂O was studied as well. The vibrational properties of Pr₂(SO₄)₃ were examined by Raman and Fourier-transform infrared absorption spectroscopy methods. The band gap structure of Pr₂(SO₄)₃ was evaluated by ab initio calculations, and it was found that the valence band top is dominated by the p electrons of oxygen ions, while the conduction band bottom is formed by the d electrons of Pr³⁺ ions. The exact position of ZPL is determined via PL and PLE spectra at 77 K to be at 481 nm, and that enabled a correct assignment of luminescent bands. The maximum luminescent band in Pr₂(SO₄)₃ belongs to the ³P₀ → ³F₂ transition at 640 nm.     

基于石墨烯的布洛赫表面波调控特性研究

布洛赫表面波(Bloch surface wave,BSW) 具有传输损耗低、显著表面局域场增强、环境敏感等特性,因而被视为研究近场光和物质相互作用的关键技术。其主要在截断的一维光子晶体与外界介质的界面激发并沿此界面传播,通过传播界面微纳结构的设计,可在纳米尺度实现对BSW的有效调控。本文从BSW的模式特性出发,提出了石墨烯加载的一维光子晶体BSW传感器件结构。通过改变石墨烯层的结构参数,调节激发模式在光子带隙中的位置,研究激发模式的光场传输特性,实现对BSW激发波长、振幅和相位的调控。进一步利用其对外界介质折射率变化非常敏感的特性,对其传感检测能力进行研究。结果表明,该器件有望实现高灵敏度的生化传感检测应用。该研究为新型BSW集成光子器件的设计与发展提供了新思路。     

基于改进VGG网络的单体热电池X光图像无损检测方法研究

为解决单体热电池生产中出现的安装错误、人工检测耗时耗力的问题,提出一个结合迁移学习和卷积 神 经网络(convolutional neural network,CNN) 的单体热电池缺陷检测模型。首先,对数据集图像进行裁剪、加噪等预处理,以VGG16(visual geometry group 16) 网络作为 模型的骨干架构,在瓶颈层后增添选择性核(selective kernel,SK) 卷积;然后,增添全局平均池化(global average pooling,GAP) 层, 增加Dropout层及添加 L2 正则化等微调操作,得到单体热电池缺陷检测模型Q-VGGNet;最后,在大型公开数据集ImageNet上进 行预训练学习,将获得的权重参数迁移到单体热电池图像识别模型Q-VGGNet上。测试实验表明:6种 网络模型对数据集缺陷图像的总体识别准确率分别达到了98.39%、94.44%、97.27%、96.34%、93.71%、 95.61%,Q-VGGNet网 络模型 对合格图像和 漏装负极、极耳断裂、漏装集流片3种缺陷图像 识别准确率 分别达到了99.6%,95.9%,99.6%和98.4%。检测结果表明:该方法能够更准确、快速地检测热电池缺陷, 拥有良好的缺陷诊断能力,较传统方法提高近3%,为人工检测单体热电池缺陷提供了良好的解决途径。     

旋光晶体的寻常折射率与左旋光和右旋光折射率的关系

由光的波动方程证明,若介质为旋光物质,则其极化率张量χ一定有非对角对称的共轭虚元素,并导出了旋光晶体的寻常折射率no与左旋光折射率nL和右旋光折射率nR之间的关系.将理论分析结果与实验数据相对照,结果完全吻合.     

基于单片机的切纸机位移测量系统

介绍了一种基于单片机的切纸机位移测量系统。该系统以AT89C2051单片机为核心,实现了对切纸机刀具位置、进刀量以及进刀次数的实时测量,完成了多位测量结果的快速显示和测量结果的掉电保护。该系统测量准确、使用方便,大大提高了切纸机位移测量的精确度和工人的工作效率。