弛豫铁电体微畴—宏畴转变稳定性的一种新判据

利用铅基弛豫铁电体的局域冻结模型和Ｖｏｇｅｌ－Ｆｕｌｃｈｅｒｇ模型，求出了铅基弛豫铁电体的活化能、频率因子和冻结温度。并在此基础上提出了动态跃迁频率作为微畴－宏畴转变稳定性的新判据。动态跃迁频率越小，微畴向宏畴转变越困难，即微畴越稳定。此判据同时考虑了动力学因素和活化能，具有普适性。     

Nanoscale domain structures in 0.91Pb(Zn1/3Nb2/3)O3-0.09PbTiO3 (91PZN-9PT) single crystals studied by piezoresponse forcemicroscopy

High-resolution domain studies have been performed in 91PZN-9PT single crystals by piezoresponse force microscopy. Nanometer- and micron-sized strip-shaped 180º and parallel 90º domains were observed in the rhombohedral (R) and tetragonal (T) phases. Domain patterns with the typical sizes 5–200 nm were observed on the (001)_cub surface of unpoled sample. The existence of nanodomains in the sample is tentatively attributed to the relaxor nature of PZN-PT where small polar clusters may form under zero-field cooling conditions. The domain observation confirms the structure of the morphotropic 91PZN-9PT crystals, which is composed of both the R and T (or monoclinic) orientations states. The outstanding piezoelectric properties may result from the cooperative response of the microscale/nanoscale domain structure.     

弛豫铁电体的键能与配位数模型

基于一定浓度的杂质会在钛酸钡型铁电体中导致键能与配位数的高斯型分布原理,利用键能与配位数起伏模型导出了介电峰温与测量频率的关系.当键能和配位数的相对起伏接近时,其关系呈现出一般弛豫铁电体所普遍具有的Vogel-Fulcher函数形式,且冻结温度仅与键能的相对起伏和激活能有关.并由此解释了低掺杂浓度下杂质均匀分布导致弥散性的机理和超过临界浓度时的弛豫铁电性的机理.同时提出,杂质替代对畴的形成和生长所产生的强烈抑制作用及微畴化是实现键能起伏与配位数起伏一致的来源.     

PNN—PT弛豫铁电陶瓷钙钛矿结构的形成及其介电性能

研究了０．７５ＰＮＮ－０．２５ＰＴ弛豫铁电陶瓷钙钛矿结构的形成及其介电性能，结果表明，通过添加过量镍可以有效抑制焦绿石相的生成，获得单相钙钛矿结构，从而获得优异的介电性能。     

Bi_（0.5）Na_（0.5）TiO_3-BaTiO_3-KNbO_3陶瓷的介电特性及相变行为研究

采用固相反应法制备了（1-x）Bi0.47Na0.47Ba0.06TiO3-xKNbO3（BNBT-xKN,x=0～0.08）陶瓷,借助铁电分析仪、阻抗分析仪、扫描电镜（SEM）等仪器研究了KNbO3（KN）引入后,对陶瓷的微观结构、相变行为和介电性的影响.BNBT-xKN的扫描电镜（SEM）图显示：适量的KN对BNBT陶瓷具有细化晶粒、增大致密度作用.介电温谱（30~500℃）显示BNBT、BNBT-0.01KN、BNBT-0.02KN陶瓷有3个介电异常峰,而BNBT-0.04KN和BNBT-0.08KN陶瓷中有2个介电异常峰,并对陶瓷中出现的介电异常进行了讨论.通过介电温谱数据拟合,讨论了BNBT-xKN陶瓷的介电弛豫特性,并解释了BNBT-xKN陶瓷退极化的原因以及出现双电滞回线的机理.     

Atomic pair distribution function at the Brazilian Synchrotron Light Laboratory: application to the Pb1–xLaxZr0.40Ti0.60O3 ferroelectric system

This work reports the setting up of the X‐ray diffraction and spectroscopy beamline at the Brazilian Synchrotron Light Laboratory for performing total scattering experiments to be analyzed by atomic pair distribution function (PDF) studies. The results of a PDF refinement for Al₂O₃ standard are presented and compared with data acquired at a beamline of the Advanced Photon Source, where it is common to perform this type of experiment. A preliminary characterization of the Pb_1–xLa_xZr_0.40Ti_0.60O₃ ferroelectric system, with x = 0.11, 0.12 and 0.15, is also shown.     

Monte Carlo simulation on dielectric relaxation and dipole cluster state in relaxor ferroelectrics

The Ginzburg--Landau theory on ferroelectrics with random field induced by dipole defects is studied by using Monte Carlo simulation, in order to investigate the dipole configuration and the dielectric relaxation of relaxor ferroelectrics. With the increase of random field, the dipole configuration evolves from the long-range ferroelectric order into the coexistence of short-range dipole-clusters and less polarized matrix. The dipole-cluster phase above the transition temperature and superparaelectric fluctuations far below this temperature are identified for the relaxor ferroelectrics. We investigate the frequency dispersion and the time-domain spectrum of the dielectric relaxation, demonstrating the Vogel--Fulcher relationship and the multi-peaked time-domain distribution of the dielectric relaxation.     

(1-x)(K0.5Na0.5)NbO3-xSrTiO3陶瓷的弛豫铁电性能

通过对（1-x）（K_0.5Na_0.5）NbO₃-xSrTiO₃（0≤x≤0.15）陶瓷的相组成、晶体结构和介电性能的研究发现,该陶瓷为单一的钙钛矿结构相.当x含量较小（x＜0.1）时为正交相结构,x≥0.1时转变为四方相结构.随着SrTiO₃掺杂量的增加,样品的致密度增加,样品由正常铁电相逐渐向弥散铁电相转变,且相 关键词： 弛豫铁电体 0.5Na_0.5）NbO₃铁电陶瓷')" href="#">（K_0.5Na_0.5）NbO₃铁电陶瓷 3掺杂')" href="#">SrTiO₃掺杂 相变温度     

Ca、Bi掺杂Ba_(0.67)Sr_(0.33)TiO_3陶瓷弛豫特性研究

通过低成本固相法制备了Ca、Bi掺杂Ba_(0.67)Sr_(0.33)TiO_3陶瓷.利用透射电子显微镜(TEM)和阻抗分析仪分析技术,详细研究了Ca、Bi掺杂Ba_(0.67)Sr_(0.33)TiO_3陶瓷的弛豫特性.研究发现Ca、Bi掺杂使BST陶瓷呈现显著的铁电弛豫行为,且随着掺杂量的增加,介电峰弥散程度和弛豫强度逐渐增强.     

PBSZT弛豫铁电陶瓷偏压压电效应的研究

研究了镧和铋掺杂的锆钛酸铅钡锶（ＰＢＳＺＴ）弛豫铁电陶瓷在不同直流偏压及温度下的介电常数ε３３、平面机电耦合系数ｋｐ 和等效横向压电常数ｄ３１。实验表明,ＰＢＳＺＴ弛豫铁电陶瓷的ｄ３１值可由直流偏压控制且温度系数远小于ＰＭＮ－ＰＴ系陶瓷。室温下镧和铋掺杂的ＰＢＳＺＴ陶瓷在１０ ｋＶ／ｃｍ 的偏压下｜ｄ３１｜分别为２１０ ｐＣ／Ｎ和２２０ ｐＣ／Ｎ。