Maintenance of Soft Calibration Models in the Determination of Zinc,Cadmium, Lead and Copper by Differential Pulse Anodic Stripping Voltammetry

A strategy for constructing a global multivariate calibration model that includes calibration samples measured over time on different days is developed and applied in electroanalysis. Both synthetic and real samples (tap, extracted and river water) are analyzed by differential‐pulse anodic stripping voltammetry, showing the suitability of the global model constructed that provides successful results similar to those of the usual multivariate calibration. In addition the capability of discrimination of this model is evaluated in prediction for the mean of three replicates with estimation of probability of false noncompliance, α, and false compliance, β, being found 3.1, 11.2, 6.7 and 64.7 nM for nominal concentrations of zinc, cadmium, lead and copper of 96.0, 40.4, 37.3 and 328.0 nM respectively when α=β=0.05. It has been proven that the use of the global calibration does not imply a loss of multivariate analytical sensitivity, using this parameter as quality index of the analytical procedure. The viability of using calibration maintenance strategies with electroanalytical techniques is shown, providing a way to save time and experimental effort when these techniques are used in routine analysis.     

A Novel Model for Protein Immobilization on Microspheres

The immobilization of proteins, especially receptor proteins commonly used in high through-put screening of drugs (HTS), have received great attention in recent years. There are many successful isothermal models for describing the adsorption of protein onto solid surface, such as Langmuir model, Bi-Langmuir model, Fowler model, Freundlich model, Freundlich-Langmuir model and Tekmin model etc. In all these models, Langmuir model was the most favorable one model accepted by many researchers, but the experimental results showed that it was not entirely fit to all adsorption behaviors. So new models were required for describing protein adsorption onto microspheres in different conditions.In our research, a novel isothermal model, including Langmuir and other adsorbing behaviors was presented basing on the holding degree of surface active sites and the interaction styles of protein immobilization. In Langmuir model, the adsorbing amount of protein was described as [PS] =Km[P]/1 + K[P], where [PS] was the concentration of adsorbed protein, [P] was the concentration of freeprotein at equilibrium state, and Km and K was constant. According to the interactions of protein and ligands, there were three patterns in the interactions of protein and ligands. On the similar assumption that the interaction of protein and microspheres were three styles, and based on the definition of the holding degree of surface active sites (Y), three adsorption behaviors could be described as Y K[ P ]φ/ K[P]φ+1 or ln K + φ ln[P] =ln(Y/1-Y) in which [P] was the concentration of free protein at equilibrium state, and φ and K was constant. Different scale of φ presented different adsorption behaviors, especially when φ was 1, the adsorption behavior was Langmuir adsorbing model. Figure I indicated the different adsorbing results in different adsorption behaviors (φ＞1, φ＜1,and φ=1).     

Synthesis And Properties Of Functional Ultra-High Molecular Weight Transparent Styrene-Butadiene Block Copolymer

Functional ultra-high molecular weight transparent styrene-butadiene block copolymer possesses both high transparency and impact resistance and has excellent comprehensive properties prior to other transparent resins. In this paper we not only use anionic polymerization process which includes 1 time addition of initiator and 3 time addition of monomers, but also introduce functional coupling agent for the fist time to prepare mentioned functional block copolymer. The typical preparation proces…     

Stable nonequilibrium probability densities and phase transitions for meanfield models in the thermodynamic limit

A nonlinear Fokker-Planck equation is derived to describe the cooperative behavior of general stochastic systems interacting via mean-field couplings, in the limit of an infinite number of such systems. Disordered systems are also considered. In the weak-noise limit; a general result yields the possibility of having bifurcations from stationary solutions of the nonlinear Fokker-Planck equation into stable time-dependent solutions. The latter are interpreted as non-equilibrium probability distributions (states), and the bifurcations to them as nonequilibrium phase transitions. In the thermodynamic limit, results for three models are given for illustrative purposes. A model of self-synchronization of nonlinear oscillators presents a Hopf bifurcation to a time-periodic probability density, which can be analyzed for any value of the noise. The effects of disorder are illustrated by a simplified version of the Sompolinsky-Zippelius model of spin-glasses. Finally, results for the Fukuyama-Lee-Fisher model of charge-density waves are given. A singular perturbation analysis shows that the depinning transition is a bifurcation problem modified by the disorder noise due to impurities. Far from the bifurcation point, the CDW is either pinned or free, obeying (to leading order) the Grüner-Zawadowki-Chaikin equation. Near the bifurcation, the disorder noise drastically modifies the pattern, giving a quenched average of the CDW current which is constant. Critical exponents are found to depend on the noise, and they are larger than Fisher's values for the two probability distributions considered.     

CPM自滤波非稳腔YAG激光器研究

把由非谐振环和凸面全反射镜构成的自滤波非稳腔应用于撞脉冲锁模Ｎｄ：ＹＡＧ激光器，改善了光束的空间质量和输出稳定性，获得发散角为２倍衍射极限，能量５０ｍＪ，脉宽１０ｐｓ的锁模脉冲，并与未加滤波小孔的ＣＰＭ非稳腔的输出性能进行实验比较。，     

Observable signals of gauge-mediated supersymmetry breaking

The observable consequences of gauge-mediated supersymmetry breaking (GMSB) are reviewed here. Implications of scenarios both with a neutralino and a slepton as the next lightest supersymmetric particle (NLSP) are surveyed in relation to hadronic ande ⁺ e ^- colliders. We also discuss the phenomenological consequences of the NLSP decaying slowly, giving rise to delayed events in the detectors.The importance of distinguishing signals of GMSB models from those of the commonly discussed supergravity-type theories is emphasized.     

Shell effects in the symmetric-modal fission of pre-actinide nuclei

Mass distributions of fragments in the low-energy fission of nuclei from ¹⁸⁷Ir to ²¹³At have been analysed. This analysis has shown that shell effects in symmetric-mode fragment mass yields from the fission of pre-actinide nuclei could be described if one assumes the existence of two strongly deformed neutron shells in the arising fragments with neutron numbers N₁ ≈ 52 and N₂ ≈ 68. A new method has been proposed for quantitatively describing the mass distributions of the symmetric fission mode for pre-actinides with A ≈ 180–220.     

随机化交通灯的二维元胞自动机交通模型

元胞自动机交通模型以简单的规则反映交通系统中的多种因素，可以分析各种交通现象，且可在计算机上方便、高效地运作·Ｂｉｈａｍ－Ｍｉｄｄｌｅｔｏｎ－Ｌｅｖｉｎｅ模型（ＢＭＬ模型）实现了二维交通问题的元胞自动机模型的模拟研究·本文对ＢＭＬ模型作了改进，解除了该模型中关于交通灯同步变化的限制·在新模型中，每个路口的交通灯可以自由选定起始工作时间和变化节奏，于是可以更全面、准确地反映交通灯对交通系统性能的影响·本文还对新模型中出现的若干新效应作了解释·