Salt Concentration Effects in Planar Light‐Emitting Electrochemical Cells

Incorporation of ions in the active layer of organic semiconductor devices may lead to attractive device properties like enhanced injection and improved carrier transport. In this paper, we investigate the effect of the salt concentration on the operation of light‐emitting electrochemical cells, using experiments and numerical calculations. The current density and light emission are shown to increase linearly with increasing ion concentration over a wide range of concentrations. The increasing current is accompanied by an ion redistribution, leading to a narrowing of the recombination zone. Hence, in absence of detrimental side reactions and doping‐related luminescence quenching, the ion concentration should be as high as possible.     

Nonparabolicity effects and the spin-split electron dwell time in symmetric III-V double-barrier structures

We start from the fourth-order nonparabolic and anisotropic conduction band bulk dispersion relation to obtain a one-band effective Hamiltonian, which we apply to an AlGaSb symmetric double-barrier structure with resonant energies significantly (more than 200 meV) above the well bottom. The spin-splitting is described by the k³ Dresselhaus spin-orbit coupling term modifying only the effective mass of the spin eigenstates in the investigated structure. Apart from the bulk-like resonant energy shift due to the band nonparabolicity, we obtain a substantial shift depending on the choice of boundary conditions for the envelope functions at interfaces between different materials. The shift of resonant energy levels leads to the change of spin-splitting and the magnitude of the dwell times. We attempt to explain the influence of both the nonparabolicity and boundary conditions choice by introducing various effective masses.     

Tuning Carbon Materials for Supercapacitors by Direct Pyrolysis of Seaweeds

The sea provides a large variety of seaweeds that, because of their chemical composition, are fantastic precursors of nanotextured carbons. The carbons are obtained by the simple pyrolysis of the seaweeds under a nitrogen atmosphere between 600 and 900 °C, followed by rinsing the product in slightly acidic water. Depending on the origin of the seaweed and on the pyrolysis conditions, the synthesis may be oriented to give an oxygen‐enriched carbon or to give a tuned micro/mesoporous carbon. The samples with a rich oxygenated surface functionality are excellent as supercapacitor electrodes in an aqueous medium whereas the perfectly tuned porous carbons are directly applicable for organic media. In both cases, the specific surface area of the attained carbons does not exceed 1300 m² g⁻¹, which results in high‐density materials. As a consequence, the volumetric capacitance is very high, making these materials more interesting than activated carbons from the point of view of developing small and compact electric power sources. Such versatile carbons, obtained by a simple, ecological, and cheap process, could be well used for environment remediation such as water and air treatment.     

保单驱动索赔离散风险模型的精算量分布

研究了一类索赔是由保单驱动的带随机利率的离散时间非寿险风险保险模型,证明了该模型的盈余首次超过给定水平的时间、破产前最大盈余、破产持续时间以及盈余首次回复为正后的瞬间值等精算量的分布都可以由一类积分方程的唯一解给出。     

浅谈BCCH与TCH载频故障对网络性能的不同影响

载频故障对网络性能有着很重要的影响，章首先介绍了BCCH载频与TCH载频所承载的相关信道；后，分别会对网络性能造成哪些影响。如何根据网络现象判断网络故障所在，是解决网络问题的关键。文其次从硬件和软件两方面重点描述了BCCH载频、TCH载频出现故障     

Asynchronous sampling for ultrafast experiments with low momentum compaction at the ANKA ring

A high‐repetition‐rate pump–probe experiment is presented, based on the asynchronous sampling approach. The low‐α mode at the synchrotron ANKA can be used for a time resolution down to the picosecond limit for the time‐domain sampling of the coherent THz emission as well as for hard X‐ray pump–probe experiments, which probe structural dynamics in the condensed phase. It is shown that a synchronization of better than 1 ps is achieved, and examples of phonon dynamics of semiconductors are presented.     

The dependence of polymer conductivity on the work function of metallic electrodes

It is shown that the occurrence of metallic conductivity in polymers is due to their electrification. In particular, the current density depends on the electron work function of metallic electrodes which are in contact with the polymer.     

Pinwheel broadcast paradigm in supporting energy‐saving mobile devices

Because of the limited bandwidth and restricted number of channels in the wireless access environment, the broadcast paradigm has become an important technique for accessing messages. Energy saving is an important issue in the mobile computing environment. In this paper, we propose a multichannel broadcast paradigm that constructs the broadcast channels according to the access frequency of each type of message in order to save energy in mobile devices (MDs). The pinwheel scheduling algorithm (PSA) presented in this paper is used to organize all types of messages in the broadcast channels in the most symmetrical distribution in order to reduce both the tuning time and the access time. The performance of the proposed mechanism is analyzed, and the improvement over existing methods is demonstrated numerically. The results show that the proposed mechanism is capable of improving both the tuning time and the access time due to the presence of skewness in the access distribution among the disseminated messages. When the number of message types increases, both the tuning time and the access time can be further improved as long as a small number of broadcast channels are added. Copyright © 2009 John Wiley & Sons, Ltd.