Construction of nonanuclear supramolecular structures from simple modular units

A porphyrazine based supramolecule with a nonanuclear structure has been prepared by the ready coordination of pyridine donor sites in octakis(4-pyridoxyethylthio)porphyrazinatomagnesium with vanadyl bis(acetylacetonate) and characterized by EPR spectroscopy.     

Resonant-cavity-enhanced photodetectors and LEDs in the mid-infrared

In this paper we outline the use of resonant-cavity enhancement for increasing the exterior coupling efficiency of photodetectors and light-emitting diodes (LEDs) in the mid-infrared (MIR) spectral region. This method is potentially very important in the MIR because encapsulation is not presently feasible due to the lack of suitable materials. Among other potential applications, resonant-cavity-enhanced (RCE) photodetectors and LEDs could be particularly suitable for greenhouse gas detection because of their ‘pre-tunable’ spectrally narrowed resonantly enhanced peaks. We also present the optical characterization of an InAs RCE photodetector aimed at the detection of methane gas (λ≈3.3 μm), and an InAs/InAs_0.91Sb_0.09 resonant-cavity LED (RCLED) aimed at carbon dioxide gas (λ≈4.2 μm). The high peak responsivity of the RCE photodetector was 34.7 A/W at λ=3.14 μm, and the RCLED peaked at λ=3.96 μm. These are among the longest operating wavelengths for III–V RCE photodetectors and RCLEDs reported in the literature.     

电磁诱导透明和导致极慢光速的机制

根据有关文献 ,描述了电磁诱导透明和导致光速极慢的物理机制 ,并对实验结果也做了介绍     

Determination of optical nonlinearities in Cu(mpo)2 by Z-scan technique

The optical nonlinearities of Cu(mpo)₂ [formula = C₁₀H₈N₂CuO₂S₂] complex have firstly been investigated by using the Z-scan technique with a nanosecond-pulsed Nd:YAG laser at its second harmonic (532 nm) radiation. The nonlinear optical absorption and refraction coefficients of Cu(mpo)₂ have been measured with the different on-axial peak irradiances I ₀ at the waist ranging from 0.48 to 5.66 GW/cm². The nonlinear transmittance characteristics exhibit the near resonant two-photon absorption (TPA) at 532 nm and are explained by a population redistribution model. The nonlinear absorption originates from the near resonant TPA while the mechanism of the nonlinear refraction is the near resonant TPA transition enhancement. The linear increasing dependences of the optical nonlinearities on the incident irradiance arise from the population redistribution due to the near resonant TPA.     

Hydrogel‐like elastic membrane consisting of semi‐interpenetrating polymer networks based on a phosphorylcholine polymer and a segmented polyurethane

To obtain a hydrogel‐like elastic membrane, we prepared semi‐interpenetrating polymer networks (IPNs) by the radical polymerization of methacrylates such as 2‐methacryloyloxyethyl phosphorylcholine (MPC), 2‐hydroxyethylmethacrylate, and triethyleneglycol dimethacrylate diffused into segmented polyurethane (SPU) membranes swollen with a monomer mixture. The values of Young's modulus for the hydrated semi‐IPN membranes were less than that for an SPU membrane because of higher hydration, but they were much higher than that for a hydrated MPC polymer gel (non‐SPU). According to a thermal analysis, the MPC polymer influenced the segment association of SPU. The diffusion coefficient of 8‐anilino‐1‐naphthalenesulfonic acid sodium salt from the semi‐IPN membrane could be controlled with different MPC unit concentrations in the membrane, and it was about 7 × 10² times higher than that of the SPU membrane. Fibroblast cell adhesion on the semi‐IPN membrane was effectively reduced by the MPC units. We concluded that semi‐IPNs composed of the MPC polymer and SPU may be novel polymer materials possessing attractive mechanical, diffusive‐release, and nonbiofouling properties. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 68–75, 2003     

Graceful Signed Graphs

A (p, q)-sigraph S is an ordered pair (G, s) where G = (V, E) is a (p, q)-graph and s is a function which assigns to each edge of G a positive or a negative sign. Let the sets E ⁺ and E ^– consist of m positive and n negative edges of G, respectively, where m + n = q. Given positive integers k and d, S is said to be (k, d)-graceful if the vertices of G can be labeled with distinct integers from the set {0, 1, ..., k + (q – 1)d such that when each edge uv of G is assigned the product of its sign and the absolute difference of the integers assigned to u and v the edges in E ⁺ and E ^– are labeled k, k + d, k + 2d, ..., k + (m – 1)d and –k, – (k + d), – (k + 2d), ..., – (k + (n – 1)d), respectively.In this paper, we report results of our preliminary investigation on the above new notion, which indeed generalises the well-known concept of (k, d)-graceful graphs due to B. D. Acharya and S. M. Hegde.     

Subword complexes in Coxeter groups

Let (Π,Σ) be a Coxeter system. An ordered list of elements in Σ and an element in Π determine a subword complex, as introduced in Knutson and Miller (Ann. of Math. (2) (2003), to appear). Subword complexes are demonstrated here to be homeomorphic to balls or spheres, and their Hilbert series are shown to reflect combinatorial properties of reduced expressions in Coxeter groups. Two formulae for double Grothendieck polynomials, one of which appeared in Fomin and Kirillov (Proceedings of the Sixth Conference in Formal Power Series and Algebraic Combinatorics, DIMACS, 1994, pp. 183-190), are recovered in the context of simplicial topology for subword complexes. Some open questions related to subword complexes are presented.     

全变差有界函数列的一致(R)可积性

给出了一致有界单调函数列一致可积性定理 ,由此得出全变差序列有界的收敛函数列的一致可积性 .说明了该结论可判断一些非一致收敛函数列的逐项积分性质 .     

New 6-Arylsulfonyl-1,2-benzoisothiazol-3(2H)-one 1,1-Dioxides Derived from Diphenyl Sulfone Monosulfonyl Chlorides

Various methods were studied for the oxidation of 2-methyl-5-(phenylsulfonyl)benzenesulfamide and its derivatives. The oxidation by sodium dichromate in sulfuric acid was found most efficient. The effects of temperature, concentration, reagent ratio, and time of the oxidation reaction on the yield of the desired product were investigated. Conditions were proposed for obtaining the desired product in yields up to 95%. A synthesis was developed for a series of new saccharin derivatives.     

基于Karhunen-Loève变换和小波谱特征矢量量化的三维谱像数据压缩

提出了基于Karhunen Lo埁ｖｅ变换的小波谱特征矢量量化三维谱像数据压缩方法耍幔颍瑁酰睿澹?Lo埁ｖｅ变换 /小波变换 /小波谱特征矢量量化方法应用了Karhunen Lo埁ｖｅ变换的消除谱相关性优良性能 ,应用二维小波变换消除空间相关性 ,在小波变换域内应用二维集分割嵌入块编码和一维谱特征矢量量化对三维谱像数据压缩 ,获得较高的压缩性能。实验结果表明 :Karhunen Lo埁ｖｅ变换 /小波变换 /小波谱特征矢量量化编码比Karhunen Lo埁ｖｅ变换 /小波变换 /改进对块零树编码和Karhunen Lo埁ｖｅ变换 /小波变换 /快速矢量量化编码方法在同样压缩比条件下 ,峰值信噪比提高 2dB和 1dB以上 ,而速度提高了 1.5和 8倍 ,整体压缩性能有较大的提高