Synthesis of well‐defined polymeric activated esters

Monomers bearing an activated ester group can be polymerized under various controlled polymerization techniques, such as ATRP, NMP, RAFT polymerization, or ROMP. Combining the functionalization of polymers via polymeric activated esters with these controlled polymerization techniques generate possibilities to realize highly functionalized polymer architectures. Within this highlight two different research areas of activated esters in polymer science will be discussed: (i) the preparation of defined reactive polymer architectures by controlled polymerization techniques and (ii) the preparation of defined reactive thin films. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 6677–6687, 2008     

Rubidium-beam microwave clock pumped by distributed feedback diode lasers

A rubidium-beam microwave clock, optically pumped by a distributed feedback diode laser, is experimentally investigated. The clock is composed of a physical package, optical systems, and electric servo loops. The physical package realizes the microwave interrogation of a rubidium-atomic beam. The optical systems, equipped with two 780-nm distributed feedback laser diodes, yield light for pumping and detecting. The servo loops control the frequency of a local oscillator with respect to the microwave spectrum. With the experimental systems, the microwave spectrum, which has an amplitude of 4 n A and a line width of 700 Hz, is obtained. Preliminary tests show that the clock short-term frequency stability is 7 × 10~(-11) at 1 s, and 3 × 10~(-12) at 1000 s. These experimental results demonstrate the feasibility of the scheme for a manufactured clock.     

一类新混沌系统的线性状态反馈控制

研究了一类新混沌系统的控制问题.利用Routh-Hurwitz准则对受控系统进行了稳定性分析，结合线性状态反馈方法理论上严格证明了达到控制目标反馈系数的选择原则.数值研究证明了该方法能够有效地控制混沌系统到失稳的平衡点或周期解，同时控制效果在弱噪声干扰下具有很强的鲁棒性. 关键词： 新混沌系统 线性状态反馈控制 Routh-Hurwitz准则 噪声     

A low noise CMOS RF front-end for UWB 6-9 GHz applications

An integrated fully differential ultra-wideband CMOS RF front-end for 6-9 GHz is presented.A resistive feedback low noise amplifier and a gain controllable IQ merged folded quadrature mixer are integrated as the RF front-end. The ESD protected chip is fabricated in a TSMC 0.13μm RF CMOS process and achieves a maximum voltage gain of 23-26 dB and a minimum voltage gain of 16-19 dB,an averaged total noise figure of 3.3-4.6 dB while operating in the high gain mode and an in-band IIP3 of-12.6 dBm while in th...     

中继协作无线网络中不完美反馈下基于网络编码的重传方案

无线广播网络传输过程中,目的节点反馈信息丢失或部分丢失导致发送节点不能了解目的节点的真实接收状态.为提高不完美反馈下无线网络的重传效率,本文提出中继协作无线网络中不完美反馈下基于网络编码的重传方案.本方案基于部分可观察马尔科夫决策过程对不完美反馈下的重传过程进行建模.发送节点根据系统观测状态和最大置信度更新系统估计状态,根据数据包发送顺序,优先选择最早丢失且能够恢复最多丢包的编码包重传.目的节点缓存不可解编码包以提升编解码机会.重传过程中源节点关注目的节点请求包需求,相同情况优先选择传输可靠性较高的中继节点,以提升传输有效性.仿真结果表明,在不完美反馈下相对于传统方案,本方案可有效提高重传效率.     

引入电流负反馈后电路输出阻抗变化的测试难点及解决方案

引入电流负反馈会使放大电路的输出电阻变大,这种变化在实验测量时几乎没有出现。我们在分析原因后,提出了一种简单、易行的解决方案,并且对电路参数进行了合理化设计,使实验效果非常理想。     

一种大动态视频对数放大器的设计

介绍了一种大动态范围视频对数放大器的设计,并给出了研制结果。该视频对数放大器是在自制单片IC基础上混合集成,单片IC采用PN结隔离双极工艺制作。经测试,该电路动态范围达84 dB、增益为75 dB、对数斜率为50 mV/dB、对数精度为±2 dB。     

Identifying Reactive Sites and Transport Limitations of Oxygen Reactions in Aprotic Lithium‐O2 Batteries at the Stage of Sudden Death

Discharging of the aprotic Li‐O₂ battery relies on the O₂ reduction reaction (ORR) forming solid Li₂O₂ in the positive electrode, which is often characterized by a sharp voltage drop (that is, sudden death) at the end of discharge, delivering a capacity far below its theoretical promise. Toward unlocking the energy capabilities of Li‐O₂ batteries, it is crucial to have a fundamental understanding of the origin of sudden death in terms of reactive sites and transport limitations. Herein, a mechanistic study is presented on a model system of Au|Li₂O₂|Li⁺ electrolyte, in which the Au electrode was passivated with a thin Li₂O₂ film by discharging to the state of sudden death. Direct conductivity measurement of the Li₂O₂ film and in situ spectroscopic study of ORR using ¹⁸O₂ for passivation and ¹⁶O₂ for further discharging provide compelling evidence that ORR (and O₂ evolution reaction as well) occurs at the buried interface of Au|Li₂O₂ and is limited by electron instead of Li⁺ and O₂ transport.     

基于信道相关统计及有限反馈的多基站协作波束成型

为减少多基站协作波束成形系统中基站间的信息交换量和用户信道信息反馈量,提出一种基站联合利用有限反馈信道参数和信道空间相关矩阵估计信道矢量函数的方法;基于所估计的信道矢量函数,提出一种多基站协作扩展迫零波束成形算法。相比已有的多基站协作波束成形方案,所提算法能在反馈/回程开销和系统性能之间取得更合理的折中,计算仿真验证了所提算法的有效性。     

位移和速度反馈的数学模型及实现方法

本文提出了位移和速度同时反馈的数学模型 .并给出了位移和速度反馈的实现方法 ,该方法用传统的差动变压器实现了位移和速度的同时反馈