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141.
Jun Hu Nan Zhang Pan‐Ke Zhang Yun Chen Xing‐Hua Xia Hong‐Yuan Chen Jing‐Juan Xu 《Angewandte Chemie (International ed. in English)》2020,59(41):18244-18248
We report a new mass spectrometric method for detecting electrogenerated intermediates. This approach is based on simultaneous activation of electrospray ionization and redox reaction on a wireless bipolar ultramicroelectrode, which is fabricated in the tip of a quartz nanopipette. The hollow structure of the ultramicroelectrode permits rapid transferring the transient species from electrode–electrolyte interfaces into the gas phase for mass spectrometric identification on the time scale of microseconds. The long‐sought fleeting intermediates including TPrA.+, whose lifetime in solution is only 200 μs, and catecholamine o‐semiquinone radicals, the second‐order rate constant of which is typically 109 m ?1 s?1, were successfully identified, helping clarify the previously hidden reaction pathways. Accordingly, our method may have wide applicability in exploring the dynamics of many electrochemical reactions, especially their ultrafast initial steps. 相似文献
142.
Samit Bera Bhaskar Das Arnab De Atish Barua Susmita Das Bratati De 《Natural product research》2020,34(4):599-603
AbstractThe methanolic extract of Cycas revoluta cone (MECR) was analyzed by GC-MS and UHPLC for metabolite profiling and was evaluated for anti-colon cancer property by using in vitro assays like Cell Viability Assay, Colony Formation Assay, ROS Determination, Flowcytometry, DAPI staining assay, Tunel assay. GC-MS and HPLC analysis confirmed the presence of different phytochemicals in the extract of Cycas revoluta cone. In-vitro studies showed MECR extract showed significant anti-colon cancer activity by reducing proliferation and inducing apoptosis in colon cancer cell (HCT-8) line, but no such activity was seen in normal colon cell (CCD-18Co) line. The investigation confirms that MECR may be a promising candidate in colon cancer protection. 相似文献
143.
Jacques Penelle Vronique Mayn Roland Touillaux 《Journal of polymer science. Part A, Polymer chemistry》1996,34(16):3369-3378
2-(Trimethylsiloxy)butadiene (TMSBD) and 2-(tert-butyldimethylsiloxy)butadiene (TBMSBD) were copolymerized with styrene (St) and methyl methacrylate (MMA) under free-radical conditions. The obtained polymers were found to contain reactive silyl enol ether groups in a ratio identical to the TMSBD or TBMSBD molar fraction in the copolymer. All investigated samples displayed only 1,4- and 3,4-microstructures. The influence of several experimental factors on the yields, rates of polymerization, microstructures, and copolymer compositions were examined. Monomer reactivity ratios r1 and r2 at 60°C were determined from copolymer composition curves at low conversions. The homopolymerization of TBMSBD was also investigated and results were compared with those previously obtained for TMSBD. A slight increase in rates was observed and was rationalized on the basis of the higher viscosity resulting from the structural change in the monomer. Thermal stabilities of the synthesized polymers were investigated by TGA and their glass transition temperatures were determined by DSC. All measurements are compatible with a possible use of TMSBD and TBMSBD copolymers as reactive polymers. © 1996 John Wiley & Sons, Inc. 相似文献
144.
扩声系统中普遍存在由声反馈导致的啸叫问题。如何合理有效地抑制声反馈,提高扩声系统增益是衡量扩声系统性能的重要依据。实践证明,移频器能显著提高扩声系统增益。虽然移频电路只能应用于语言类扩声系统中,但因其电路实现相对简单、抑制啸叫效果较明显等特点,得到了广泛应用。依据Weaver法移频原理,利用PSpice仿真软件对移频增音电路进行了仿真分析,为广大音响设计工程师提供了有价值的参考。 相似文献
145.
本文介绍了电流反馈放大器(CFA)的基本原理,用四个CFA和几个电阻、电容设计了一种三输入单输出的新的通用滤波器。这种滤波器在无需电阻电容匹配的情况下,能实现二阶的低通、带通、高通、带阻以及全通五种滤波功能。每种滤波功能的特征角频率ω0都能由接地电容调节,而品质因数Q可由接地电阻单独调节。该滤波器对有源和无源元件的灵敏度都不超过1。利用PSPICE软件对电路图进行了仿真,仿真结果与理论分析一致。 相似文献
146.
A nonautonomous delayed logistic model with linear feedback regulation is pro- posed in this paper.Sufficient conditions are derived for the existence,uniqueness and global asymptotic stability of positive periodic solution of the model. 相似文献
147.
Brandon Aguiar Helena Carmo Jorge Garrido Jos M. Sousa Lobo Isabel F. Almeida 《Molecules (Basel, Switzerland)》2022,27(1)
Polyphenols are a large family of natural compounds widely used in cosmetic products due to their antioxidant and anti-inflammatory beneficial properties and their ability to prevent UV radiation-induced oxidative stress. Since these compounds present chromophores and are applied directly to the skin, they can react with sunlight and exert phototoxic effects. The available scientific information on the phototoxic potential of these natural compounds is scarce, and thus the aim of this study was to evaluate the photoreactivity and phototoxicity of five phenolic antioxidants with documented use in cosmetic products. A standard ROS assay was validated and applied to screen the photoreactivity of the natural phenolic antioxidants caffeic acid, ferulic acid, p-coumaric acid, 3,4-dihydroxyphenylacetic acid (DOPAC), and rutin. The phototoxicity potential was determined by using a human keratinocyte cell line (HaCaT), based on the 3T3 Neutral Red Uptake phototoxicity test. Although all studied phenolic antioxidants absorbed UV/Vis radiation in the range of 290 to 700 nm, only DOPAC was able to generate singlet oxygen. The generation of reactive oxygen species is an early-stage chemical reaction as part of the phototoxicity mechanism. Yet, none of the studied compounds decreased the viability of keratinocytes after irradiation, leading to the conclusion that they do not have phototoxic potential. The data obtained with this work suggests that these compounds are safe when incorporated in cosmetic products. 相似文献
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