N—甲基异靛蓝在不同溶剂中的^1H—NMR研究

用选择照射方法研究了N-甲基异靛蓝(isoindigatin)在(CD_3)_2CO、CDCl_3、DMSO-d_6溶剂中及重水交换后的~1H NMR谱。得到了化学环境极为类似的两芳环质子在不同溶剂中的NMR谱线归属和偶合常数。     

A numerical solution for the simultaneous disturbance decoupling and row-by-row decoupling problem

The numerical computation of the simultaneous disturbance decoupling and row-by-row decoupling problem is considered. Based on a condensed form for the system matrices the solvability of the simultaneous disturbance decoupling and row-by-row decoupling problem is reduced to the verification of an integer equality and the nonsingularity of a lower-dimensional constant matrix. The condensed form we use is computed using only orthogonal transformations, which can be implemented in a numerically stable way. Hence, it leads directly to an effective numerical method for solving the disturbance decoupling and row-by-row decoupling problem using existing tools such as LAPACK and Matlab. Our result complements existing geometric and structural approaches which are of a theoretical nature and are not suitable for numerical computation.     

基于PWM整流器的功率控制器的仿真研究

文章研究了一种基于PWM整流器的功率控制器。由三相电压型整流器在三相静止坐标系中的数学模型,导出其在两相旋转坐标系的数学模型,并在此基础上引入了基于电网电压前馈解耦的三相PWM整流器控制系统,实现对于有功电流和无功电流的单独控制,从而达到对于有功、无功功率控制的目的。     

ADC外围电路的设计

ADC外围电路的设计通常包括模拟电路、数字电路和电源电路的设计。为了满足ADC的需要,ADC外围电路的设计重点是输入放大信号,为了使其充分发挥整体性能,必须在ADC转换期间保持输入电压的稳定;为了消除模拟多路开关因阻抗不匹配和转换阶跃信号变化对ADC输入及采样阶段的影响,需在多路开关与ADC之间加接高输入阻抗的电压跟随器,并待阶跃变化稳定后,再让采样保持电路进入采样阶段;为了满足微控制器对时序的要求,必须选择恰当的接口形式。此外,采用良好的接地方式与电压去耦方法,可以避免模拟信号和数字信号受到噪声干扰,也可避免两种信号产生互相干扰。为了防止噪声对数字信号的影响,还使用了相应的隔离方式。     

高密度Si基半导体电容器的性能及其制作

随着各种混合信号电路的性能和集成度的迅速提高以及对电路模块和元器件小型化的需要,集成无源技术成为一种取代分立无源器件以达到小型化的解决方案。鉴于电容器被广泛用于滤波、调谐和电源回路退耦等各种板级集成封装中,采用Si MEMS工艺,在半导体表面深刻蚀三维(3D)图形以增大有效表面积,制作了一种高电容密度的半导体pn结退耦电容器,并分析研究了其主要制成工艺和性能。结果显示,所制作的电容器的电容密度达8～12nF/mm2,相比无表面三维刻蚀图形的半导体电容器电容密度增大了10倍以上,退耦频率范围为10kHz～3.2GHz,可用于中低频率较大范围内的退耦。     

Site-specific ϕ- and ψ-torsion angle determination in a uniformly/extensively 13C- and 15N-labeled peptide

A solid-state rotational-echo double resonance (REDOR) NMR method was introduced to identify the ?- and ψ-torsion angle from a ¹H–¹⁵N or ¹H–¹³C′ spin system of alanine-like residues in a selectively, uniformly, or extensively ¹⁵N-/¹³C-labeled peptide. When a C_α(i) or a ¹⁵N peak is site-specifically obtainable in the NMR spectrum of a uniformly ¹⁵N/¹³C-labeled sample system, the ψ- or ?-torsion angle specified by the conformational structure of peptide geometry involving ¹⁵N(i)–¹H_αi–¹⁵N(i + 1) or ¹³C′(i − 1)–¹H^Ni–¹³C′(i) spin system can be identified based on ¹³C_α- or ¹⁵N-detected ¹H_α–¹⁵N or ¹H_N–¹³C REDOR experiment. This method will conveniently be utilized to identify major secondary motifs, such as α-helix, β-sheet, and β-turn, from a uniformly ¹⁵N-/¹³C-labled peptide sample system. When tested on a ¹³C-/¹⁵N-labeled model system of a three amino acid peptide Gly–[U–¹³C, ¹⁵N]Ala–[U–¹³C, ¹⁵N]Leu, the ψ-angle of alanine obtained experimentally, ψ = −40 ± 30°, agreed reasonably well with the X-ray determined angle, ψ = −39°.     

The influence of the molecular system on the performance of heteronuclear decoupling in solid-state NMR

The intensity of the carbon signal in a CPMAS experiment has been measured for two CH and three CH(2) moieties in four test molecules under different phase-modulated proton decoupling conditions and as a function of the spinning rate. The proton decoupling schemes investigated were the golden standard TPPM and three of the GTn family. Aim of this analysis was to better describe experimentally the impact and limitations of phase-modulated decoupling. Sizeable differences in the response to decoupling were observed in otherwise chemically identical molecular fragments, such as the CHCH(2) found in tyrosine, phenyl-succinic acid or 9-Anthrylmethyl-malonate, probably due to differences in spin-diffusion rates. In keeping with known facts, the efficiency of the decoupling was observed to decrease with the MAS rate, but with somewhat different trends for the tested systems.     

Heteronuclear dipolar decoupling in solid-state nuclear magnetic resonance under ultra-high magic-angle spinning

We compare in this communication several heteronuclear dipolar decoupling sequences in solid-state nuclear magnetic resonance experiments under a magic-angle spinning frequency of 60 kHz. The decoupling radiofrequency field amplitudes considered are 190 and 10 kHz. No substantial difference was found among the sequences considered here in performance barring the difference in the optimisation protocol of the various schemes, an aspect that favours the use of swept-frequency two pulse phase modulation (SW(f)-TPPM).     

Multiple resonance heteronuclear decoupling under MAS: dramatic increase of spectral resolution at moderate magnetic field and MAS frequencies

The effects of multiple-resonance heteronuclear decoupling under magic angle spinning (MAS) on the resolution of one-dimensional ¹⁹F and ³¹P and various two-dimensional MAS NMR spectra and on the residual non-refocusable coherence lifetimes in fluorinated aluminophosphate AlPO₄-CJ2, i.e. a compound that contains numerous highly abundant nuclei but no homonuclear spin bath, has been investigated. The design of the four-channel (¹H, ¹⁹F, ²⁷Al, ³¹P) MAS probe used for this study is first described. ¹H and ¹H–²⁷Al double-resonance decouplings allows lengthening the optimized transverse relaxation and increasing the resolution in the ¹⁹F and ³¹P dimensions. Under the application of multi-nuclear decoupling, a two-dimensional ¹⁹F–³¹P CP-HETCOR correlation spectrum for AlPO₄-CJ2 is recorded with unprecedented high-resolution in the two dimensions. Moreover, because ¹H-decoupling increases the ¹⁹F , it has been applied during the entire duration of the 2D NMR experiments, allowing the direct use of residual small interactions to generate ¹⁹F–¹⁹F and ¹⁹F–²⁷Al 2D NMR correlation spectra in AlPO₄-CJ2.     

基于解耦差分泽尼克待定系数法的二维横向剪切波面重建算法

横向剪切干涉术是一种自参考干涉计量技术,其原理是被检测波前与其自身被剪开的波前之间在重叠范围内相干涉,由干涉图得到两相互剪切波前的波前差,通过波面重建算法得到待测波面.在波面重建算法中,泽尼克待定系数法是其中的一种.分析了横向剪切干涉技术的测量原理;提出了一种新的基于解耦差分泽尼克待定系数法的二维横向剪切波面重建算法....