Electron paramagnetic resonance and thermoluminescence study of Ag ions in Li2B4O7 crystals

Electron paramagnetic resonance (EPR) is used to investigate the effects of ionizing radiation on Ag-doped lithium tetraborate (Li₂B₄O₇) crystals. Two similar, yet distinct, trapped-hole centers (Ag²⁺ ions substituting for Li⁺ ions) are produced by 60 kV x rays. One Ag²⁺ ion, labeled Center A, has no nearby defects and the other Ag²⁺ ion, labeled Center B, has a neighboring impurity which is most likely a Ag⁺ ion substituting for a Li⁺ ion. The production and thermal decay properties of the two Ag²⁺ ions are described and their g matrices and ¹⁰⁷Ag and ¹⁰⁹Ag hyperfine matrices are obtained from the EPR angular dependences. The principal values of the g matrices are similar for the two centers, but the hyperfine principal values differ significantly (Center B has smaller values than Center A). There are also differences in the directions of the principal axes for the two centers. Together, these results imply (1) that the unpaired spin is less localized for Center B and (2) that the ground-state positions of the neighboring oxygen ions are different for Centers A and B. This explains why the peaks of the Ag²⁺ charge-transfer photoluminescence bands associated with Centers A and B occur at different wavelengths (502 and 725 nm, respectively). An isochronal pulsed thermal anneal shows that these radiation-induced Ag²⁺ ions serve as the recombination site for the intense thermoluminescence peak observed near 152 °C.     

基于反向旋转位相板的共形光学系统设计

在共形光学系统中,椭球形整流罩打破了球形整流罩的旋转对称性,引入了随目标视场变化而变化的动态像差。共形光学设计的主要任务就是消除或者减小椭球形整流罩引入的动态像差,使共形光学系统的成像质量满足使用要求。设计了基于反向旋转位相板的共形光学系统,利用一对反向旋转位相板的反向旋转对目标视场进行动态扫描,利用固定校正器、衍射元件和泽尼克位相板校正了椭球形整流罩引入的动态像差。成像系统采用二次成像的透射式结构,实现了冷光阑效率100%。结果表明:该方法不仅有别于传统扫描方式,而且有效地消除了大长径比的共形光学系统的动态像差。     

饱和非线性效应对负折射材料中孤子自频移的影响

以描述负折射材料中包含拉曼效应的高阶非线性薛定谔方程为模型,采用分步傅里叶算法数值分析了高阶效应,尤其是饱和非线性效应对自聚焦负折射率材料中的孤子拉曼自频移的影响。结果表明,在自聚焦负折射率材料中饱和非线性效应使孤子拉曼自频移速度加快;饱和非线性效应与负的自陡效应共同作用进一步加快孤子自频移的速度;饱和非线性效应同正的自陡效应、三阶色散效应共同作用时孤子拉曼自频移在整体上受到抑制。     

Deformation of cholesteric elastomers by uniaxial stress along the helix axis

The deformation of cholesteric elastomers by mechanical stress applied parallel to the helix axis is studied by calculation of the free-energy density. The Frank-elasticity contribution is taken into account. A chiral solvent, present at cross-linking time, is in general considered to be replaced after cross-linking by a solvent with different chirality. Two special cases considered are zero and unchanged solvent chirality, the first known as that of imprinted cholesteric elastomers, the latter equivalent to intrinsic cholesteric elastomers with chemically attached chiral groups. Depending on material parameters and imposed strain, the director can show a tilt towards the helix axis up to the maximum tilt, corresponding to a nematic state. In case of intrinsic elastomers with low conformation anisotropy, direct transitions from untilted to nematic states can be induced by straining. The helix structure of the director field is coarsened with an average wave number different to that of the information inscribed in the network at cross-linking time, if this lowers the average free-energy density. Switching between different states can be achieved with electric fields of reasonable values applied parallel to the helix axis. Spectra of the reflection of polarized light are calculated.     

Quantum transport in honeycomb lattice ribbons with armchair and zigzag edges coupled to semi-infinite linear chain leads

We study quantum transport in honeycomb lattice ribbons with either armchair or zigzag edges. The ribbons are coupled to semi-infinite linear chains serving as the input and output leads and we use a tight-binding Hamiltonian with nearest-neighbor hops. The input and output leads are coupled to the ribbons through bar contacts. In narrow ribbons we find transmission gaps for both types of edges. The appearance of this gap is due to the enhanced quantum interference coming from the multiple channels in bar contacts. The center of the gap is at the middle of the band in ribbons with armchair edges. This particle-hole symmetry is because bar contacts do not mix the two sublattices of the underlying bipartite honeycomb lattice when the ribbon has armchair edges. In ribbons with zigzag edges the gap center is displaced to the right of the band center. This breakdown of particle-hole symmetry is the result of bar contacts now mixing the two sublattices. We also find transmission oscillations and resonances within the transmitting region of the band for both types of edges. Extending the length of a ribbon does not affect the width of the transmission gap, as long as the ribbon’s length is longer than a critical value when the gap can form. Increasing the width of the ribbon, however, changes the width of the gap. In ribbons with zigzag edges the gap width systematically shrinks as the width of the ribbon is increased. In ribbons with armchair edges the gap is not well-defined because of the appearance of transmission resonances. We also find only evanescent waves within the gap and both evanescent and propagating waves in the transmitting regions.     

Omnidirectional reflection and flat-top transmissionin Thue-Morse quasicrystal with single-negative materials

By means of transfer matrix method, we investigate the transmittance and reflectance of Thue-Morse (T-M) structure composed of negative-permittivity and negative-permeability materials. It is shown that the width and location of an omnidirectional reflectance band remain invariant with the change of generation order, and that the omnidirectional reflectance band is determined by both TE and TM polarization, which different completely from that in dielectric T-M structure. Moreover, a flat-top total transmission band occurs around the same frequency in which the general zero average permittivity and permeability are both satisfied in T-M structure. The basis for these phenomena are presented and discussed.     

Electrical generation of pure spin current with oscillating spin-orbit interaction

We propose an electrical scheme for the generation of a pure spin current without a charge current in a two-terminal device, which consists of a scattering region of a two-dimensional electron gas (2DEG) with Rashba (R) and/or Dresselhaus (S) spin-orbit interaction (SOI) and two normal leads. The SOI is modulated by a time-dependent gate voltage to pump a spin current. Based on a tight-binding model and the Keldysh Green’s function technique, we obtain the analytical expression of the spin current. It is shown that a pure spin current can be pumped out, and its magnitude could be modulated by device parameters such as the oscillating frequency of the SOI, as well as the SOI strength. Moreover, the spin polarisation direction of the spin current could also be tuned by the strength ratio between RSOI and DSOI. Our proposal provides not only a fully electrical means to generate a pure spin current but also a way to control the spin polarisation direction of the generated spin current.     

The structure and optical characters of the ZnO film grown on GaAs/Al2O3 substrate

In this paper ZnO films are grown on GaAs/Al₂O₃ substrates at different temperature by metal-organic chemical vapor deposition (MOCVD). The GaAs/Al₂O₃ substrates are formed by depositing GaAs layer (∼35 nm) on the Al₂O₃ substrate. The results of X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) demonstrate that most of the Ga and As atoms form Ga-As bond and the GaAs layer does not present any orientation. The characters of the ZnO films grown on GaAs/Al₂O₃ substrates are investigated by XRD, photoluminescence (PL), atomic force microscopy (AFM) and Raman scattering. Compared with ZnO film grown on Al₂O₃ substrate, ZnO film prepared by our fabrication scheme has good crystal and optical quality. Meanwhile its grain size becomes bigger according to the AFM image. Raman analysis indicates that the intrinsic defects and the in-plane tensile stress are obviously reduced in ZnO/GaAs/Al₂O₃ samples.     

Highly sensitive room-temperature method of non-invasive in vivo detection of magnetic nanoparticles

Methods of non-invasive in vivo quantification of magnetic nanoparticles (MP) have been proposed and realized. The methods are based on non-linear MP magnetization at two frequencies and measuring the response at combinatorial frequencies. The first method is developed for real-time study of MP dynamics and their clearance from the blood system of animals. High sensitivity of 3 ng of Fe₃O₄ in 0.1 ml was achieved for MP detection in mice tail veins. The second technique is proposed for MP detection inside animal tissues by an external probe. The proposed methods could essentially widen capabilities of biomedical research which involves magnetic nanoparticles.     

Magnetocaloric properties in the Cr-doped La0.7Sr0.3MnO3 manganites

Single-phase polycrystalline samples of La_0.7Sr_0.3Mn_1-xCr_xO₃ with nominal composition of x=0.00, 0.20, 0.40 and 0.50 were prepared by a conventional solid-state reaction method in air. Investigations of magnetization were carried out in the temperature range 5-400 K and magnetic field range 0-8 T. It was found that the Curie temperature T_C decreases with increasing x and the maximum magnetic entropy change (−ΔS_M) for x=0.20 is ∼1.203 and ∼2.653 J/kg K, respectively for 2 and 6 T magnetic field near the temperature of 280 K.