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101.
Monica Sorescu L Diamandescu D Tarabasanu-Mihaila 《Journal of Physics and Chemistry of Solids》2004,65(10):1719-1725
α-Fe2O3-In2O3 mixed oxide nanoparticles system has been synthesized by hydrothermal supercritical and postannealing route, starting with (1−x)Fe(NO3)3·9H2O·xIn(NO3)3·5H2O aqueous solution (x=0-1). X-ray diffraction and Mössbauer spectroscopy have been used to study the phase structure and substitutions in the nanosized samples. The concentration regions for the existence of the solid solutions in the α-Fe2O3-In2O3 nanoparticle system together with the solubility limits of In3+ ions in the hematite lattice and of Fe3+ ions in the cubic In2O3 structure have been evidenced. In general, the substitution level is considerably lower than the nominal concentration x. A justification of the processes leading to the formation of iron and indium phases in the investigated supercritical hydrothermal system has been given. 相似文献
102.
Cristian Barbarosie Anca‐Maria Toader 《Mathematical Methods in the Applied Sciences》2005,28(9):1089-1114
We prove bounds on the homogenized coefficients for general non‐periodic mixtures of an arbitrary number of isotropic materials, in the heat conduction framework. The component materials and their proportions are given through the Young measure associated to the sequence of coefficient functions. Upper and lower bounds inequalities are deduced in terms of algebraic relations between this Young measure and the eigenvalues of the H‐limit matrix. The proofs employ arguments of compensated compactness and fine properties of Young measures. When restricted to the periodic case, we recover known bounds. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
103.
Hierarchically ordered structures facilitate the incorporation of diverse functions simultaneously. The present report introduces a simple and novel strategy for producing hierarchically ordered polymeric films. Hierarchical ordering of aqueous droplets on a polymer solution is realized by the imposition of physical confinement via various shaped gratings. After drying of the solution, well‐ordered hierarchical structures were fabricated in the remaining polymer film. The size of the grating structure and the lattice size of spontaneous hexagonally packed aqueous pores comprise two different length scales, thereby offering multiscale ordering. Interfacial wetting of the polymer solution to the grating surface was crucial in terms of obtaining a highly ordered structure that can be tuned by dissolving a small amount of surfactant in the polymer solution. The present novel approach provides a new opportunity for lithography‐free fabrication of complex hierarchical structures. 相似文献
104.
S. Bidault L. Viau O. Maury S. Brasselet J. Zyss E. Ishow K. Nakatani H. LeBozec 《Advanced functional materials》2006,16(17):2252-2262
The bottom‐up design of polymer films exhibiting quadratic nonlinear optical properties that can be tuned optically and chemically is described. The polymer matrices are doped with metal‐containing chromophores built around a ZnII core and photoisomerizable ligands with two different geometries. These molecules possess specifically designed photophysical and nonlinear optical properties to be used towards all‐optical poling, an interference process between one‐ and two‐photon excitations that locally induces macroscopic second‐order effects in polymer films. It is shown that grafting the molecules onto the polymer chains improves the stability of the macroscopic photoinduced nonlinearity in the films. 相似文献
106.
S. A. Patlazhan 《Journal of Polymer Science.Polymer Physics》1993,31(12):1649-1665
A statistical theory of light scattering from deformed isotropic and textured heterogeneous polymer materials is formulated. Two types of textured structures are analyzed: assemblies of optically isotropic and anisotropic rods and a spatially anisotropic distribution of isotropic spherical inclusion centers. The small-angle Hv light-scattering patterns are calculated. The appearance of scattering from isotropic rods and spheres in deformed materials has been demonstrated. The changes of the Hv scattering patterns as a function of elongation and strucuture parameters are discussed. © 1993 John Wiley & Sons, Inc. 相似文献
107.
I.V. Kityk A. Ali Umar M. Oyama 《Physica E: Low-dimensional Systems and Nanostructures》2005,27(4):420-426
We have found that the gold nanoparticles on the ITO substrates might be considered promising materials for circularly polarized light-induced linear electrogyration (EG). The maximal achieved value of the EG susceptibility described by third-order axial tensor caused by probe circularly polarized light at a wavelength of 1060 nm was equal to about 13 deg/mm at pulsed electric field strength 30.0 V/cm with a duration of about 1 ms. We have revealed that the maximal EG coefficient is achieved for the samples possessing maximal resistivity. The investigated composites possess long-lived EG grating which decreases by not more than 12% after 120 min of laser treatment. Applying a non-circular pump light leads to the diminishing of the observed EG. 相似文献
108.
We study the aggregation of oxygen dipoles well dispersed in a CaF2 crystal upon annealing at temperatures ranging from 370 to 420 K. The concentration of oxygen dipoles is monitored by measuring the intensity of the ionic thermocurrent peak as well as by absorption and luminescence spectroscopies. Results from three methods agree within experimental error and yield an activation energy of (1.2±0.1) eV for the diffusion of isolated oxygen centres in the crystal. 相似文献
109.
V.I. Anisimov I.A. Nekrasov D.E. Kondakov T.M. Rice M. Sigrist 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(2):191-201
The electronic structures of the metallic and insulating phases of the alloy series Ca2-xSrxRuO4 ( 0 ?
x
? 2) are calculated using LDA, LDA+U and Dynamical Mean-Field Approximation methods. In the end members the groundstate respectively
is an orbitally non-degenerate antiferromagnetic insulator (x
= 0) and a good metal (x
= 2). For x
> 0.5 the observed Curie-Weiss paramagnetic metallic state which possesses a local moment with the unexpected spin S
= 1/2, is explained by the coexistence of localized and itinerant Ru-4d-orbitals. For 0.2 <
x
< 0.5 we propose a state with partial orbital and spin ordering. An effective model for the localized orbital and spin degrees
of freedom is discussed. The metal-insulator transition at x
= 0.2 is attributed to a switch in the orbital occupation associated with a structural change of the crystal.
Received 27 July 2001 相似文献
110.
Akhlesh Lakhtakia Martin W. McCall Werner S. Weiglhofer 《AEUE-International Journal of Electronics and Communications》2002,56(6):407-410
This brief overview covers a rapidly occurring development in the area of microwave composite materials: isotropic dielectric–magnetic mediums wherein the phase velocity vector and the time–averaged Poynting vector are oppositely directed. Such materials have also been inappropriately designated as left–handed materials. Ramifications for aberration–free lenses, homogenization approaches, and complex mediums are also presented. 相似文献