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91.
92.
93.
The pentafluorobenzenethiyl radical is an efficient hydrogen abstractor from an activated methylene or methine group and bis(pentafluorophenyl) disulfide is an efficient electron acceptor from the resulting radical intermediate. Thus benzyl-OTBS ether was easily converted into the corresponding pinacol, and 2-phenyl-1,3-dioxanes are converted into the monobenzoates of diols. 相似文献
94.
Kuan‐Wei Lee Hong‐Cheu Lin 《Journal of polymer science. Part A, Polymer chemistry》2007,45(20):4564-4572
A series of new liquid crystalline homopolymers, copolymers, and block copolymers were polymerized from styrene‐macroinitiator ( SMi ) and methacrylates with pendent 4,4′‐bis(biphenyl)fluorene ( M1 ) and biphenyl‐4‐ylfluorene ( M2 ) groups through atom transfer radical polymerization (ATRP). The number‐average molecular weights (Mn) of polymers P1 ‐ P4 were 10,007, 14,852, 6,275, and 10,463 g mol?1 with polydispersity indices values of 1.21, 1.15, 1.31, and 1.22, respectively. All polymers exhibit the nematic phase. The thermal, mesogenic, and photoluminescent properties of all polymers were investigated. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4564–4572, 2007 相似文献
95.
在相对碰撞平动能为 0 .0 5eV的分子束实验条件下 ,研究了亚稳态CO(a) +NO(X)的E E传能通道 .通过测量和分析交碰区的传能发射光谱 ,在 780和 860nm处观测到了NO(b -a)跃迁Ogawa带的△v =+ 4和△v =+ 3序的发射光谱 .从而首次在实验上直接证实了传能过程中第四通道的存在 (CO (a) +NO(X)→CO (X) +NO(b) ) .这一通道的发现解释了前人测量到的在CO(a)与NO(X)碰撞传能过程中CO(a)的猝灭速率远大于NO(A ,B)生成速率的实验结果 ,并进一步证实了这一“经典”E E传能体系为电子交换机理的传能观点 相似文献
96.
Xiaohua He Hailiang Zhang Deyue Yan Xiayu Wang 《Journal of polymer science. Part A, Polymer chemistry》2003,41(18):2854-2864
A series of side‐chain liquid‐crystalline (LC) homopolymers of poly[6‐(4‐methoxy‐4′‐oxy‐azobenzene) hexyl methacrylate] with different degrees of polymerization were synthesized by atom transfer radical polymerization (ATRP), which were prepared with a wide range of number‐average molecular weights from 5.1 × 103 to 20.6 × 103 with narrow polydispersities of around 1.17. Thermal investigation showed that the homopolymers exhibit two mesophases, a smectic phase, and a nematic phase, and the phase‐transition temperatures of the homopolymers increase clearly with increasing molecular weights. A series of novel LC coil triblock copolymers with narrow polydispersities was synthesized by ATRP, and their thermotropic phase behavior was investigated with differential scanning calorimetry and polarized optical microscopy. The LC coil triblocks were designed to have an LC conformation of poly[6‐(4‐methoxy‐4′‐oxy‐azobenzene) hexyl methacrylate] with a wide range of molecular weights from 3.5 × 103 to 1.7 × 104 and the coil conformation of poly(ethylene glycol) (PEG) (number‐average molecular weight: 6000 or 12,000) segment. Their characterization was investigated with 1H NMR, Fourier transform infrared spectra, and gel permeation chromatography. Triblock copolymers exhibited a crystalline phase, a smectic phase, and a nematic phase. The phase‐transition temperatures from the smectic to nematic phase and from the nematic to isotropic phase increased, and the crystallization of PEG depressed with increasing molecular weight of the LC block. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2854–2864, 2003 相似文献
97.
Yi Qin Thomas Trautmann 《Journal of Quantitative Spectroscopy & Radiative Transfer》2004,84(1):105-114
As a computationally effective tool, the first-order term of the radiative perturbation theory has been computed successfully, and has been applied in a number of areas. In this article, we develop the computational expressions for the higher-order terms of the perturbation expansion in a plane parallel atmosphere. These expressions are then implemented, and numerical results for some typical cases are presented. These results indicate that the computation is successful and that the higher-order terms are essential in cases where the first-order term alone cannot predict the perturbation with sufficient accuracy. 相似文献
98.
Spectral changes induced by moderate electric fields provide detailed insight into the electronic states of organic and inorganic solids. Although the basic effects, Stark effect and Franz–Keldysh effect, are the same in both types of material, the electroabsorption spectra vary strongly in size and spectral lineshape due to competing interactions. The large variance of the effects is demonstrated by representative examples of high mobility semiconductors, quantum wells, π-conjugated polymers, and charge transfer transitions in single crystals, disordered films and a double-quantum well. It is shown that only high-quality samples reveal the quantum mechanics of field-induced effects which are very sensitive to disorder. 相似文献
99.
Guey‐Sheng Liou Hung‐Yi Lin Yu‐Lun Hsieh Yi‐Lung Yang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4921-4932
N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl3), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (Tgs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (ΦF) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007 相似文献
100.
The mobile agent is a fundamental building block of the mobile computing paradigm. In mobile agent security, oblivious transfer
(OT) from a trusted party can be used to protect the agent’s privacy and the hosts’ privacy. In this paper, we introduce a
new cryptographic primitive called Verifiable Distributed Oblivious Transfer (VDOT), which allows us to replace a single trusted party with a group of threshold trusted servers. The design of VDOT uses a novel
technique called consistency verification of encrypted secret shares. VDOT protects the privacy of both the sender and the receiver against malicious attacks of the servers. We also show the
design of a system to apply VDOT to protect the privacy of mobile agents. Our design partitions an agent into the general
portion and the security-sensitive portion. We also implement the key components of our system. As far as we know, this is
the first effort to implement a system that protects the privacy of mobile agents. Our preliminary evaluation shows that protecting
mobile agents not only is possible, but also can be implemented efficiently.
This work was supported in part by the DoD University Research Initiative (URI) program administered by the Office of Naval
Research under grant N00014-01-1-0795. Sheng Zhong was supported by ONR grant N00014-01-1-0795 and NSF grants ANI-0207399
and CCR-TC-0208972. Yang Richard Yang was supported in part by NSF grant ANI-0207399. A preliminary version of this paper
was presented at the DialM-POMC Joint Workshop on Foundations of Mobile Computing in 2003.
Sheng Zhong received his Ph.D. in computer science from Yale University in the year of 2004. He holds an assistant professor position
at SUNY Buffalo and is currently on leave for postdoctoral research at the Center for Discrete Mathematics and Theoretical
Computer Science (DIMACS). His research interests, on the practical side, are security and incentives in data mining, databases,
and wireless networks. On the theoretical side, he is interested in cryptography and game theory.
Yang Richard Yang is an Assistant Professor of Computer Science at Yale University. His research interests include computer networks, mobile
computing, wireless networking, sensor networks, and network security. He leads the LAboratory of Networked Systems (LANS)
at Yale. His recent awards include a Schlumberger Fellowship and a CAREER Award from the National Science Foundation. He received
his B.E. degree from Tsinghua University (1993), and his M.S. and Ph.D. degrees from the University of Texas at Austin (1998
and 2001). 相似文献