流道缩扩比对半波纹微通道流动和传热特性的影响

为探究流道缩扩比对半波纹微通道流动和传热特性的影响,设计了5种不同缩扩比的半波纹微通道模型,并对各通道内的层流流动(200＜Re＜1000,Re为雷诺数)和传热进行了数值模拟研究。结果表明,半波纹微通道的压降和努塞尔数随着流道缩扩比的减小而增大;与光滑微通道相比,半波纹微通道具有更优的传热性能但压降损失也更高;引入η作为综合性能指标,发现减小流道缩扩比是提高半波纹微通道综合换热能力的有效方式,且当Re＞490时,其综合换热能力均优于光滑微通道。     

BP神经网络结合变量选择方法在牛奶蛋白质含量检测中的应用北大核心CSCD

牛奶中的蛋白质含量会影响牛奶的品质,利用高光谱图像的光谱特征信息研究对牛奶蛋白质含量预测的可行性。本文提出一种基于竞争性自适应重加权算法(competitive adaptive reweighted sampling, CARS)和连续投影算法(successive projections algorithm, SPA)结合多层前馈神经网络(back propagation, BP)的预测建模方法,实验以含有不同浓度蛋白质的牛奶为对象,利用可见光/近红外高光谱成像系统共采集到5种牛奶共计250组高光谱数据,通过实验对比选择采用标准化方法对获取到的吸收光谱预处理,然后采用CARS结合SPA筛选特征波长,得到18个特征波长,建立CARS-SPA-BP模型,经过试验,CARS-SPA-BP模型的训练集决定系数和测试集决定系数R;和R;分别达到0.971和0.968,训练集均方根误差(root mean square error of calibration,RMSEC)和测试集均方根误差(root mean square error of prediction,RMSEP)达到了0.033和0.034。研究发现,采用CARS结合SPA筛选的牛奶特征波长建立的多层前馈神经网络模型,其模型预测结果与全波长建模相比并没有明显降低,因此将CARS结合SPA用于波长筛选并且结合BP神经网络基本可以完成对牛奶蛋白质含量的预测。为验证CARS-SPA-BP模型的预测能力,在相同数据环境下,使用较为传统的偏最小二乘回归(partial least squares regression, PLSR)进行建模,实验结果表明,CARS-SPA-BP相较于PLSR,R;和RMSEP均有明显提升。研究表明,CARS-SPA-BP可充分利用牛奶光谱特征信息实现较高精度的牛奶蛋白质含量检测。     

Solid-state synthesis and properties of SmCoO3

In this paper, perovskite oxide SmCoO₃ was prepared by the solid-state reaction method using Co₂O₃ and Sm₂O₃ as raw materials. The structure and properties of the samples were investigated by XRD, Raman spectral techniques, and DC measurements and so on. The results of XRD and Raman spectra showed that the mixtures of Co₂O₃ and Sm₂O₃ can react to produce a single phase perovskite oxide SmCoO₃ around 1353 K. The single-phase SmCoO₃ changes from an insulator to a semi-conductor and transition occurs around 470 K. The thermal expansion coefficient (2.17 × 10⁻⁵ K⁻¹) of the single-phase SmCoO₃ is approximately equal to that of doped LaGaO₃, but much bigger than that of SDC(Ce_0.85Sm_0.15O₂) above 873 K.     

Synthesis and Electrochemical Studies of Spinel LiNi1−xMnxVO4

Spinel compound LiNi_1−xMn_xVO₄ (0≤x≤0.4) had been prepared by using the moist chemical method. X-ray diffraction spectra showed that the lattice constant increased with x in the LiNi_1−xMn_xVO₄, XPS spectra indicating that Li1s had a chemical shift towards lesser binding energy, and manganese in LiNi_1−xMn_xVO₄ existing as the mixed valence of Mn²⁺ and Mn³⁺. The electrochemical charge and discharge testing at a current density of 0.1 mA/cm² between the potentials of 4.0 and 3.0 V vs Li/Li⁺ in 1 mol/dm³ LiPF₆/EC+DEC (1:1 by volume) at 25°C showed that LiNi_1−xMn_xVO₄ cell has a better rechargeability, but a lower cell voltage of 4.0 V vs Li/Li⁺ than that without the doping sample, and the capacity and the cycle efficiency of the Li/LiNi_1−xMn_xVO₄ cells increased with x in the LiNi_1−xMn_xVO₄.     

Study of the bandwidth characteristic of a non-reflection-type gyrotron TWA

With a set of equations for the self-consistent large-signal interaction derived in this paper, the bandwidth characteristics of a non-reflection-type gyrotron-TWA using a tapered waveguide and tapered magnetic field system have been analysed. Numerical calculations indicate that under defined conditions an instantaneous bandwidth of nearly 10 % at a center frequency of 35 GHz with a length of the order of only8 cm of the rf interaction region could be achieved.     

基于小波变换的循环伏安弱信号特征信息提取

本研究采用连续小波变换(continuous wavelet transform，CWT)技术处理循环伏安弱信号，通过研究苯酚、对苯二酚和对硝基苯酚的共存体系循环伏安弱信号，表明CWT可以成功地识别出极弱信号中的指纹特征信息，并且经处理得到的对应的小波系数峰比原始信号更窄，更高，由此可以成功地确定弱峰的数目和位置。由循环伏安信号所得的结果，有力地证实CWT是循环伏安弱信号识别的有力工具，对于理解弱响应体系电化学机理具有重要作用。     

Synchrotron-radiated X-ray and neutron diffraction study of native cellulose

Precise determination of d-spacings and compositional ratio of cellulose I_α and I_β in various native cellulose samples was successfully carried out by synchrotron-radiated X-ray diffraction and time-of-flight (TOF) neutron diffraction from quasi-powder specimens. X-ray diffraction peaks were separated by the deconvolution method using six types of profile function: Gaussian, Lorentzian, intermediate Lorentzian, modified Lorentzian, pseudo-Voigt, and Pearson VII. In terms of R-factors, the pseudo-Voigt function gave the best fit with the observation, and was used for determination of d-spacings. The numerical results for Valonia cellulose were: dI_α (1 0 0) = 0.613 nm; dI_β (1 1 0) = 0.603 nm; dI_β (1 1 0) = 0.535 nm; dI_α (0 1 0) = 0.529 nm; I_α content = 0.65. The differences determined between dI_α (1 0 0) and dI_β (1 1 0) and between dI_β (1 1 0) and dI_α (0 1 0) were similar to those previously reported. Comparison between unresolved peaks for the two types of cellulose samples revealed a small but definite difference between dI_α (1 1 0) and dI_β (2 0 0). The TOF neutron diffractometry using deuterated samples confirmed this difference. This revised version was published online in August 2006 with corrections to the Cover Date.     

有机官能化MSU-x孔分子筛的界面特征

MSU- x是自 M41S系列介孔分子筛问世以来所合成的另一类新型介孔分子筛材料 ,它具有三维立体交叉排列的 " worm- like"孔道结构特征及采用中性模板剂、廉价无毒等诸多合成优点 [1～ 4],有着潜在的应用价值 .为了改善纯硅的介孔材料的表面和孔道性质 ,扩大其应用领域 ,除了在骨架引入金属离子或在其孔道中负载催化活性物质外 ,对介孔材料进行有机官能化制备无机-有机杂化材料改善其骨架和孔道性质是当前研究的热点之一 [5].正是由于活性有机基团的存在 ,使得这些材料可直接用于催化反应 ,或作为中间介质成为其它络合离子的主体 .由于有机基…     

药物不良反应的特点与预防

药物不良反应已成为全社会关注的热点，及时了解有关不良反应的情况并采取必要的预防措施，以保证患者用药安全，维护患者身体健康是医务工作者刻不容缓的任务。     

侧链对聚对苯撑乙炔溶解性和光谱性能的影响

利用钯催化反应合成了一类侧链含不同烷氧取代基(甲氧基，辛烷氧基，十二烷氧基)的聚时苯撑乙炔，讨论了侧链烷氧取代基对聚对苯撑乙炔的分子量和溶解性的影响，比较了聚合物的紫外吸收光谱和荧光光谱特征。