Wearable Organic Electrochemical Transistor Array for Skin-Surface Electrocardiogram Mapping Above a Human Heart

Electrocardiogram (ECG) mapping can provide vital information in sports training and cardiac disease diagnosis. However, most electronic devices for monitoring ECG signals need to use multiple long wires, which limit their wearability and conformability in practical applications, while wearable ECG mapping based on integrated sensor arrays has been rarely reported. Herein, ultra-flexible organic electrochemical transistor (OECT) arrays used for wearable ECG mapping on the skin surface above a human heart are presented. QRS complexes of ECG signals at different recording distances and directions relative to the heart are obtained. Furthermore, the ECG signals are successfully analyzed by the devices before and after exercise, indicating potential applications in some sports training and fitness scenarios. The OECT arrays that can conveniently monitor spacial ECG signals in the heart region may find niche applications in wearable electronics and healthcare products in the future.     

基于单电子晶体管的数字滤波器硬件实现

基于互补型单电子晶体管（SET）逻辑门，提出了SET加法器、移位寄存器和ROM的单元电路。在讨论数字滤波器硬件实现原理基础上，由这三个单元电路实现了一个二阶IIR滤波器。SET的SPICE宏模型验证了设计的正确性。     

变温C-V和传输线模型测量研究AlGaN/GaN HEMT温度特性

通过对异质结材料上制作的肖特基结构变温C-V测量和传输线模型变温测量,研究了蓝宝石衬底AlGaN/GaN异质结高电子迁移率晶体管的直流特性在25～200℃之间的变化,分析了载流子浓度分布、沟道方块电阻、欧姆比接触电阻和缓冲层泄漏电流随温度的变化规律.得出了器件饱和电流随温度升高而下降主要由输运特性退化造成,沟道泄漏电流随温度的变化主要由栅泄漏电流引起的结论.同时,证明了GaN缓冲层漏电不是导致器件退化的主要原因.     

基于物理并适用于电路仿真的多晶硅薄膜晶体管薄层电荷模型

本文利用薄层电荷理论,建立了一个基于表面势的、物理的多晶硅薄膜晶体管(Polysilicon Thin-Film Transistors,poly-Si TFTs)的电流模型,且该模型适用于电路仿真.推导了 poly-Si TFTs 表面势的近似解法,该求解法非迭代的计算大大地提高了计算效率,且精确度高并得到实验验证.基于物理的迁移率方程考虑了晶界势垒高度,和由于声子散射与表面粗糙散射引起的迁移率退化.基于 Brews 的薄层电荷模型和上述非迭代计算表面势,本电流模型同时考虑了漏致势垒降低(DIBL)效应、kink 效应和沟道长度调制效应.对不同沟长的器件实验数据比较发现,提出的模型在很广的工作电压内与实验数据符合得非常好.同时本模型的所有方程都具有解析形式,电流方程光滑连续,适用于电路仿真器如 SPICE.     

Cyclodimers and Cyclotrimers of 2,3 -Bisalkynylated Anthracenes,Phenazines and Diazatetracenes

The synthesis of novel (N−)acene-based cyclooligomers is reported. Glaser-Hay coupling of the bisethynylated monomers results in cyclodimers and cyclotrimers that are separable by column and gel-permeation chromatographies. For the diazatetracene, the use of sec-butyl-silylethynyl groups is necessary to achieve solubility. Diazatetracene-based cyclodimers and cyclotrimers were used as semiconductors in thin-film transistors. Although their optoelectronic properties are quite similar, their electron mobilities in proof-of-concept thin-film transistors differ by an order of magnitude.     

Energetic distribution of interface states extracted from photo-conductance of organic thin film transistors

In this paper, a new method is introduced to obtain the energetic distribution of the interface states (density of states; DOS) extracted from the photo-conductance of organic thin film transistors (OTFTs) which exhibit varied transfer characteristics under illumination with different photon energies. The method was applied to pentacene OTFTs, and the results were compared with existing data. The major findings were not only the existence of the well-known peaks of DOS at 1.82 eV (free exciton of pentacene), and at 1.49 eV (extrinsic exciton due to dihydropentacene) but also new peaks were found at 1.25 eV, 1.29 eV, 1.31 eV, and 1.35 eV in the mid-gap. The new peaks were strongly enhanced under exposure to oxygen, and thus seem to be related to the defects associated with the presence of oxygen.     

Solution processable PEDOT:PSS based hybrid electrodes for organic field effect transistors

We report high performance solution processed conductive inks used as contact electrodes for printed organic field effect transistors (OFETs). Poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) electrodes show highly improved very low sheet resistance of 65.8 ± 6.5 Ω/square (Ω/□) by addition of dimethyl sulfoxide (DMSO) and post treatment with methanol (MeOH) solvent. Sheet resistance was further improved to 33.8 ± 8.6 Ω/□ by blending silver nanowire (AgNW) with DMSO doped PEDOT:PSS. Printed OFETs with state of the art diketopyrrolopyrrole-thieno[3,2-b]thiophene (DPPT-TT) semiconducting polymer were demonstrated with various solution processable conductive inks, including bare, MeOH treated PEDOT:PSS, single wall carbon nanotubes, and hybrid PEDOT:PSS-AgNW, as the source and drain (S/D) electrode by spray printing using a metal shadow mask. The highest field effect mobility, 0.49 ± 0.03 cm² V⁻¹ s⁻¹ for DPPT-TT OFETs, was obtained using blended AgNW with DMSO doped PEDOT:PSS S/D electrode.