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971.
972.
973.
974.
本文在连续时间场合研究回归函数的非参数估计量之一———局部光滑统计量的性质 .不仅给出其a.s.收敛的一个速度 ,而且证明了该统计量不受边界效应影响的优良性质 ;同时指出了在连续时间的场合 ,估计量中窗宽的选择和样本的轨道性质都对该估计量的性质产生重要的影响 相似文献
975.
Conventional batch mode analysis of dissolved sulfide by cathodic stripping voltammetry (CSV) is known to suffer from loss of sulfide in the cell to the waste mercury pool, compromising quantification of sulfide. Here we report a simple alternative approach to batch-mode differential pulse CSV (DPCSV). A fresh aliquot of sample is used for each voltammetric scan to minimize loss of sulfide through reaction with the mercury by limiting the time for sulfide-mercury contact, which is found to be more important in suppressing the sulfide signal than the amount of free mercury in the cell. Our improved batch-mode method exhibited a limit of detection of 1.3 nM, a relative standard deviation of 2.5% in NaOH supporting electrolyte and a linear response to as high a concentration as 1600 nM in a supporting electrolyte composed of Na2CO3/NaHCO3 (pH 8.3) mixed with an equal volume of oxic groundwater. A relative standard deviation of 4.5% was obtained for a groundwater sample in Na2CO3/NaHCO3 (pH 8.3) supporting electrolyte. These values are comparable to previously published results. Compared to other sensitive sulfide analytical techniques such as gas chromatography or high performance liquid chromatography (HPLC), DPCSV is preferred for sulfide analysis in the field due to its simple and portable instrumentation, lack of complex sample preparation, and short analysis time. The method was applied on site to analyze Fe-rich, reducing groundwater samples collected at a landfill site in Winthrop, Maine. Sulfide concentrations ranged from undetectable (<4 nM) to 7340 nM, generally increasing as the oxidation/reduction potential (ORP) of the water became more negative. We also demonstrate, for the first time, that the onset of sulfate reduction as indicated by the presence of small amounts of sulfide (tens to hundreds of nM) occurs in groundwater systems when the ORP value reaches −130 mV. 相似文献
976.
The paper presents analytical and simulation models to study the impact of interrupt overhead on operating system throughput of network elements such as PC‐based routers, servers, and hosts when subjected to high‐speed network traffic. Under such high network traffic, the system throughput will be negatively affected due to interrupt overhead caused by the incoming traffic. We first present an analytical model for the ideal system when interrupt overhead is ignored. We then present two models which describe the impact of high interrupt rate on system throughput. One model is for employing PIO in which network adapters are not equipped with DMA engines, and the other model is for employing DMA in which network adapters are equipped with DMA engines. The paper also describes detailed discrete‐event simulation models for the ideal system and for systems with DMA and PIO. Simulations results as well as reported experimental measurements show that our analytical models are valid and give a good approximation. Our analysis and simulation work can be valuable in providing insight to understand and predict system behaviour, as well as improving and maintaining good host performance. The paper identifies analytically critical design operation points such as that of overload condition. The paper also proposes solutions and recommendations for improving performance. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
977.
N. Farzinnejad A.A. Miran Beigi L. Fotouhi K. Torkestani H.A. Ghadirian 《Journal of Electroanalytical Chemistry》2005,580(2):245-254
Electroreduction of 4-amino-6-methyl-3-thio-1,2,4-triazine-5-one (I), 6-methyl-3-thio-1,2,4-triazine-5-one (II), and 2,4-dimethoxy-6-methyl-1,3,5-triazine (III) in dimethylformamide was investigated. Electrochemical techniques including differential pulse voltammetry (DPV), cyclic voltammetry (CV), chronoamperometry, and coulometry were employed to study the mechanism of the electrode process. From the analysis of the voltammetric and spectroscopic experiments a mechanism was proposed for the electroreduction of thio-triazine and triazine compounds. Compounds I and II having thiol groups exhibited similar redox behavior. Both compounds displayed two cathodic peaks, whereas the third compound (III), with no thiol group, showed only one cathodic peak in the same potential range as the second peak of compounds I and II.The results of this study show that in the former wave, the one electron reduction of thiol led to a dimer (disulfide) species and in the latter, the triazine ring was reduced in a two-electron process. The effects of various physical and electrochemical parameters were studied and the electrochemical behavior of the monomers was reported as a function of these parameters. A completely irreversible behavior was observed from cyclic voltammograms obtained under different conditions. Furthermore, in this study some numerical constants, such as diffusion constant, transfer coefficient, and rate constant of coupled chemical reaction were determined. 相似文献
978.
979.
唐益民 《电气电子教学学报》2003,25(4):55-58,63
直流脉宽调制伺服系统以其可控性好、调速范围宽、功率因数高等一系列优点被越来越多的应用于工业控制、机器人、军工、航空航天等领域,并引起业内学者的广泛的重视。但是目前许多国内大专院校相关课程缺少直流脉宽调制伺服系统的实验器材。本文基于此背景,研制了一种直流PWM伺服系统驱动器实验平台。它具备常规单极性、受限单极性以及双极性三种工作模式。试用结果表明该系统具有显示度强、可靠性高、接口灵活的优点,适合于实验使用。 相似文献
980.
In this paper, we establish global necessary and sufficient optimality conditions for D.C. vector optimization problems under
reverse convex constraints. An application to vector fractional mathematical programming is also given.
Mathematics Subject Classifications (1991). Primary 90C29, Secondary 49K30. 相似文献