Performance Improvement of Acid Pretreated 3D-printing Composite for the Heavy Metal Ions Analysis

The performance enhancement of 3D-printed electrode comprised of polylactic acid (PLA) and graphite (Gr) doped with graphene oxide (GO) was studied to detect five heavy metal ions in trace level. The pretreatment of PLA/Gr/GO electrode with potential cycling in H₂SO₄ solution achieved the most sensitive response. The characteristics of the composite electrodes were verified using XPS, FE-SEM, EDXS, Raman, and impedance spectroscopy. The experimental variables affecting the response current were optimized with respect to pH, deposition time, ratio of PLA/Gr/GO, and supporting electrolytes. The pretreated 3D-PLA/Gr/GO electrode showed a wide dynamic range from 0.5 ppb to 1.0 ppm with low detection limits of 0.039–0.13 ppb. The reliability of the PLA/Gr/GO electrode was evaluated by analyzing the reference samples of European Reference Materials.     

多路宽带带状线功率分配器设计分析

宽带功率分配器是电子系统的重要部件。提出了宽带带状线功率分配器的设计方案,详细论述了二功分器、八功分器的设计方法,研究了该方法在工程中存在的问题及解决办法。应用电路与电磁场仿真软件进行了仿真,制作了一个3～10 GHz的功率分配器样件,对样件进行了指标测试,详细分析了测试结果与仿真结果存在差异的原因。     

Advanced Polymer Designs for Direct-Ink-Write 3D Printing

The rapid development of additive manufacturing techniques, also known as three-dimensional (3D) printing, is driving innovations in polymer chemistry, materials science, and engineering. Among current 3D printing techniques, direct ink writing (DIW) employs viscoelastic materials as inks, which are capable of constructing sophisticated 3D architectures at ambient conditions. In this perspective, polymer designs that meet the rheological requirements for direct ink writing are outlined and successful examples are summarized, which include the development of polymer micelles, co-assembled hydrogels, supramolecularly cross-linked systems, polymer liquids with microcrystalline domains, and hydrogels with dynamic covalent cross-links. Furthermore, advanced polymer designs that reinforce the mechanical properties of these 3D printing materials, as well as the integration of functional moieties to these materials are discussed to inspire new polymer designs for direct ink writing and broadly 3D printing.     

Electrical Impedance Spectroscopic Study of CNT/Ethylene-alt-CO/Propylene-alt-CO Polyketones Nanocomposite

Impedance spectroscopy was utilized to investigate the dielectric properties, ac conductivity and charge transport mechanisms in propylene-alt-CO/ethylene-alt-CO (EPEC) random terpolymer filled with multi-walled carbon nanotubes (MWCNT) as a function of nanofiller content, frequency, and temperature. Equivalent resistor-capacitor (RC) circuit models were proposed to describe the impedance characteristics of the unfilled terpolymer and the nanocomposite at different temperatures. For the nanocomposites, the ac conductivity tended to be frequency independent at low frequencies. At high frequencies, the ac conductivity increased with frequency. The dc conductivity (i.e., plateau of the ac conductivity at low frequencies) at room temperature increased from 10^?9 (Ω·m)^?1 for the unfilled polymer to l0^?3 (Ω·m)^?1 for the 6 wt% MWCNT/EPEC nanocomposite. At low temperatures, the equivalent RC model for EPEC-0 and EPEC-2 was found to consist of a parallel RC circuit. However, for 6 wt% MWCNT/EPEC nanocomposite, an RC model consisting of an R/constant phase element (CPE) circuit and a resistor in series was required to describe the impedance behavior of the nanocomposite.     

3D printing as a means of learning and communication: The 3Ducation project revisited

This research project explores to what extent the utilization of open-source 3D printers and 3D design software could serve as means of learning and communication. The principles of non-formal education aligned with the concept of constructionism are used to create an experimental educational scenario focused on geocultural tourism for persons with visual impairments. This paper documents our experience and presents our findings from a 25-day long project, which took place in Zagori, northwestern Greece. 11 high school students from Portugal designed and manufactured natural and cultural heritage artifacts carrying messages in the Braille language. The objects were then handed to people with visual impairments with a twofold aim. First, to enable the communication among persons with and without visual impairments; and, second, to empower students to participate in training projects through open educational procedures. We conclude that open educational practices can boost students’ active engagement in educational processes. Finally, 3D printing encourages a meaningful communication among people with and without visual impairments via the tangible exploration of geocultural components.     

Anhydride‐Assisted Spontaneous Room Temperature Sintering of Printed Bioresorbable Electronics

Bioresorbable electronic devices are promising replacements for conventional build‐to‐last electronics in implantable biomedical systems and consumer electronics. However, bioresorbable devices are typically achieved by complex complementary metal oxide semiconductor fabrication processes that minimize exposure to humidity. Emerging printable techniques for bioresorbable electronics demand further improvement in electrical conductivity and mechanical robustness. This paper presents a room‐temperature spontaneous sintering method of bioresorbable inks that contain zinc nanoparticles and anhydride. The entire process can be conducted in atmosphere environment under 90% humidity within 300 min. It has minimum requirement for external heating and special ambient conditions, allowing humidity to trigger the surface chemistry of zinc nanoparticles and spontaneous welding between neighboring nanoparticles. The resulting bioresorbable patterns are highly conductive (σ = 72 400 S m^?1) and mechanically robust (>1500 bending cycles) to enable practical applications. A radio circuit achieved through the above method can operate stably over 14 days in air and disappear in water for less than 30 min. The spontaneous room‐temperature sintering represents a rapid and energy‐efficient approach to achieve high‐performance bioresorbable electronics with improved mechanical robustness and electrical performance, leading to broader impacts in the areas of healthcare, information security, and consumer electronics.     

Printed Circuit Board-Based Electrolyte Regulator for Laminar Microfluidics

The trench on a printed circuit board was reconstructed to fabricate a microfluidic framework that allows low-cost production for small quantities and integration with multifunctional elements. An on-chip electrolyte regulator was thus proposed on this platform to analyze diffusion properties in laminar flow. A numerical model was developed, highlighting the interplay between the electrolyte migration and hydrodynamic properties. Solutions with dissolved sodium chloride were simulated and experimentally tested for the regulation of electrical conductivity under the guidance of the normalized Nernst-Planck equation. The diffusion mechanism and the resulting concentration field were demonstrated in detail. This approach provides a satisfactory manufacturing method and a useful tool for integrated microfluidic systems.     

电子电路故障检测技术探索

本文深入探究电子电路障碍检测技术出现故障的原因,对电子电路故障的检测技术实施具体分析。     

Unity direct chain with feedback series impedance based innovative negative group delay circuit

An innovative negative group delay (NGD) circuit theory on unity direct chain (UDC) topology is developed in this paper. The NGD UDC cells are based on the operational amplifier adder with feedback series impedance. Innovative topologies of high-pass NGD UDC cell composed of RL-series network, all-pass RC-parallel network and low-pass RC-series network are identified. It is a first time that all-pass NGD original topologies are defined. NGD analyses and synthesis methods of each NGD UDC cells are provided. The UDC cell based NGD functions are validated with SPICE simulations. The proofs-of-concept (POC) of UDCs behave as all-pass and low-pass NGD functions with group delay equal to −1 ms at very low frequencies. The low-pass NGD cut-off frequency is 424 Hz. The high pass NGD circuit generates −1 µs at the optimal NGD frequency of about 5.15 kHz. Further analysis of the operational amplifier gain and bandwidth effects is performed. The operational amplifier gain affects significantly the NGD level and bandwidth for the all considered UDC cells. Nevertheless, only the RC-parallel feedback based UDC cell is particularly sensitive to the operational bandwidth.     

Bioprinting of Collagen: Considerations,Potentials, and Applications

Collagen is the most abundant extracellular matrix protein that is widely used in tissue engineering (TE). There is little research done on printing pure collagen. To understand the bottlenecks in printing pure collagen, it is imperative to understand collagen from a bottom‐up approach. Here it is aimed to provide a comprehensive overview of collagen printing, where collagen assembly in vivo and the various sources of collagen available for TE application are first understood. Next, the current printing technologies and strategy for printing collagen‐based materials are highlighted. Considerations and key challenges faced in collagen printing are identified. Finally, the key research areas that would enhance the functionality of printed collagen are presented.