一种高效的大功率宽带整流电路

提出了一种由π型匹配枝节、整流二极管、直通滤波器组成的高效大功率宽带整流电路。采用2只HSMS-282P肖特基二极管桥设计单级倍压整流电路,使电路在整流效率不下降的情况下提升输入的功率容量;采用π型匹配枝节实现阻抗匹配,使电路具有宽频特性,同时其并联短路枝节可以作为输入滤波器,实现小型化和整流效率的提高。直通滤波器用于抑制基频和二极管非线性产生的高次谐波,以提高整流效率。实测结果表示：在2.05~2.6 GHz带宽内整流效率大于60%;在2.45 GHz工作频率和35 dBm输入功率下,整流电路在330 Ω负载上获得70%的整流效率。该整流电路具有整流效率高、功率容量大、频带宽的特性,可为工程人员设计大功率微波整流电路提供设计指导。     

手持终端设备主备电池控制系统设计

手持终端设备属于一种嵌入式系统,特别在工业应用领域对其供电持续性的要求很高。为了解决单电池供电下设备续航能力不足导致传输数据丢失的问题,本文设计一种主备电池控制系统,提高了整机的续航能力和电源系统的可靠性。方案设计对切换灵敏度、功耗和可靠性方面进行了综合考虑,已经应用到实际产品中,取得了良好的效果。     

一种Ku波段综合馈电多功能板的研制

基于多层微波数字复合基板层叠互联技术,研制的Ku波段综合馈电多功能板集成了射频收发网络、电源分配网络、阵面波控及波控分配网络,主要负责16个片式T/R组件的功率分配与合成,同时为各T/R组件提供电源及控制信号。文中对多功能板的架构设计、工作原理进行了说明,重点介绍了各微波垂直互联电路和射频收发网络的设计,最后加工并测试了验证样件,测试结果良好。收发网络总口驻波＜1.9,分口驻波＜1.3,插损＜16 dB,相邻端口的隔离度＞20 dB,且幅度一致性≤0.602 dB,相位一致性≤6.429°。工程应用可行性和实用性得到了验证。     

Development of an Enzymeless/Mediatorless Glucose Sensor Using Ruthenium Oxide‐Prussian Blue Combinative Analogue

Presented in this work is the first step towards an enzymeless/mediatorless glucose sensor. We first observed remarkable electrocatalytic oxidation of glucose using combinative ruthenium oxide (RuOx)‐Prussian blue (PB) analogues (designated as mvRuOx‐RuCN, mv: mixed valent) at ca. 1.1 V (vs. Ag/AgCl) in acidic media (pH 2 Na₂SO₄/H₂SO₄). Individual RuOx and PB analogs failed to give any such catalytic response. A high ruthenium oxidation state (i.e., oxy/hydroxy‐Ru^VII, E°≈1.4 V vs. RHE), normally occurring in strong alkaline conditions at RuOx‐based electrodes, was electrogenerated and stabilized (without any conventional disproportionation reaction) in the mvRuOx‐RuCN matrix for glucose catalysis. Detail X‐ray photoelectron spectroscopic studies can fully support the observation. The catalyst was chemically modified onto a disposable screen‐printed carbon electrode and employed for the amperometric detection of glucose via flow injection analysis (FIA). This system has a linear detection range of 0.3–20 mM with a detection limit and sensitivity of 40 μM (S/N=3) and 6.2 μA/(mM cm²), respectively, for glucose. Further steps towards the elimination of interference and the extendibility to neutral pHs were addressed.     

废弃线路板化学分析采样、制样及检测方法

介绍废弃线路板中有回收价值元素和有害物质分析的采样、制样及检测技术。样品经过分类采样、剪切破碎和高温灰化制样,采用样品全分析或副批混合样分析。通过提高称样量、多次测定求平均值的办法,火试金富集-重量法测定贵金属金、银。湿法王水溶解样品,碘量法测定主体元素铜。电感耦合等离子体发射光谱(ICP-AES)法测定其它杂质元素,被测元素质量浓度在0~10μg/mL范围内与光谱强度呈良好线性关系,相关系数均大于0.9998。测定结果的相对标准偏差小于10%(n=5),加标回收率为97.0%~102.5%。该方法简单、快速,有效地解决了线路板样品不均匀而难采样,以及硬度、韧性强制样难,金属易包裹难分解的技术瓶颈,测定结果准确,具有代表性。该方法适用于废弃线路板化学成分分析,其它废弃电子产品检测可参考此方法。     

Novel method for bulk resistance evaluation in conductivity measurement for high-purity water

A major issue with the electrolytic conductivity measurement for pure water is the lack of standard or reference methods. A primary method traceable to SI and suitable for pure-water conductivity measurement was developed at the Physikalisch-Technische Bundesanstalt (PTB), Germany, as the base for the calibration method for the conductivity measuring devices at the low conductivity level. This paper provides a novel method to calculate the bulk resistance of pure water using impedance measured at a single frequency, which is one of the key procedures for the primary methods.     

Stripping Chronopotentiometry with Dry‐Preservable Supporting Electrolyte

The determination of some toxic metals by stripping chronopotentiometry with a supporting solution having an unconventional composition has been investigated with the aim of using such components in disposable measuring cells preservable in dry state and quite ready for use, only needing addition of a small volume of sample. The new supporting solution is prepared with a solid strong acid, p‐toluenesulfonic acid, in the place of the inorganic acids commonly used to improve the cation availability. The other components are, as usual, sodium chloride, which fixes the potential of the screen‐printed silver – silver chloride reference electrode, and mercury(II) chloride as the plating agent. This supporting solution has been tested in batch measurements with the mercury film glassy carbon electrode as well as with screen‐printed carbon‐ink electrodes, either with mercury film or bare. The physical shape of the mercury layer electrolytically deposited on screen‐printed carbon‐ink electrodes from a supporting solution containing 0.1 M p‐toluenesulfonic acid and 0.1 M sodium chloride has been investigated by scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) microanalysis. In chronopotentiometric stripping p‐toluenesulfonic acid performs as well as the usual inorganic strong acids, particularly in terms of sensitivity. At 0.1 mol dm^?3 it proved very suitable for the determination of toxic metals, in particular lead(II), at levels down to a few μg dm^?3. The overall results appear promising and can open new avenues for preparing disposable cells for on‐field stripping chronopotentiometric determination of toxic metals.     

镍电极开路电位测定微量硼氢根离子

实验采用循环伏安法，用镍电极代替铂铑等贵金属电极测定了碱性体系中不同硼氢根离子浓度下的开路电位，得出了研究电极的开路电位（-0．355～-0．280vs.SCE／V）与微量硼氢根离子浓度的对应关系，并用于监测电解偏硼酸钠制备硼氢化钠体系中微量硼氢根离子，同时计算了该方法的误差。结果表明，测量结果的相对标准偏差为2．2％；回收率为98．4％。该法简单、快速，可测定10^-5～10^-3mol／L范围的硼氢根离子浓度。     

Examination of the statistical method in the conjugated circuit theory

Summary The recently proposed statistical method for the calculation of resonance energies in the conjugated circuit theory is tested on the example of polyacenes. It is found that for the estimation of the resonance energy with a 10% average error, the method requires a sample consisting of about 20 (randomly chosen) Kekulé structures. Further increase of the sample size gives no significant gain in the accuracy of the method.

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Überprüfung der statistischen Methode in der Konjugierten-Ring-Theorie

Zusammenfassung Die unlängst vorgeschlagene statistische Methode in der Konjugierten-Ring-Theorie (conjugated circuit theory) wird am Beispiel der Polyacene getestet. Es wurde festgestellt, daß für die Abschätzung der Resonanzenergien bei einem mittleren Fehler von 10% für diese Methode ungefähr 20 (willkürlich gewählte) Kekulé-Strukturen nötig sind. Weitere Erhöhung dieser Anzahl bringt keine signifikante Verbesserung der Genauigkeit der Methode.

     

Fluorinated compounds for advanced IC interconnect applications: a survey of chemistries and processes

The semiconductor industry is now in the early stages of an unprecedented change in materials set for the integrated circuit (IC) interconnect structure. The traditional layers of aluminum conductors and silicon dioxide dielectrics are being replaced by copper thin films and a variety of low k candidates, respectively. In many cases, fluorine confers desirable properties on either the precursors or the final films. At the same time, fluorine presents some potentially adverse effects, which have led to a so-called “fear-of-fluorine” in interconnect applications. This paper will review the proposed uses of fluorinated compounds in the interconnect structures, covering both precursors and the resulting thin films. Both the status of technical studies, and the prospects for commercial implementation, will be addressed.