MIMO扩频通信系统矩阵信道估计

为了解决第三代移动通信系统下行链路容量瓶颈问题，在HSDPA的解决方案中，MIMO系统的提案越来越受到重视。本文提出了一种移动深衰落环境下的MIMO系统信道估计方案，并进行了详细的理论推导，给出了独立MIMO深衰落信道环境下的仿真结果。     

On the Low-Lying Electronically Excited States of Azobenzene Dimers: Transition Density Matrix Analysis

Azobenzene-containing molecules may associate with each other in systems such as self-assembled monolayers or micelles. The interaction between azobenzene units leads to a formation of exciton states in these molecular assemblies. Apart from local excitations of monomers, the electronic transitions to the exciton states may involve charge transfer excitations. Here, we perform quantum chemical calculations and apply transition density matrix analysis to quantify local and charge transfer contributions to the lowest electronic transitions in azobenzene dimers of various arrangements. We find that the transitions to the lowest exciton states of the considered dimers are dominated by local excitations, but charge transfer contributions become sizable for some of the lowest ππ* electronic transitions in stacked and slip-stacked dimers at short intermolecular distances. In addition, we assess different ways to partition the transition density matrix between fragments. In particular, we find that the inclusion of the atomic orbital overlap has a pronounced effect on quantifying charge transfer contributions if a large basis set is used.     

非线性一维光子晶体特性的动态调制

对含有非线性材料的一维光子晶体带隙结构进行了数值计算.在外部入射光强调制下,非线性缺陷层折射率的改变会引起禁带内缺陷模的移动,而光子晶体禁带位置与宽度基本保持不变;若基本周期层取非线性材料,随入射光强的改变,禁带内部缺陷模发生相同的移动,同时,禁带位置和禁带宽度也会发生移动.利用这一性质可以对光子晶体进行动态外部调制,在此基础上对非线性一维光子晶体动态滤波选频进行了实验设计.     

单负材料一维光子晶体的透射谱特性

利用传输矩阵法研究了单负材料一维光子晶体(AB)m(ADBDB)n(AB)mA的透射谱,发现:透射谱中出现2个共振隧穿模,其位置和间距可由周期数m或n,以及介质层厚度d调节控制。改变m,会出现2个恒定间距的共振隧穿模;改变dA,共振隧穿模间距增大,且当dA≥25mm时,间距增大加剧;改变n,共振隧穿模逐渐趋于简并,当n≥6时,两隧穿模合二为一;改变dD,两共振隧穿模亦逐渐趋于简并,当dD≥20mm时,两隧穿模亦合二为一。这些特性可为利用光子晶体设计可调性高品质单通道、双通道滤波器提供参考。     

Matrimid–polyaniline/clay mixed‐matrix membranes with plasticization resistance for separation of CO2 from natural gas

Mixed‐matrix membranes (MMMs) of Matrimid® and polyaniline/clay (PC) are investigated for CO₂/CH₄ separation and CO₂‐induced plasticization. PC particles are synthesized through in‐situ polymerization of aniline in the presence of organophilic clay and then incorporated into Matrimid by solution casting method. Chemical structure and morphology of PC powder and fabricated membranes are analyzed by Fourier transform infrared (FTIR), X‐ray diffraction (XRD), differential scanning calorimetry/thermogravimetric analysis (DSC/TGA) and scanning electron microscopy (SEM). The XRD spectra of PC particles show the exfoliation of silicate layers throughout the polyaniline (PAni) matrix, and SEM images indicate flower‐petal morphology for PC particles. The permeability values of CO₂ and CH₄ increase 30–35% by incorporation of 10 wt% PC without any significant drop in selectivity. PC particles with flower‐petal morphology plays an important role in increasing the gas permeability values of both gases while Matrimid is the only phase that controls CO₂/CH₄ selectivity. The plasticization pressure was increased to 30 bar by incorporation of 10 wt% PC in the Matrimid matrix. CO₂ permeability and p_plast improved 35% and 200%, respectively, resulting in 300% enhancement in the capacity of MMM in the purification of natural gas with a selectivity of about 40. Copyright © 2016 John Wiley & Sons, Ltd.     

磁性亲水亲脂平衡萃取材料辅助基质固相分散萃取-高效液相色谱-串联质谱法同时测定中药材中76种农药残留

建立灵敏、可靠的中药材中农药多残留的检测方法对保证中药材的质量和安全十分重要.制备了磁性亲水亲脂平衡萃取材料Fe3 O4@PLS,将其应用于农药多残留的磁性基质固相分散萃取中,并结合高效液相色谱-串联质谱法(HPLC-MS/MS)检测了金银花、菊花和三七块根(干)3种中药材中76种农药残留量.研究通过扫描电子显微镜(S...     

基于两步分布协同拍卖的多机协同任务分配

针对多异构机载平台对不同类型的地面目标执行攻击任务的协同任务分配问题,以平台载弹量以及摧毁任务目标的需弹量建立平台与任务之间的关系,以各平台的任务序列以及执行任务时的武器使用量序列作为决策变量,在基地-任务航路矩阵和任务-任务航路矩阵的基础上,综合考虑平台武器约束、平台航程约束、任务需弹量等约束,建立多机协同任务分配模型。设计了两步分布协同拍卖算法,通过多次生成任务的拍卖招标顺序和基地的拍卖竞标顺序,实现了多机协同任务分配问题的优化求解。仿真结果表明,所建模型和求解算法能够有效合理地解决多机协同对地攻击的任务分配问题。     

基于模糊技术的非线性系统目标跟踪融合算法

提出了一种基于模糊技术的非线性系统中多传感器目标跟踪融合算法.在基于卡尔曼滤波器的分布式融合算法中,利用模糊技术中的决策距离思想,对实时跟踪目标的多传感器进行动态分组,以获得在非线性系统中目标跟踪的最佳融合数据精度.仿真结果证明,该算法是一种有效的分布式融合算法.     

介质折射率对一维三元光子晶体带隙的影响

利用光学传输矩阵法,数值模拟了一维二元、三元光子晶体的带隙结构,得出:三元光子晶体的主带隙略宽于二元光子晶体的主带隙;三元光子晶体的主带隙主要取决于最高折射率的介质和最低折射率的介质,而与居于两者之间的介质关系不大,并作出了相应的关系曲线。最后推导了三元光子晶体的色散关系。     

High-vacuum pyrolysis of 1,1,1-trifluoro-2-bromo-2-chloroethane. IR spectrum of 1,1,1-trifluoro-2-chloroethyl radical in an argon matrix

The products of high-vacuum pyrolysis of 1,1,1-trifluoro-2-bromo-2-chloroethane were studied by matrix IR spectroscopy. The decomposition of 1,1,1-trifluoro-2-bromo-2-chloroethane was shown to occur predominantlyvia two directions: to form the 1,1,1-trifluoro-2-chloroethyl radical and trifluoromethylcarbene isomerizing to trifluoroethylene. The CF₃CHCl radical has been detected in the matrix for the first time. The bands observed in the IR spectrum were calculated by the quantum-chemical B3LYP/6-311 G(d,p) method and assigned to normal vibrations of the radical. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2085–2088, October, 1998.